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公开(公告)号：US20120252946A1
公开(公告)日：2012-10-04
申请号：US13352452
申请日：2012-01-18
CPC分类号： C08K5/521 , B60C1/0016 , C08L21/00
摘要： A composition includes a diene rubber and a metal phosphate ester of the formula: M being a metal with an oxidation state of +3 or +4, and R1 and R2 are independently selected from any organic moiety including hydrogen, except R1 and R2 cannot both be hydrogen. In addition, a method of making a rubber composition includes combining a solvent and a phosphate ester and mixing these to form a solution. A source of metal ions is then added to the solution. The metal in the source of metal ions is selected from the group consisting of metals with an oxidation state of +3 or +4. The product is then is combined with a diene rubber composition to form a useful article, such as the tread of a tire.
摘要翻译： 组合物包括二烯橡胶和下式的金属磷酸酯：M是具有+3或+4的氧化态的金属，R 1和R 2独立地选自包括氢的任何有机部分，除了R 1和R 2不能都是 是氢。 此外，制备橡胶组合物的方法包括混合溶剂和磷酸酯并将其混合以形成溶液。 然后将金属离子源加入溶液中。 金属离子源中的金属选自氧化态为+3或+4的金属。 然后将产物与二烯橡胶组合物组合以形成有用的制品，例如轮胎的胎面。
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2.发明申请Multiple-Acid-Derived Metal Soaps Incorporated In Rubber Compositions And Method For Incorporating Such Soaps In Rubber Compositions 有权掺入橡胶组合物中的多酸衍生的金属皂以及在橡胶组合物中掺入这种皂的方法公开(公告)号：US20110039994A1
公开(公告)日：2011-02-17
申请号：US12827361
申请日：2010-06-30
CPC分类号： C08L9/06 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08K5/0091 , C08K5/098 , C08K13/02 , C08L33/064 , Y10T152/10
摘要： A composition includes a polymer matrix, a multiple-acid-derived metal soap, wherein the metal has an oxidation state of +3 or +4. An associated method for making a rubber composition includes the steps of: combining a solvent and a multiple carboxylic, phosphonic, phosphoric, sulfuric, or sulfonic acid, or mixtures thereof, and mixing to form solution A; adding a source of metal ions to solution A and mixing to form a product A, the metal being selected from the metals having an oxidation state of +3 or +4, whereby product A includes a multiple-acid-derived metal soap; and combining the multiple-acid-derived metal soap with a diene rubber. A method of making a tire component includes the steps of: combining a solvent and a multiple carboxylic, phosphonic, phosphoric, sulfuric, or sulfonic acid, or mixtures thereof, and mixing to form solution A; adding a source of metal ions to solution A and mixing to form a product A, the metal being selected from the metals having an oxidation state of +3 or +4, whereby product A includes a multiple-acid-derived metal soap; combining the multiple-acid-derived metal soap with a diene rubber; and molding and vulcanizing the rubber composition into a tire component.
摘要翻译： 组合物包括聚合物基质，多酸衍生的金属皂，其中金属具有+3或+4的氧化态。 制备橡胶组合物的相关方法包括以下步骤：将溶剂与多种羧酸，膦酸，磷酸，硫酸或磺酸或其混合物混合并混合以形成溶液A; 向溶液A中加入金属离子源，混合形成产物A，金属选自氧化态为+3或+4的金属，由此产物A包括多酸衍生的金属皂; 并将多酸衍生的金属皂与二烯橡胶组合。 制造轮胎部件的方法包括以下步骤：将溶剂与多种羧酸，膦酸，磷酸，硫酸或磺酸或其混合物混合并混合以形成溶液A; 向溶液A中加入金属离子源，混合形成产物A，金属选自氧化态为+3或+4的金属，由此产物A包括多酸衍生的金属皂; 将多酸衍生金属皂与二烯橡胶组合; 并将橡胶组合物成型和硫化成轮胎部件。
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3.发明授权Gels derived from polypropylene grafted alkyl vinylether-maleimide copolymers 失效由聚丙烯接枝的烷基乙烯基 - 马来酰亚胺共聚物得到的凝胶公开(公告)号：US06191217B1
公开(公告)日：2001-02-20
申请号：US09193591
申请日：1998-11-17
IPC分类号： C08G6348
CPC分类号： C08G81/021
摘要： The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkyl vinylether-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkyl vinylether-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkyl vinylether-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.
摘要翻译： 本发明教导了一种能够形成高阻尼软聚合物凝胶的方法。 该方法包括：在基本上干燥的条件下使聚（烷基乙烯基醚 - 共 - 马来酰亚胺）聚合物与马来化的聚亚烷基和烷基二胺反应，以足以形成聚亚烷基接枝的聚（烷基乙烯基醚 - 共 - 马来酰亚胺）聚合物产物; 并且将聚亚烷基接枝的聚（烷基乙烯醚 - 共 - 马来酰亚胺）聚合物产物与足以形成凝胶的增量油分散。 本发明还考虑了由聚合物凝胶组合物制成的聚合物凝胶组合物，聚合物组合物和制品。
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4.发明授权Gels derived from extending grafted comb polymers and polypropylene via a solution synthesis 失效通过溶液合成从延伸的接枝梳状聚合物和聚丙烯衍生的凝胶
公开(公告)号：US6107409A
公开(公告)日：2000-08-22
申请号：US73739
申请日：1998-05-06
CPC分类号： C08F8/32 , C08G81/021
摘要： The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting in a suitable solvent a poly(alkenyl benzene-co-maleic anhydride) and a primary amine to form a poly(alkenyl benzene-co-maleimide) polymer. The poly(alkenyl benzene-co-maleimide) polymer while remaining in solvent is grafted with a maleated polyalkylene through the use of a grafting agent such as an alkyl diamine to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product. The solvent is then removed from the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product and the polymer is mixed with extender such as oil sufficient to form the gel. During oil extension the graft copolymer is further crosslinked due to the presence of additional alkyl diamine.
摘要翻译： 本发明教导了一种能够形成高阻尼软聚合物凝胶的方法。 该方法包括：在合适的溶剂中使聚（烯基苯 - 共 - 马来酸酐）和伯胺反应形成聚（烯基苯 - 共 - 马来酰亚胺）聚合物。 保留在溶剂中的聚（烯基苯 - 共 - 马来酰亚胺）聚合物通过使用接枝剂如烷基二胺与马来化的聚亚烷基二胺接枝以形成聚亚烷基接枝的聚（烯基苯 - 共 - 马来酰亚胺）聚合物产物。 然后从聚亚烷基接枝的聚（烯基苯 - 共 - 马来酰亚胺）聚合物产物中除去溶剂，并将聚合物与足以形成凝胶的增量剂如油混合。 在油延伸期间，由于存在另外的烷基二胺，接枝共聚物进一步交联。
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公开(公告)号：US06476117B1
公开(公告)日：2002-11-05
申请号：US09586873
申请日：2000-06-05
IPC分类号： C08L2326
CPC分类号： C08F8/00 , C08F297/00
摘要： Thermoplastic elastomers containing hard segments formed from polyalkylenes and soft segments formed from elastomeric polymers near their gelation point are formed. Compositions containing these materials are elastomeric and exhibit excellent damping capabilities over a wide range of temperatures and frequencies.
摘要翻译： 形成包含由聚烯烃形成的硬链段和在其凝胶化点附近由弹性体聚合物形成的软链段的热塑性弹性体。 含有这些材料的组合物是弹性体，并且在宽范围的温度和频率下表现出优异的阻尼能力。
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6.发明授权Multiple-acid-derived metal soaps incorporated in rubber compositions and method for incorporating such soaps in rubber compositions 有权掺入橡胶组合物中的多酸衍生金属皂和在橡胶组合物中掺入这种肥皂的方法公开(公告)号：US08389609B2
公开(公告)日：2013-03-05
申请号：US12827361
申请日：2010-06-30
IPC分类号： C08G18/48
CPC分类号： C08L9/06 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08K5/0091 , C08K5/098 , C08K13/02 , C08L33/064 , Y10T152/10
摘要： A composition includes a polymer matrix, a multiple-acid-derived metal soap, wherein the metal has an oxidation state of +3 or +4. An associated method for making a rubber composition includes the steps of: combining a solvent and a multiple carboxylic, phosphonic, phosphoric, sulfuric, or sulfonic acid, or mixtures thereof, and mixing to form solution A; adding a source of metal ions to solution A and mixing to form a product A, the metal being selected from the metals having an oxidation state of +3 or +4, whereby product A includes a multiple-acid-derived metal soap; and combining the multiple-acid-derived metal soap with a diene rubber. A method of making a tire component includes the steps of: combining a solvent and a multiple carboxylic, phosphonic, phosphoric, sulfuric, or sulfonic acid, or mixtures thereof, and mixing to form solution A; adding a source of metal ions to solution A and mixing to form a product A, the metal being selected from the metals having an oxidation state of +3 or +4, whereby product A includes a multiple-acid-derived metal soap; combining the multiple-acid-derived metal soap with a diene rubber; and molding and vulcanizing the rubber composition into a tire component.
摘要翻译： 组合物包括聚合物基质，多酸衍生的金属皂，其中金属具有+3或+4的氧化态。 制备橡胶组合物的相关方法包括以下步骤：将溶剂与多种羧酸，膦酸，磷酸，硫酸或磺酸或其混合物混合并混合以形成溶液A; 向溶液A中加入金属离子源，混合形成产物A，金属选自氧化态为+3或+4的金属，由此产物A包括多酸衍生的金属皂; 并将多酸衍生的金属皂与二烯橡胶组合。 制造轮胎部件的方法包括以下步骤：将溶剂与多种羧酸，膦酸，磷酸，硫酸或磺酸或其混合物混合并混合以形成溶液A; 向溶液A中加入金属离子源，混合形成产物A，金属选自氧化态为+3或+4的金属，由此产物A包括多酸衍生的金属皂; 将多酸衍生金属皂与二烯橡胶组合; 并将橡胶组合物成型和硫化成轮胎部件。
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公开(公告)号：US08063142B2
公开(公告)日：2011-11-22
申请号：US10791049
申请日：2004-03-02
申请人： Xiaorong Wang , Victor J. Foltz
发明人： Xiaorong Wang , Victor J. Foltz
IPC分类号： C08L53/02
CPC分类号： C08L21/00 , B82Y40/00 , C08F279/02 , C08L23/26 , C08L51/04 , C08L53/02 , Y10T428/2998 , C08L2666/24 , C08F212/36
摘要： A process for forming a nanoparticle composition is provided. The process includes polymerizing conjugated diene monomer in a hydrocarbon solvent to form a first reaction mixture, and charging excess alkenylbenzense monomer and anionic catalyst to form mono-block and diblock polymers. Micelles of said mono-block and diblock polymers are formed, and at least one crosslinking agent is added to cross-link the micelles and form nanoparticles. The nanoparticles preferably have a poly(alkenylbenzene) core and an outer layer including monomer units selected from the group consisting of conjugated dienes, alkenylbenzenes, alkylenes, and mixtures thereof, and a size distribution of between about 1 and 1000 nm.
摘要翻译： 提供了形成纳米颗粒组合物的方法。 该方法包括在烃溶剂中聚合共轭二烯单体以形成第一反应混合物，并加入过量的链烯基苯基单体和阴离子催化剂以形成单嵌段和二嵌段聚合物。 形成所述单嵌段和二嵌段聚合物的胶束，并加入至少一种交联剂以交联胶束并形成纳米颗粒。 纳米颗粒优选具有聚（烯基苯）核，外层包括选自共轭二烯，烯基苯，亚烷基及其混合物的单体单元，其尺寸分布在约1nm至1000nm之间。
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公开(公告)号：US07601772B2
公开(公告)日：2009-10-13
申请号：US11642190
申请日：2006-12-20
IPC分类号： C08K9/04
摘要： The present invention provides a nano-composite comprising a clay and a cationic mediator comprised of a hydrophobic unit and a cationic unit. The clay is exfoliated or intercalated by the cationic mediator. The present invention further provides a polymer formulation comprising the nano-composite. The nano-composite is practically useful in formulating compositions such as rubber and tire products with improved and well-balanced properties including gas permeability, cure properties, and/or mechanical properties etc.
摘要翻译： 本发明提供一种包含粘土和由疏水单元和阳离子单元组成的阳离子介体的纳米复合材料。 粘土被阳离子介质剥离或嵌入。 本发明还提供了包含纳米复合材料的聚合物制剂。 纳米复合材料实际上可用于配制诸如橡胶和轮胎产品的组合物，其具有改进的良好平衡的性能，包括气体渗透性，固化性能和/或机械性能等。
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公开(公告)号：US07041734B2
公开(公告)日：2006-05-09
申请号：US10855998
申请日：2004-05-28
申请人： Xiaorong Wang , Victor J. Foltz
发明人： Xiaorong Wang , Victor J. Foltz
IPC分类号： C08L51/08
CPC分类号： C08L53/00 , C08L53/025 , C08L2666/02
摘要： A gel composition that is the combination of or reaction product of ingredients comprising a thermoplastic elastomer copolymer comprising polystyrene-b-poly(ethylene-ethylene/propylene)-b-polystyrene, a nylon-grafted elastomer, and an extender.
摘要翻译： 作为包含聚苯乙烯-b-聚（乙烯 - 乙烯/丙烯）-b-聚苯乙烯，尼龙接枝弹性体和增量剂的热塑性弹性体共聚物的成分的组合或成分的组合的凝胶组合物。
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公开(公告)号：US06706823B2
公开(公告)日：2004-03-16
申请号：US10039008
申请日：2001-12-31
申请人： Xiaorong Wang , Victor J. Foltz , James E. Hall
发明人： Xiaorong Wang , Victor J. Foltz , James E. Hall
IPC分类号： C08L7908
摘要： A conductive polymer gel composition including a copolymer with alkenyl monomer units and maleimide monomer units, a crosslinking agent, and an electrolyte solution. The conductive polymer has a current resistance less than or equal to 10−4 ohms and can be used to provide electrolyte cells.
摘要翻译： 包含具有烯基单体单元和马来酰亚胺单体单元的共聚物的导电聚合物凝胶组合物，交联剂和电解质溶液。 导电聚合物的电流电阻小于或等于10 -4欧姆，可用于提供电解质电池。
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