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公开(公告)号：US07488774B2
公开(公告)日：2009-02-10
申请号：US11384737
申请日：2006-03-20
申请人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
发明人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
CPC分类号： C08F279/04
摘要： A continuous process for producing high impact polystyrene comprising feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture, polymerizing the reaction mixture in said linear flow reactor to at least the phase inversion point of the mixture, and feeding the reaction mixture from the first linear flow reactor to a second reactor for post-inversion polymerization of the mixture. A method of producing an elastomer-reinforced polymer comprising inverting a reaction mixture comprising at least one vinyl aromatic monomer, an elastomer, and a free radical initiator in a plug flow reactor. A high impact polystyrene reactor system, comprising a linear flow reactor having an inlet and an outlet, and a continuously stirred tank reactor having an inlet in fluid communication with the linear flow reactor outlet and receiving an effluent from the linear flow reactor.
摘要翻译： 一种用于生产高抗冲聚苯乙烯的连续方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物，将所述线性流动反应器中的反应混合物聚合至至少 混合物的相转化点，并将反应混合物从第一线性流动反应器进料到第二反应器用于混合物的反转后聚合。 一种生产弹性体增强聚合物的方法，包括在活塞流反应器中使包含至少一种乙烯基芳族单体，弹性体和自由基引发剂的反应混合物倒置。 一种高抗冲聚苯乙烯反应器系统，包括具有入口和出口的线性流动反应器和连续搅拌的罐式反应器，其具有与线性流动反应器出口流体连通的入口并接收来自线性流动反应器的流出物。
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公开(公告)号：US20060257293A1
公开(公告)日：2006-11-16
申请号：US11128803
申请日：2005-05-13
申请人： Thanh Nguyen , Jay Reimers
发明人： Thanh Nguyen , Jay Reimers
IPC分类号： B01J19/00
CPC分类号： B01J19/18 , B01F7/00291 , B01F7/00633 , B01F15/066 , B01J2219/00063 , B01J2219/00081 , B01J2219/00094 , B01J2219/002 , B01J2219/00238 , F28D7/0066 , F28D7/0091
摘要： A plug flow reactor having an inner shell 27 surrounded by outer shell 21 and having at least one annular flow passage 35 therebetween can be used to prepare compositions, including polymers. The plug flow reactor also includes inlet port 36, an outlet port 37 and a plurality of exchanger tubes 26 wherein the exchanger tubes are in fluid communication to the at least one annular flow passage. Polystyrene and high impact polystyrene can be prepared using the reactor.
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公开(公告)号：US20070142594A1
公开(公告)日：2007-06-21
申请号：US11384596
申请日：2006-03-20
IPC分类号： C08F136/00
CPC分类号： C08F279/02 , B01F7/045 , B01J10/002 , B01J19/0013 , B01J19/0066 , B01J19/1818 , B01J2219/00128 , B01J2219/00243 , B01J2219/182 , C08L51/04 , F28C3/06 , C08L2666/02
摘要： A method for removing heat from a horizontal linear flow reactor, comprising introducing vapor bubbles into a liquid medium in the reactor and removing the vapor from the reactor. A method of producing an elastomer reinforced polymer comprising autorefrigerating the reactants in a horizontal linear flow reactor in which both initial polymerization and phase inversion occur. A method of removing heat from a horizontal plug flow reactor comprising aerating the reactants within the reactor, wherein the aeration promotes radial mixing of the reactants but does not substantially promote axial mixing of the reactants. A horizontal linear flow reactor, comprising a horizontal reaction chamber having one or more mechanical flow facilitators disposed therein and a sparger attached to the bottom of at least a portion of the reaction chamber.
摘要翻译： 一种用于从水平线性流动反应器中除去热量的方法，包括将蒸汽气泡引入反应器中的液体介质中并从反应器中除去蒸汽。 一种制备弹性体增强聚合物的方法，包括在初始聚合和相转化都发生的水平线性流动反应器中自动制冷反应物。 一种从卧式活塞式流动反应器中除去热的方法，包括使反应器内的反应物充气，其中曝气促进反应物的径向混合，但基本上不促进反应物的轴向混合。 一种水平线性流动反应器，包括具有一个或多个机械流动促进器的水平反应室，以及附着在反应室的至少一部分的底部的分布器。
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公开(公告)号：US08192695B2
公开(公告)日：2012-06-05
申请号：US11121795
申请日：2005-05-04
申请人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
发明人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
CPC分类号： B01J10/002 , B01F3/04531 , B01F7/001 , B01F7/00241 , B01F7/00275 , B01F7/00633 , B01F7/183 , B01F15/00883 , B01F15/00915 , B01J19/006 , B01J19/0066 , B01J2219/00777 , B01J2219/00779
摘要： Disclosed is a reactor or sparging vessel suitable for use for reaction mixtures containing vapor and/or gas bubbles. It comprises a mechanical agitation means suitable to redistribute flow radially and at least one perforated plate suitable to provide resistance to axial flow. In desirable embodiments it may include at least one electrically or hydraulically-stimulated rotatable shaft upon which at least one blade impeller is mounted, and at least one perforated plate oriented such that it provides resistance to axial flow. The perforated plate may have channels therethrough whose cross-sectional dimension is smaller than the projected average diameter of the vapor and/or gas bubbles. The reactor or sparging vessel offers improved flow dynamics, including reduced back mixing and narrowed residence time distribution. A method of employing the reactor for a reaction mixture containing vapor and/or gas bubbles is also disclosed. An impeller blade having two curvatures is also disclosed.
摘要翻译： 公开了适用于含有蒸气和/或气泡的反应混合物的反应器或喷射容器。 它包括适于重新分布流动的机械搅拌装置和适于提供对轴向流动的阻力的至少一个多孔板。 在理想的实施例中，其可以包括至少一个电或液压刺激的可旋转轴，至少一个叶片叶轮安装在该可旋转轴上，并且至少一个多孔板定向成使得其提供对轴向流动的阻力。 多孔板可以具有通道，其横截面尺寸小于蒸气和/或气泡的投影平均直径。 反应器或喷射容器提供改善的流动动力学，包括减少后混合和缩短的停留时间分布。 还公开了使用反应器用于含有蒸汽和/或气泡的反应混合物的方法。 还公开了具有两个曲率的叶轮叶片。
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公开(公告)号：US20070142549A1
公开(公告)日：2007-06-21
申请号：US11384737
申请日：2006-03-20
申请人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
发明人： Doug Berti , Aron Griffith , Jay Reimers , Thanh Nguyen
IPC分类号： C08F297/08
CPC分类号： C08F279/04
摘要： A continuous process for producing high impact polystyrene comprising feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture, polymerizing the reaction mixture in said linear flow reactor to at least the phase inversion point of the mixture, and feeding the reaction mixture from the first linear flow reactor to a second reactor for post-inversion polymerization of the mixture. A method of producing an elastomer-reinforced polymer comprising inverting a reaction mixture comprising at least one vinyl aromatic monomer, an elastomer, and a free radical initiator in a plug flow reactor. A high impact polystyrene reactor system, comprising a linear flow reactor having an inlet and an outlet, and a continuously stirred tank reactor having an inlet in fluid communication with the linear flow reactor outlet and receiving an effluent from the linear flow reactor.
摘要翻译： 一种用于生产高抗冲聚苯乙烯的连续方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物，将所述线性流动反应器中的反应混合物聚合至至少 混合物的相转化点，并将反应混合物从第一线性流动反应器进料到第二反应器用于混合物的反转后聚合。 一种生产弹性体增强聚合物的方法，包括在活塞流反应器中使包含至少一种乙烯基芳族单体，弹性体和自由基引发剂的反应混合物倒置。 一种高抗冲聚苯乙烯反应器系统，包括具有入口和出口的线性流动反应器和连续搅拌的罐式反应器，其具有与线性流动反应器出口流体连通的入口并接收来自线性流动反应器的流出物。
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公开(公告)号：US20060251554A1
公开(公告)日：2006-11-09
申请号：US11121795
申请日：2005-05-04
申请人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
发明人： Laurent Doucet , Philippe Tanguy , Doug Berti , Thanh Nguyen , Guillaume Franc , Jay Reimers
CPC分类号： B01J10/002 , B01F3/04531 , B01F7/001 , B01F7/00241 , B01F7/00275 , B01F7/00633 , B01F7/183 , B01F15/00883 , B01F15/00915 , B01J19/006 , B01J19/0066 , B01J2219/00777 , B01J2219/00779
摘要： Disclosed is a reactor or sparging vessel suitable for use for reaction mixtures containing vapor and/or gas bubbles. It comprises a mechanical agitation means suitable to redistribute flow radially and at least one perforated plate suitable to provide resistance to axial flow. In desirable embodiments it may include at least one electrically or hydraulically-stimulated rotatable shaft upon which at least one blade impeller is mounted, and at least one perforated plate oriented such that it provides resistance to axial flow. The perforated plate may have channels therethrough whose cross-sectional dimension is smaller than the projected average diameter of the vapor and/or gas bubbles. The reactor or sparging vessel offers improved flow dynamics, including reduced back mixing and narrowed residence time distribution. A method of employing the reactor for a reaction mixture containing vapor and/or gas bubbles is also disclosed. An impeller blade having two curvatures is also disclosed.
摘要翻译： 公开了适用于含有蒸气和/或气泡的反应混合物的反应器或喷射容器。 它包括适于重新分布流动的机械搅拌装置和适于提供对轴向流动的阻力的至少一个多孔板。 在理想的实施例中，其可以包括至少一个电或液压刺激的可旋转轴，至少一个叶片叶轮安装在该可旋转轴上，并且至少一个多孔板定向成使得其提供对轴向流动的阻力。 多孔板可以具有通道，其横截面尺寸小于蒸气和/或气泡的投影平均直径。 反应器或喷射容器提供改善的流动动力学，包括减少后混合和缩短的停留时间分布。 还公开了使用反应器用于含有蒸气和/或气泡的反应混合物的方法。 还公开了具有两个曲率的叶轮叶片。
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公开(公告)号：US06864331B1
公开(公告)日：2005-03-08
申请号：US10731729
申请日：2003-12-09
申请人： Jay Reimers , Thanh Nguyen
发明人： Jay Reimers , Thanh Nguyen
CPC分类号： B01J19/0006 , B01J2219/00191 , C08F2/00 , G01N21/3563 , G01N21/359
摘要： Disclosed is a process for preparing a polymer. The process includes at least one process stream and the process stream has at least one characteristic of interest. The process further includes passing the process stream past a sensor probe connected to a near-IR spectrophotometer and passing light from a light source through the probe and into the spectrometer wherein the light source, spectrometer and sensor probe are connected by a fiber optic cable. The effect of the interaction of the process stream and the light passing through the senor probe is measured and used to define a value for the characteristic of interest. The value for the characteristic of interest is a component of an algorithm and the algorithm is used, in real time, to monitor, control, or monitor and control the process for preparing a polymer.
摘要翻译： 公开了一种制备聚合物的方法。 该方法包括至少一个工艺流，并且工艺流具有至少一个感兴趣的特性。 该方法还包括使工艺流通过连接到近红外分光光度计的传感器探针，并将来自光源的光通过探针并进入光谱仪，其中光源，光谱仪和传感器探针通过光纤电缆连接。 测量过程流和通过传感器探头的光的相互作用的影响并用于定义感兴趣特征的值。 感兴趣的特征值是算法的一个组成部分，并且实时地使用该算法来监视，控制或监视和控制聚合物的制备过程。
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公开(公告)号：US07396879B2
公开(公告)日：2008-07-08
申请号：US11062369
申请日：2005-02-22
申请人： Jay Reimers
发明人： Jay Reimers
CPC分类号： C08F6/006
摘要： Residual monomer in a polymer matrix may be reduced by a method including admixing a polymer matrix comprising an amount of residual monomer and a conjugated diene. This method can be carried out under reaction conditions such that the amount of residual monomer is reduced. The monomer comprises at least one electron withdrawing substituent and the conjugated diene comprises at least one electron donating substituent. This method is particularly useful for reducing the amount of residual styrene monomer in polystyrene homopolymer and copolymer compositions.
摘要翻译： 聚合物基质中的残余单体可以通过包括混合包含一定量残余单体和共轭二烯的聚合物基质的方法来还原。 该方法可以在反应条件下进行，使得残留单体的量减少。 单体包含至少一个吸电子取代基，共轭二烯包含至少一个给电子取代基。 该方法对于降低聚苯乙烯均聚物和共聚物组合物中残留苯乙烯单体的量是特别有用的。
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公开(公告)号：US07332058B2
公开(公告)日：2008-02-19
申请号：US10632213
申请日：2003-07-31
申请人： Jay Reimers
发明人： Jay Reimers
CPC分类号： B01D1/06 , B01D1/0011 , C08F6/001 , Y10S159/10 , Y10S159/15 , Y10S159/32
摘要： Disclosed is a process for devolatilizing a polymer including passing the polymer through a devolatizer including a plate heat exchanger wherein the plates of the plate heat exchanger are heated by a plurality of heating tubes and wherein the heating tube including a return tube nested inside of a supply tube. The use of the disclosed invention allows for a comparatively small heat profile across heating plates as compared to prior art plate heat exchangers.
摘要翻译： 公开了一种使聚合物脱挥发分的方法，包括使聚合物通过包括板式热交换器的脱挥器，其中板式换热器的板被多个加热管加热，并且其中加热管包括嵌套在供应源内的回流管 管。 与现有技术的板式换热器相比，使用所公开的发明允许加热板上的相对较小的热分布。
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10.发明申请公开(公告)号：US20070032562A1
公开(公告)日：2007-02-08
申请号：US11198542
申请日：2005-08-04
申请人： Jose Sosa , Jay Reimers
发明人： Jose Sosa , Jay Reimers
IPC分类号： C08F2/50
CPC分类号： C08F2/48 , C08F112/08 , C08F279/02 , C08F212/08
摘要： A method for the production of a vinyl aromatic polymer through the use of a supported light-induced photoreductant. A reactor is provided which contains a catalyst bed comprising a light-induced photoreductant component supported on a particulate substrate forming a permeable catalyst bed. A reaction stream comprising a vinyl aromatic monomer, a soluble reductant, and a transition metal salt is introduced into the reactor and passed through the catalyst bed. In addition, a gaseous oxidizing agent is introduced into the reactor and flowed through the catalyst bed and into contact with the reaction stream. The catalyst bed is irradiated with electromagnetic radiation in the ultraviolet or visible light range at an intensity sufficient to activate the photoreductant component and produce a free radical to initiate polymerization of the vinyl aromatic monomer to form a corresponding vinyl aromatic polymer. The vinyl aromatic polymer is then recovered from the reactor. The photoreductant component is a photoreductant dye, such as a group consisting of acridine, methylene blue, rose bengal, tetraphenylporphine, A protoporphyrin, A phthalocyanine and eosin-y and erythrosin-b. The transition metal salt may be an iron, cobalt or manganese salt and the soluble reductant is selected from the group consisting of diethanolamine, thiodiethanol, triethanolamine, benzoin, ascorbic acid, ester, glyoxal trimer and toluene sulfinic acid.
摘要翻译： 一种通过使用支撑的光诱导的光致感光体制备乙烯基芳族聚合物的方法。 提供了一种反应器，其包含催化剂床，所述催化剂床包含负载在形成可渗透催化剂床的颗粒基质上的光诱导的光致反应物组分。 将包含乙烯基芳族单体，可溶还原剂和过渡金属盐的反应物流引入反应器并通过催化剂床。 另外，将气态氧化剂引入反应器中并流过催化剂床并与反应物流接触。 催化剂床在紫外线或可见光范围内用电磁辐射照射，其强度足以激活光致感光体组分并产生自由基以引发乙烯基芳族单体的聚合以形成相应的乙烯基芳族聚合物。 然后从反应器中回收乙烯基芳族聚合物。 光致感光成分是光致感染染料，如吖啶，亚甲基蓝，玫瑰红，四苯基卟吩，原卟啉，A酞菁，曙红，红蛋白b组成的组。 过渡金属盐可以是铁，钴或锰盐，可溶性还原剂选自二乙醇胺，硫代二乙醇，三乙醇胺，苯偶姻，抗坏血酸，酯，乙二醛三聚体和甲苯亚磺酸。
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