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公开(公告)号：US5463042A
公开(公告)日：1995-10-31
申请号：US186109
申请日：1994-01-25
CPC分类号： C10G27/10 , B01J31/1616 , B01J31/183 , B01J31/403 , C09B47/045 , B01J2231/70 , B01J2531/025 , B01J2531/845 , B01J2531/847 , B01J2540/12 , B01J2540/32 , Y02P20/584
摘要： A layered double hydroxide intercalated with a metal complex of a polyaryl compound is described. A preferred complex is porphin or phthylocyanine. The metals are preferably selected from Group VII-B and Group VIII cobalt and iron triads. The resulting LDH metal complexes are useful for the oxidation of oxidate compounds such as thiols and phenols.
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公开(公告)号：US5459259A
公开(公告)日：1995-10-17
申请号：US186127
申请日：1994-01-25
CPC分类号： C10G27/10 , B01J31/1616 , B01J31/183 , B01J31/403 , C09B47/045 , B01J2231/70 , B01J2531/025 , B01J2531/845 , B01J2531/847 , B01J2540/12 , B01J2540/32 , Y02P20/584
摘要： A layered double hydroxide intercalated with a metal complex of a polyaryl compound is described. A preferred complex is porphin or phthylocyanine. The metals are preferably selected from Group VII-B and Group VIII cobalt and iron triads. The resulting LDH metal complexes are useful for the oxidation of oxidate compounds such as thiols and phenols.
摘要翻译： 描述了嵌入多芳基化合物的金属络合物的层状双氢氧化物。 优选的复合物是卟吩或phthylocyanine。 金属优选选自VII-B族和VIII族钴和铁三元组。 所得的LDH金属络合物可用于氧化化合物如硫醇和酚。
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公开(公告)号：US5302709A
公开(公告)日：1994-04-12
申请号：US981603
申请日：1992-11-25
CPC分类号： C10G27/10 , B01J31/1616 , B01J31/183 , B01J31/403 , C09B47/045 , B01J2231/70 , B01J2531/025 , B01J2531/845 , B01J2531/847 , B01J2540/12 , B01J2540/32 , Y02P20/584
摘要： A layered double hydroxide intercalated with a metal complex of a polyaryl compound is described. A preferred complex is porphin or phthylocyanine. The metals are preferably selected from Group VII-B and Group VIII cobalt and iron triads. The resulting LDH metal complexes are useful for the oxidation of oxidate compounds such as thiols and phenols.
摘要翻译： 描述了嵌入多芳基化合物的金属络合物的层状双氢氧化物。 优选的复合物是卟吩或phthylocyanine。 金属优选选自VII-B族和VIII族钴和铁三元组。 所得的LDH金属络合物可用于氧化化合物如硫醇和酚。
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公开(公告)号：US5453526A
公开(公告)日：1995-09-26
申请号：US188899
申请日：1994-01-31
CPC分类号： C10G27/10 , B01J31/1616 , B01J31/183 , B01J31/403 , C09B47/045 , B01J2231/70 , B01J2531/025 , B01J2531/845 , B01J2531/847 , B01J2540/12 , B01J2540/32 , Y02P20/584
摘要： A layered double hydroxide intercalated with a metal complex of a polyaryl compound is described. A preferred complex is porphin or phthylocyanine. The metals are preferably selected from Group VII-B and Group VIII cobalt and iron triads. The resulting LDH metal complexes are useful for the oxidation of oxidate compounds such as thiols and phenols.
摘要翻译： 描述了嵌入多芳基化合物的金属络合物的层状双氢氧化物。 优选的复合物是卟吩或phthylocyanine。 金属优选选自VII-B族和VIII族钴和铁三元组。 所得的LDH金属络合物可用于氧化化合物如硫醇和酚。
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公开(公告)号：US5414080A
公开(公告)日：1995-05-09
申请号：US186111
申请日：1994-01-25
CPC分类号： C10G27/10 , B01J31/1616 , B01J31/183 , B01J31/403 , C09B47/045 , B01J2231/70 , B01J2531/025 , B01J2531/845 , B01J2531/847 , B01J2540/12 , B01J2540/32 , Y02P20/584
摘要： A layered double hydroxide intercalated with a metal complex of a polyaryl compound is described. A preferred complex is porphin or phthylocyanine. The metals are preferably selected from Group VII-B and Group VIII cobalt and iron triads. The resulting LDH metal complexes are useful for the oxidation of oxidate compounds such as thiols and phenols.
摘要翻译： 描述了嵌入多芳基化合物的金属络合物的层状双氢氧化物。 优选的复合物是卟吩或phthylocyanine。 金属优选选自VII-B族和VIII族钴和铁三元组。 所得的LDH金属络合物可用于氧化化合物如硫醇和酚。
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6.发明授权公开(公告)号：US06391278B1
公开(公告)日：2002-05-21
申请号：US09246739
申请日：1999-02-08
IPC分类号： C01B3344
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X−I+ templating pathway (Pathway 3) and mild reaction conditions.
摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合 同时通过简单的溶剂萃取提供中性模板的简便回收。 中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。 此外，使用介导的S + X-I +模板途径（途径3）和温和的反应条件，已经制备了类似于MCM-41的六方晶过渡金属取代的催化剂。
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7.发明授权
公开(公告)号：US5855864A
公开(公告)日：1999-01-05
申请号：US798066
申请日：1997-02-11
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B33/38 , C01B33/44 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06 , C07C46/08 , C07C50/02 , C01B33/26
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S.degree.) and neutral inorganic precursors (I.degree.) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 .ANG., small elementary particle size (.ltoreq.400 .ANG.), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I.degree.) with neutral diamine surfactants (S.degree.-S.degree.) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S.sup.+ X.sup.- I.sup.+ templating pathway (Pathway 3) and mild reaction conditions.These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 .ANG.) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S DEG）和中性无机前体（I DEG）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 这种模板方法允许制备六角形或六边形状的介孔氧化催化剂，其具有至少约17安培，小的基本粒度（
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8.发明授权
公开(公告)号：US5712402A
公开(公告)日：1998-01-27
申请号：US409173
申请日：1995-03-23
IPC分类号： B01J29/03 , B01J29/04 , B01J29/89 , B01J37/03 , C01B33/20 , C01B33/38 , C01B33/44 , C01B37/00 , C01B37/02 , C01B39/04 , C07C46/06 , C07C46/08 , C07C50/02
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S.degree.) and neutral inorganic precursors (I.degree.) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 .ANG., small elementary particle size (.ltoreq.400 .ANG.), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 .ANG.) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S DEG）和中性无机前体（I DEG）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 这种模板方法允许制备六角形或六边形状的介孔氧化催化剂，其具有至少约17安培，小的基本粒度（
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9.发明授权公开(公告)号：US06193943B1
公开(公告)日：2001-02-27
申请号：US08797718
申请日：1997-02-11
IPC分类号： C01B3338
CPC分类号： B01J21/04 , B01J21/066 , B01J23/14 , B01J29/0308 , B01J29/041 , B01J29/046 , B01J29/049 , B01J29/89 , B01J35/1061 , B01J37/03 , B01J37/036 , C01B33/20 , C01B37/00 , C01B37/005 , C01B37/02 , C07C46/06 , C07C46/08
摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X·I+ templating pathway (Pathway 3) and mild reaction conditions. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 Å) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.
摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合 同时通过简单的溶剂萃取提供中性模板的简便回收。 中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。 此外，已经使用介导的S + X.I +模板途径（途径3）和温和的反应条件制备了类似于MCM-41的六方晶过渡金属取代的催化剂。这些新的介孔金属硅酸盐分子筛显示出极好的催化活性 苯的过氧化羟基化和具有太大（大于6）的动力学直径的取代芳族化合物的氧化，以进入常规的微孔过渡金属取代的分子筛如钛和钒硅酸盐的孔结构。
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10.发明授权Process using recyclable sorbents for the removal of sox from flue gases and other gas streams 失效使用可回收的吸附剂从烟道气和其他气体流中除去黄油的方法
公开(公告)号：US5785938A
公开(公告)日：1998-07-28
申请号：US691424
申请日：1996-08-02
CPC分类号： B01J20/06 , B01D53/508 , C01B17/78
摘要： A process for removing and then capturing noxious sulfur oxides from gas streams, particularly from the flue gases of coal-burning power plants, using Ni-containing heated layered double hydroxide (LDH) as recyclable sorbents. The sorbent compositions contain metal components that form stable metal sulfites and sulfates at one temperature, but are decomposed at a higher temperature to regenerate the sorbent material.
摘要翻译： 使用含Ni加热的层状双氢氧化物（LDH）作为可回收的吸附剂，从煤气流，特别是燃煤发电厂的废气中除去并随后捕集有毒硫氧化物的方法。 吸附剂组合物包含在一个温度下形成稳定的金属亚硫酸盐和硫酸盐的金属组分，但在较高温度下分解以再生吸附剂材料。
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