Process for the preparation of polyamines and their use for the
preparation of polyurethanes
    3.
    发明授权
    Process for the preparation of polyamines and their use for the preparation of polyurethanes 失效
    制备多胺的方法及其用于制备聚氨酯的用途

    公开(公告)号:US4843107A

    公开(公告)日:1989-06-27

    申请号:US173204

    申请日:1988-03-24

    CPC分类号: C08G18/5048 C08G18/10

    摘要: Polyamines containing primary amino groups are made by a one-shot process for the hydrolysis of prepolymers containing isocyanate end groups and having an isocyanate content of from 0.5 to 40 weight % with 0.75 to 40 mol of water per equivalent of isocyanate groups in the presence of very small quantities of sodium hydroxide in certain organic, polar solvents. The compounds containing isocyanate groups used for this process are isocyanate prepolymers (preferably containing urethane groups). Hydrolysis according to this process leads directly to the polyamines with elimination of carbon dioxide. These polyamines may be isolated by the usual methods and the removal of the small quantities of catalyst may advantageously be omitted. These polyamines are useful for the preparation of polyurethane(urea)s.

    摘要翻译: 含有伯氨基的多胺通过一步法制备,用于水解包含异氰酸酯端基并且异氰酸酯含量为0.5至40重量%的预聚物,每当异氰酸酯基为0.75至40摩尔水时, 某些有机极性溶剂中极少量的氢氧化钠。 用于该方法的含有异氰酸酯基团的化合物是异氰酸酯预聚物(优选含有氨基甲酸酯基团)。 根据该方法的水解直接导致多胺消除二氧化碳。 这些多胺可以通过常规方法分离,并且可以有利地省略少量催化剂的去除。 这些多胺可用于制备聚氨酯(尿素)。

    Process for the production of polyamines
    5.
    发明授权
    Process for the production of polyamines 失效
    多胺生产工艺

    公开(公告)号:US4843108A

    公开(公告)日:1989-06-27

    申请号:US173350

    申请日:1988-03-24

    CPC分类号: C08G18/5048 C08G18/10

    摘要: Polyamines are produced by hydrolyzing isocyanate compounds having an NCO content of from 0.5 to 40 wt. % with from 0.75 to 40 moles of water per equivalent of NCO groups in the presence of from 0.021 to 0.099 wt. % sodium hydroxide and at least 10 wt. % water-miscible polar organic solvent containing nitrile, ketone, sulfoxide or ether groups having a boiling point of from 56.degree. to 250.degree. C. The reaction mixture is maintained in a homogeneous phase. The reaction is carried out at 40.degree. to 170.degree. C. These polyamines are useful in the production of polyurethane(urea)s.

    摘要翻译: 多胺通过水解NCO含量为0.5〜40重量%的异氰酸酯化合物来制造。 在0.021至0.099重量%的存在下,每当量NCO基团具有0.75至40摩尔水。 %氢氧化钠和至少10wt。 含有沸点为56〜250℃的腈,酮,亚砜或醚基的%水混溶性极性有机溶剂。将反应混合物保持在均匀相中。 反应在40℃至170℃下进行。这些多胺可用于生产聚氨酯(尿素)。

    Process for the preparation of highly elastic plastics
    6.
    发明授权
    Process for the preparation of highly elastic plastics 失效
    制备高弹性塑料的方法

    公开(公告)号:US5159046A

    公开(公告)日:1992-10-27

    申请号:US543649

    申请日:1990-06-26

    摘要: The present invention relates to a process for the preparation of a modified 1,5-naphthylene diisocyanate containing urea and biuret groups comprising reacting(a) 1,5-naphthylene diisocyanate in molten form with(b) a mixture comprising about 0.02 to about 0.5 mole of water per mole of 1,5-naphthylene diisocyanate and about 1 to about 10 parts for each part of water of an organic solvent.The present invention further relates to a process for the preparation of elastomeric moldings comprising reacting by the one-shot or prepolymer process at an isocyanate index of 70 to 130 a modified 1,5-naphthylene diisocyanate containing urea and biuret groups with compounds containing at least two isocyanate-reactive groups and having a molecular weight in the range from about 500 to about 10,000 and, optionally, organic compounds containing isocyanate-reactive groups and having a molecular weight in the range from 60 to 499.

    摘要翻译: 本发明涉及一种制备含脲和缩二脲基团的改性的1,5-亚萘基二异氰酸酯的方法,包括使(a)熔融形式的1,5-亚萘基二异氰酸酯与(b)约0.02至约0.5的混合物 摩尔水/摩尔1,5-亚萘基二异氰酸酯和约1至约10份的每份有机溶剂的水。 本发明还涉及一种制备弹性体模制品的方法,其包括通过一步或预聚物方法在异氰酸酯指数为70至130的情况下使含有脲和缩二脲基团的改性的1,5-亚萘基二异氰酸酯与至少含有化合物 两个异氰酸酯反应性基团,分子量在约500至约10,000的范围内,以及任选的含有异氰酸酯反应性基团并且分子量在60至499范围内的有机化合物。

    Process for the production of heat-resistant polyurethane urea elastomers
    7.
    发明授权
    Process for the production of heat-resistant polyurethane urea elastomers 失效
    生产耐热聚氨酯脲弹性体的方法

    公开(公告)号:US4882409A

    公开(公告)日:1989-11-21

    申请号:US245880

    申请日:1988-09-16

    IPC分类号: C08G18/10 C08G18/32

    摘要: The present invention is directed to a process for the production of a polyurethane urea elastomer which comprises preparing a heterogeneous mixture of(a) a diaminodiphenylurea corresponding to the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, represent hydrogen or a C.sub.1 -C.sub.6 alkyl radical and wherein the amino groups are in the meta and/or para position to the urea group and(b) polyisocyanates and NH.sub.2 -or OH-groups containing compounds or a NCO-terminated prepolymer prepared from a polyisocyanate and a polyhydroxyl compound having a molecular weight of 400 to about 10,000, and subsequently reacting the heterogeneous system to form a polyurethane urea elastomer by heating the mixture to a temperature below the melting point of said diaminodiphenylurea.The present invention is also directed to heterogeneous reaction mixtures based on the above diaminodiphenylureas suspended in the above NCO-terminated prepolymers.

    摘要翻译: 本发明涉及一种制备聚氨酯脲弹性体的方法,其包括制备(a)对应于式“IMAGE”的二氨基二苯脲的不均匀混合物,其中R 1,R 2,R 3和R 4可以相同或不同, 不同的,代表氢或C1-C6烷基,其中氨基位于脲基的间位和/或对位,和(b)含有多异氰酸酯和含NH 2或OH基的化合物或NCO封端的预聚物 来自多异氰酸酯和分子量为400至约10,000的多羟基化合物,随后通过将所述混合物加热至低于所述二氨基二苯基脲的熔点的温度,随后使所述非均相体系反应形成聚氨酯脲弹性体。 本发明还涉及基于悬浮在上述NCO封端的预聚物中的上述二氨基二苯基脲的不均匀反应混合物。

    Process for the preparation of polyurethane foams
    10.
    发明授权
    Process for the preparation of polyurethane foams 失效
    制备聚氨酯泡沫的方法

    公开(公告)号:US5017623A

    公开(公告)日:1991-05-21

    申请号:US396481

    申请日:1989-08-21

    摘要: This invention relates to a process for the preparation of polyurethane foams comprising reacting polyisocyanates with compounds containing at least two active hydrogen atoms and having a molecular weight of 400 to 10,000 selected from polymer-modified polyols and polyols containing predominantly primary hydroxyl groups, in the presence of water and/or organic blowing agents, catalysts, and flameproofing agents having the formula ##STR1## in which R.sup.1 and R.sup.2 are independently hydrogen or C.sub.1 -C.sub.4 alkyl;X is --(CH.sub.2).sub.n -- wherein n is an integer of from 0 to 5 (preferably 0 or 1), --CH.dbd.CH--, a branched alkylene group, an arylene group, or (NH).sub.m wherein m is 1 or 2;Y is --CN or ##STR2## wherein R.sup.1 and R.sup.2 are as defined above or both R.sup.2 together form a bond.The reaction is optionally carried out in the presence of other flameproofing agents, compounds containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight of 32 to 399, and known surface-active additives and auxiliaries.

    摘要翻译: 本发明涉及一种制备聚氨酯泡沫体的方法,其包括使多异氰酸酯与含有至少两个活性氢原子并且分子量为400至10,000的化合物反应,所述化合物在选自聚合物改性的多元醇和主要含伯羟基的多元醇中存在 的具有式“IMAGE”的水和/或有机发泡剂,催化剂和防火剂,其中R 1和R 2独立地是氢或C 1 -C 4烷基; X为 - (CH 2)n - ,其中n为0至5(优选0或1)的整数,-CH = CH-,支链亚烷基,亚芳基或(NH)m,其中m为1或 2; Y是-CN或,其中R 1和R 2如上所定义,或两个R 2一起形成键。 反应任选在其它防火剂,含有至少两个异氰酸酯反应性氢原子的化合物和分子量为32至399的化合物和已知的表面活性添加剂和助剂的存在下进行。