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公开(公告)号：US07776987B2
公开(公告)日：2010-08-17
申请号：US10566937
申请日：2004-09-03
IPC分类号： C08F110/02 , C08F8/00 , C08L23/00 , C08L23/04
CPC分类号： C09D123/08 , C08J5/18 , C08J2300/00 , C08J2323/06 , C08L23/06 , C08L23/08 , C08L23/0815 , C09D123/06 , C08L2666/06
摘要： A composition is disclosed which is particularly suited for use in extrusion coating. The composition comprises a polymeric material having a rheology such that the slope S of a natural log-natural log plot of loss modulus (or G″) versus storage modulus (or G′) is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.
摘要翻译： 公开了一种特别适用于挤出涂层的组合物。 组合物包含具有流变学性质的聚合材料，使得损耗模量（或G“）对储能模量（或G'）的自然对数 - 自然对数图的斜率S大于[0.635 *（熔体指数）+13.2 ] / [（熔体指数）+16.6]，其中聚合物材料的CDF RI分数低于GPC色谱图的0.23，其分子量高于85,000g / mol，且在 常规GPC分子量为1750,000g / mol以上。 当用于挤出涂布时，组合物显示减少的颈缩，并且颈缩不依赖于熔体强度，从而有助于改进挤出工艺。
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2.发明授权Blends of ethylenic polymers with improved modulus and melt strength and articles fabricated from these blends 有权具有改进的模量和熔体强度的乙烯类聚合物的共混物和由这些共混物制成的制品公开(公告)号：US06545094B2
公开(公告)日：2003-04-08
申请号：US09927908
申请日：2001-08-09
IPC分类号： C08L3302
CPC分类号： C08L23/0815 , C08L23/02 , C08L2205/02 , C08L2207/07 , C08L2666/04
摘要： A blend which comprises; A) a heterogeneous or homogenous linear ethylene homopolymer or interpolymer; B) a branched homopolymer or interpolymer; wherein said blend has; 1) a melt index, I2, of about 0.05 to about 20 g/10 min; 2) a flexural modulus of ≧100,000 psi or ≦30,000 psi; 3) a melt strength of ≧2 cN; 4) a melt extensibility of ≧25 mm/sec; and 5) wherein said melt strength of said blend meets the following relationship; Melt strength≧FMS*[(f*A)+((1−f)*B)]; where: A=3.3814*(I2)−0.6476 and B=16.882*(I2)−0.6564; where I2 is the measured melt index of the blend; f is the weight fraction of the linear polyethylene in the blend and FMS is ≧1.1. Also included in the present invention are foams, films, fibers, blow molded articles, wire and cable articles and extrusion coatings comprising said blend.
摘要翻译： 一种共混物，其包含：A）非均相或均匀的线性乙烯均聚物或互聚物; B）支化均聚物或互聚物; 其中所述共混物具有：1）约0.05至约20g / 10min的熔体指数I2; 2）≥100000psi或<= 30,000psi的挠曲模量; 3）≥2cN的熔体强度 ; 4）≥25mm/ sec的熔体延展性; 和5）其中所述共混物的熔体强度满足以下关系; I2是混合物的测量熔体指数; f是混合物中线性聚乙烯的重量分数，FMS是> = 1.1。 本发明还包括泡沫，膜，纤维，吹塑制品，电线和电缆制品以及包含所述共混物的挤出涂层。
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3.发明授权Carbonate blend composition having improved resistance to environmental stress cracking 有权碳酸盐混合物组合物具有改善的耐环境应力开裂性能公开(公告)号：US09120925B2
公开(公告)日：2015-09-01
申请号：US13576839
申请日：2011-04-21
申请人： Rahul Sharma , Thomas Oswald , Jill Martin
发明人： Rahul Sharma , Thomas Oswald , Jill Martin
CPC分类号： C08L69/00 , C08L51/085 , C08L67/02 , C08L2205/03 , C08L2666/02 , C08L83/00
摘要： The present invention relates to carbonate blend compositions demonstrating improved environmental stress crack resistance in combination with an excellent blend of impact, thermal, and physical properties. Said carbonate blend composition comprises a polycarbonate, a polyester, and a silicon-containing graft (co)polymer having a core-shell morphology, comprising a shell that contains (co)polymerized alkyl(meth)acrylate and glycidyl methacrylate grafted to a composite rubber core that contains polyorganosiloxane and poly(meth)alkyl acrylate components and methods to make said compositions.
摘要翻译： 本发明涉及具有改善的耐环境应力开裂性的碳酸酯共混物组合物以及冲击，热和物理性质的优异共混物。 所述碳酸酯共混物组合物包含聚碳酸酯，聚酯和具有核 - 壳形态的含硅接枝（共）聚合物，其包含含有（共）聚合的（甲基）丙烯酸烷基酯和甲基丙烯酸缩水甘油酯接枝到复合橡胶上的壳 其包含聚有机硅氧烷和聚（甲基）丙烯酸烷基酯组分以及制备所述组合物的方法。
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公开(公告)号：US06583188B2
公开(公告)日：2003-06-24
申请号：US10090536
申请日：2002-03-04
IPC分类号： C08J900
CPC分类号： C08J9/14 , C08J2323/16 , C08K5/43 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/10 , C08L2023/44 , C08L2203/14 , C08L2205/02 , C08L2205/025 , C08L2314/06 , C08L2666/04 , C08L2666/06
摘要： This invention describes grafted blend compositions, processes for their preparation and fabricated articles, especially foams therefrom. The blends exhibit enhanced melt strength, melt elongation greater than or equal to about 20 mm/s, increased upper service temperature, increased modulus, and increased hardness. The grafted blend compositions have little or no high shear viscosity increase over a corresponding polymer of the same chemical composition absent the coupling agent.
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公开(公告)号：US5884453A
公开(公告)日：1999-03-23
申请号：US892559
申请日：1997-07-14
CPC分类号： B65B11/045
摘要： A method and device for unwrapping self-adhering films at reduced noise levels are disclosed. The method and device include means to maintain a sufficiently high unwrapping take-off angle during the unwrapping and dispensing or unwinding of film rollstock. Suitable means provide for substantial acceleration and adjustment of the rollstock rotational speed relative to the speed of the first power driven member of an unwrapping apparatus, or the use of one or more carefully positioned deflector members. The method and device is particularly useful in unwrapping and dispensing operations of high cling stretch wrap films involving the use of turntable-style power driven equipment as well as in unwrapping and unwinding operations of pressure-sensitive adhesive tapes.
摘要翻译： 公开了以降低的噪声水平展开自粘膜的方法和装置。 该方法和装置包括在薄膜卷筒的展开和分配或展开期间保持足够高的展开起飞角度的装置。 合适的装置提供了相对于展开装置的第一动力驱动构件的速度或使用一个或多个精心定位的导流构件的卷筒转速的显着加速和调节。 所述方法和装置在涉及使用转台式动力驱动设备的高粘附拉伸包装膜的展开和分配操作以及压敏粘合带的展开和展开操作中特别有用。
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6.发明授权公开(公告)号：US07863386B2
公开(公告)日：2011-01-04
申请号：US11817231
申请日：2006-03-03
IPC分类号： C08L23/04 , C08F110/02
CPC分类号： C08L23/04 , C08L23/06 , C08L2205/02 , C08L2666/06 , C08F210/16 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/04
摘要： The instant invention is an improved low-density ethylenic polymer composition and method of making the same. The polymer composition according to instant invention includes a major component, and a minor component. The major component is an LDPE resin having a melt index (I2) in the range of about 0.01 dg/min to about 100 dg/min, a MW(abs)/MW(GPC) ratio of about 2.6 or less, and a melt strength of less than (14.0 e(−1.05*log 10(MI)))cN Jj16 mmor component is an LDPE resin having a melt index (I2) of less than about 5 dg/min, a molecular weight distribution of greater than about 7, and a MW(abs)/MW(GPC) ratio of at least 2.7. The polymer composition of the instant invention may further include additional components.
摘要翻译： 本发明是一种改进的低密度烯属聚合物组合物及其制备方法。 根据本发明的聚合物组合物包括主要组分和次要组分。 主要组分是熔体指数（I 2）在约0.01dg / min至约100dg / min，MW（abs）/ MW（GPC）比为约2.6或更小的范围内的LDPE树脂和熔体 强度小于（14.0e（-1.05 * log 10（MI）））cN Jj16 mmor组分是熔体指数（I 2）小于约5dg / min的LDPE树脂，分子量分布大于约 7，MW（abs）/ MW（GPC）比至少为2.7。 本发明的聚合物组合物可以进一步包括另外的组分。
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7.发明申请公开(公告)号：US20080125547A1
公开(公告)日：2008-05-29
申请号：US11816970
申请日：2006-03-03
IPC分类号： C08L23/00
CPC分类号： C08L23/04 , C08L2205/02 , C08L2666/06 , C08F210/16 , C08F210/14 , C08F2500/04 , C08F2500/11 , C08F2500/12
摘要： Ethylene polymer compositions comprising a high molecular weight high density polyethylene resin and a low density polyethylene resin are disclosed, where the polymer composition has a comparatively high melt strength for a given melt index. The compositions comprise from 25 to 99 percent by weight of the composition of a linear or substantially linear polyethylene polymer having a density of at least about 0.90 g/cc, and an I21 of less than about 20; and from 1 to 25 percent by weight of the composition of a high pressure low density type polyethylene resin having a melt index (I2) less than about 5, a molecular weight distribution greater than about 10, a Mw_abs/Mw_gpc ratio (“Gr”) of at least 2.7, and a melt strength at 190° C. greater than 19.0−12.6*log10(Mi). The compositions of the present invention are particularly well suited for blown film and thermoforming applications.
摘要翻译： 公开了包含高分子量高密度聚乙烯树脂和低密度聚乙烯树脂的乙烯聚合物组合物，其中聚合物组合物对于给定的熔体指数具有相对较高的熔体强度。 该组合物包含25至99重量％的组合物，其密度为至少约0.90g / cc，I21小于约20的直链或基本上线性的聚乙烯聚合物; 和组合物的1至25重量％的熔体指数（I 2）小于约5，分子量分布大于约10，Mw_abs / Mw_gpc比（“Gr”）的高压低密度型聚乙烯树脂， ）至少为2.7，熔体强度为190℃，大于19.0-12.6 * log10（Mi）。 本发明的组合物特别适用于吹塑薄膜和热成型应用。
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8.发明授权Blends of ethylenic polymers with improved modulus and melt strength and articles fabricated from these blends 有权具有改进的模量和熔体强度的乙烯类聚合物的共混物和由这些共混物制成的制品公开(公告)号：US06723793B2
公开(公告)日：2004-04-20
申请号：US10350564
申请日：2003-01-24
IPC分类号： C08L2306
CPC分类号： C08L23/0815 , C08L23/02 , C08L2205/02 , C08L2207/07 , C08L2666/04
摘要： A blend which comprises; A) a heterogeneous or homogenous linear ethylene homopolymer or interpolymer; B) a branched homopolymer or interpolymer; wherein said blend has; 1) a melt index, I2, of about 0.05 to about 20 g/10 min; 2) a flexural modulus of ≧100,000 psi or ≦30,000 psi; 3) a melt strength of ≧2 cN; 4) a melt extensibility of ≧25 mm/sec; and 5) wherein said melt strength of said blend meets the following relationship; Melt strength≧FMS*[(f*A)+((1−f)*B)]; where: A=3.3814*(I2)−06476 and B=16.882*(I2)−06564; where I2 is the measured melt index of the blend; f is the weight fraction of the linear polyethylene in the blend and FMS is ≧1.1. Also included in the present invention are foams, films, fibers, blow molded articles, wire and cable articles and extrusion coatings comprising said blend.
摘要翻译： 一种共混物，其包含：A）非均相或均匀的线性乙烯均聚物或互聚物; B）支化均聚物或互聚物;其中所述共混物具有：1）约0.05至约20g / 10min的熔体指数I 2; 2 ）≥100000psi或<= 30,000PSI的挠曲模量; 3）≥2cN的熔体强度; 4）> 25mm / sec的熔体延展性; 和5）其中所述共混物的熔体强度满足以下关系：其中：A = 3.3814 *（I2）< - 06476>和B = 16.882 *（I2）< - 06564>; 其中I 2是混合物的测量熔体指数; f是共混物中线性聚乙烯的重量分数，FMS = 1.1。本发明还包括泡沫，膜，纤维，吹塑制品，电线和电缆制品以及包含所述共混物的挤出涂层。
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公开(公告)号：US4696060A
公开(公告)日：1987-09-22
申请号：US783570
申请日：1985-10-03
申请人： Thomas Oswald
发明人： Thomas Oswald
CPC分类号： H04B10/032 , H04B1/74
摘要： In an optical transmission system, particularly a submerged system, a line finding system is provided which, in the event of a fault somewhere along the system, enables the remaining operative lines or paths to take over the traffic and thus "steer around" the fault. The laser sources of the submerged repeaters and switched by electrical selection at their input using failed clock or a supervisory signal to achieve the switching.
摘要翻译： 在光传输系统中，特别是淹没系统中，提供了一种寻线系统，其在系统某处存在故障的情况下，使得剩余的操作线或路径能够接管交通，从而“转向”故障 。 浸没式中继器的激光源，并通过使用故障时钟或监控信号的电气选择切换，以实现切换。
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公开(公告)号：US4501022A
公开(公告)日：1985-02-19
申请号：US445623
申请日：1982-11-30
申请人： Thomas Oswald
发明人： Thomas Oswald
IPC分类号： H04B10/00 , H04B10/04 , H04B10/06 , H04B10/14 , H04B10/16 , H04B10/22 , H04B10/26 , H04B10/28 , H04B9/00
CPC分类号： H04B10/29
摘要： A method and apparatus for optical transmission of an analog signal whose statistical properties approximate "white noise" including a repeater having an optical source, such as a laser, and signal processing means including a quadratic device having a quadratic characteristic arranged to receive the analog signal and provide an output signal to intensity modulate the source, the output signal containing terms which are proportional to the analog input signal and second order terms proportional to the square of the analog input signal, the second order terms being eliminated by a bandwidth filter.
摘要翻译： 一种模拟信号的光传输方法和装置，其模拟信号的统计特性近似“白噪声”，包括具有诸如激光器等光源的中继器，以及信号处理装置，该信号处理装置包括具有被布置为接收模拟信号的二次特性的二次装置 并且提供输出信号以对源进行强度调制，输出信号包含与模拟输入信号成比例的项和与模拟输入信号的平方成比例的二阶项，由带宽滤波器消除二阶项。
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