摘要:
Ethylene polymer compositions comprising a high molecular weight high density polyethylene resin and a low density polyethylene resin are disclosed, where the polymer composition has a comparatively high melt strength for a given melt index. The compositions comprise from 25 to 99 percent by weight of the composition of a linear or substantially linear polyethylene polymer having a density of at least about 0.90 g/cc, and an I21 of less than about 20; and from 1 to 25 percent by weight of the composition of a high pressure low density type polyethylene resin having a melt index (I2) less than about 5, a molecular weight distribution greater than about 10, a Mw_abs/Mw_gpc ratio (“Gr”) of at least 2.7, and a melt strength at 190° C. greater than 19.0−12.6*log10(Mi). The compositions of the present invention are particularly well suited for blown film and thermoforming applications.
摘要:
This invention is directed to an ethylene polymer blend comprising at least two diverse ethylene interpolymers wherein one interpolymer has a lower number of carbons than the at least one other interpolymer. The ethylene polymer blend preferably comprises at least one homogeneously branched ethylene/&agr;-olefin interpolymer blended with at least one heterogeneously branched ethylene/&agr;-olefin interpolymer and is characterized as having a density greater than or equal to 0.90 g/cm3 and in particularly preferred embodiments is further characterized as having an intrinsic tear value greater than or equal to 150 grams. The inventive ethylene polymer blend can be used to make various fabricated articles, especially extruded forms and most especially films such as high strength thin gauge packaging film, impact resistant shrink film and heat sealable packaging film.
摘要:
Polymer blends are described that include at least one first ethylene interpolymer and at least one second ethylene interpolymer wherein the difference in the number of carbon atoms in the comonomer of the first interpolymer and the comonomer of the second interpolymer is at least two, wherein the first interpolymer and/or the second interpolymer has molecular weight distribution of from about 1.8 to about 2.8; and wherein the polymer blend has a density greater than or equal to 0.90 g/cm3. Articles made from such blends are also disclosed.
摘要翻译:描述了包含至少一种第一乙烯互聚物和至少一种第二乙烯互聚物的聚合物共混物,其中第一互聚物的共聚单体和第二互聚物的共聚单体中的碳原子数的差异为至少两个,其中第一 互聚物和/或第二互聚物的分子量分布为约1.8至约2.8; 并且其中所述聚合物共混物的密度大于或等于0.90g / cm 3。 还公开了由这种共混物制成的制品。
摘要:
The present invention relates to a multi-layer oriented shrink film comprising at least one skin layer comprising a polystyrene material and at least one core layer comprising a polyolefin layer. The films are preferably primarily oriented in either the machine or the cross direction. These films are ideally suited for use as a shrink label which can be applied either as a CD shrink sleeve or applied using a continuous roll process. The films ideally have an overall density of less than 1.0 g/cm3, to facilitate recycling efforts.
摘要翻译:本发明涉及一种多层定向收缩膜,其包含至少一层包含聚苯乙烯材料的表皮层和至少一层包含聚烯烃层的芯层。 膜优选主要在机器或横向方向上定向。 这些膜理想地适合用作收缩标签,其可以作为CD收缩套筒使用,或者使用连续辊式方法施加。 这些膜理想地具有小于1.0g / cm 3的总密度,以便于再循环。
摘要:
This invention relates to cast films prepared from interpolymer compositions comprising; (A) a substantially linear ethylene/&agr;-olefin interpolymer present in the composition in an amount of from about 10 to about 100% by weight based on the combined weight of Components A and B; and (B) a heterogeneous interpolymer present in the composition in an amount of from about 0 to about 90% by weight based on the combined weight of Components A and B; and wherein said interpolymer composition has an I10/I2 value of −1.2−1.3* log(I2) The interpolymer compositions are useful in cast stretch film manufacture with the resulting cast films having an excellent balance of strength and processability.
摘要:
The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
摘要翻译:本发明涉及由包含至少一种氢化嵌段共聚物和任选的至少一种其它聚合物制备的纤维,所述其它聚合物选自反应性定制的液体聚氨酯,弹性体或磺化乙烯/乙烯基芳族互聚物, 弹性体乙烯/ C 3 -C 20α-烯烃互聚物,C 3 -C 20α-烯烃/共轭二烯互聚物,弹性聚丙烯聚合物,增强聚丙烯聚合物,弹性体热塑性聚氨酯,弹性共聚酯,部分氢化嵌段共聚物,弹性体 聚酰胺,羟基官能化聚醚(或聚醚胺),苯乙烯/共轭二烯互聚物和弹性体茂金属催化的合成聚合物或其共混物或配制体系。
摘要:
Blends of polymeric materials comprising a plurality of substantially random interpolymers each interpolymer comprising:(1) from about 1 to about 65 mole percent of polymer units derived from either(a) at least one vinyl aromatic monomer or(b) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or(c) a combination of at least one vinyl aromatic monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and(2) from about 35 to about 99 mole percent of polymer units derived from ethylene and/or at least one aliphatic alpha olefin having from 3 to 20 carbon atoms; and wherein:the amount of polymer units derived from vinyl aromatic monomer and/or aliphatic or cycloaliphatic vinyl or vinylidene monomer in any interpolymer component differs from that amount in another interpolymer component by at least 0.5 mole percent.These blends of interpolymer components give enhanced properties or processability when compared to the individual polymers comprising the blend.
摘要:
The subject invention generally provides a multilayer structure that includes a polymer mixture made from at least two polymer component materials. The invention particularly pertains to a multilayer structure containing an improved sealant layer and a polypropylene layer, wherein the sealant layer is made from a homogeneously branched ethylene polymer having particular molecular weight characteristics and a second ethylene polymer. The sealant layer has balanced properties such low heat seal and hot tack initiation temperature, a high hot tack strength and a broad hot tack seal window. The multilayer structure is particularly useful as a biaxially oriented polypropylene (BOPP) packaging film structure.
摘要:
Disclosed is a cross-linked ethylenic polymer foam structure of an ethylenic polymer material of a cross-linked, substantially linear ethylenic polymer. The substantially linear ethylenic polymer having in an uncross-linked state has: a) a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63; b) a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .gtoreq.(I.sub.10 /I.sub.2)- 4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear ethylenic polymer having about the same I.sub.2 and M.sub.w /M.sub.n. Further disclosed is a process for making the above foam structure.
摘要:
Substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, and a critical shear stress at onset of gross melt fracture of greater than about 4.times.10.sup.6 dyne/cm.sup.2 and their method of manufacture are disclosed. The substantially linear olefin polymers preferably have at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5. The new polymers have improved processability over conventional olefin polymers and are useful in producing fabricated articles such as fibers, films, and molded parts.