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    PROCESS FOR FORMING A CATALYST CARRIER
    2.
    发明申请
    PROCESS FOR FORMING A CATALYST CARRIER 审中-公开
    形成催化载体的方法

    公开(公告)号：US20110077152A1

    公开(公告)日：2011-03-31

    申请号：US12915101

    申请日：2010-10-29

    申请人： William H. Gerdes ,  Thomas Szymanski ,  Donald J. Remus ,  John R. Lockemeyer ,  Randall Clayton Yeates

    发明人： William H. Gerdes ,  Thomas Szymanski ,  Donald J. Remus ,  John R. Lockemeyer ,  Randall Clayton Yeates

    IPC分类号： B01J21/04

    CPC分类号： B01J21/04 ,  B01J21/12 ,  B01J23/50 ,  B01J23/66 ,  B01J23/688 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1071 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0072

    摘要： A carrier, which comprises non-platelet alumina and/or a bond material, has a surface area of at least 1.3 m2/g, a total pore volume and a pore size distribution such that at least 80% of the total pore volume is contained in pores with diameters in the range of from 0.1 to 10 μm, and at least 80% of the pore volume contained in the pores with diameters in the range of from 0.1 to 10 μm is contained in pores with diameters in the range of from 0.3 to 10 μm, and a process for the preparation of a carrier which comprises forming a mixture comprising: a) from 50 to 95 weight percent of a first particulate α-alumina having a median particle size (d50) of from 5 to 100 μm; b) from 5 to 50 weight percent of a second particulate α-alumina having a d50 which is less than the d50 of the first particulate α-alumina and which is in the range of from 1 to 10 μm; and c) an alkaline earth metal silicate bond material; weight percent being based on the total weight of α-alumina in the mixture; and firing the mixture to form the carrier.

    摘要翻译： 包含非血小板氧化铝和/或粘合材料的载体具有至少1.3m 2 / g的表面积，总孔体积和孔径分布，使得含有总孔体积的至少80％ 在直径在0.1至10μm范围内的孔中，包含在直径在0.1至10μm范围内的直径在0.1至10μm范围内的孔中的孔体积的至少80％包含在直径范围为0.3 以及制备载体的方法，其包括形成混合物，其包含：a）50至95重量％的中值粒径（d50）为5至100μm的第一颗粒状α-氧化铝; b）5至50重量％的d50小于第一颗粒α-氧化铝的d50并且为1至10μm范围的第二颗粒状α-氧化铝; 和c）碱土金属硅酸盐粘合材料; 重量百分数是基于混合物中α-氧化铝的总重量; 并且将混合物烧制以形成载体。

    Catalyst carrier and a process for preparing the catalyst carrier
    3.
    发明授权
    Catalyst carrier and a process for preparing the catalyst carrier 有权
    催化剂载体和制备催化剂载体的方法

    公开(公告)号：US07825062B2

    公开(公告)日：2010-11-02

    申请号：US11449019

    申请日：2006-06-06

    申请人： William H. Gerdes ,  Thomas Szymanski ,  Donald J. Remus ,  John R. Lockemeyer ,  Randall Clayton Yeates

    发明人： William H. Gerdes ,  Thomas Szymanski ,  Donald J. Remus ,  John R. Lockemeyer ,  Randall Clayton Yeates

    IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J20/00

    CPC分类号： B01J21/04 ,  B01J21/12 ,  B01J23/50 ,  B01J23/66 ,  B01J23/688 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1071 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0072

    摘要： A carrier, which comprises non-platelet alumina and/or a bond material, has a surface area of at least 1.3 m2/g, a total pore volume and a pore size distribution such that at least 80% of the total pore volume is contained in pores with diameters in the range of from 0.1 to 10 μm, and at least 80% of the pore volume contained in the pores with diameters in the range of from 0.1 to 10 μm is contained in pores with diameters in the range of from 0.3 to 10 μm, and a process for the preparation of a carrier which comprises forming a mixture comprising: a) from 50 to 95 weight percent of a first particulate α-alumina having a median particle size (d50) of from 5 to 100 μm; b) from 5 to 50 weight percent of a second particulate α-alumina having a d50 which is less than the d50 of the first particulate α-alumina and which is in the range of from 1 to 10 μm; and c) an alkaline earth metal silicate bond material; weight percent being based on the total weight of α-alumina in the mixture; and firing the mixture to form the carrier.

    摘要翻译： 包含非血小板氧化铝和/或粘合材料的载体具有至少1.3m 2 / g的表面积，总孔体积和孔径分布，使得含有总孔体积的至少80％ 在直径在0.1至10μm范围内的孔中，包含在直径在0.1至10μm范围内的直径在0.1至10μm范围内的孔中的孔体积的至少80％包含在直径范围为0.3 以及制备载体的方法，其包括形成混合物，其包含：a）50至95重量％的中值粒径（d50）为5至100μm的第一颗粒状α-氧化铝; b）5至50重量％的d50小于第一颗粒α-氧化铝的d50并且为1至10μm范围的第二颗粒状α-氧化铝; 和c）碱土金属硅酸盐粘合材料; 重量百分数是基于混合物中α-氧化铝的总重量; 并且将混合物烧制以形成载体。

    Catalyst for the reduction of oxides of nitrogen
    7.
    发明授权
    Catalyst for the reduction of oxides of nitrogen 失效
    用于还原氮氧化物的催化剂

    公开(公告)号：US4735927A

    公开(公告)日：1988-04-05

    申请号：US910591

    申请日：1986-09-23

    申请人： William H. Gerdes ,  Charles Lim ,  Thomas Szymanski

    发明人： William H. Gerdes ,  Charles Lim ,  Thomas Szymanski

    IPC分类号： B01D53/86 ,  B01J29/06 ,  B01J29/16

    CPC分类号： B01J29/06 ,  B01D53/8628

    摘要： A catalyst for the selective reduction of nitrogen oxides to nitrogen in the presence of ammonia in the form of composite bodies formed from a mixture of anatase (5 to 40% by weight), a zeolite (50 to 90%), a bond material (0 to 30%, and, optionally, promoter selected from oxides of vanadium, molybdenum, and copper, in the amount of at least 0.1% by weight.

    摘要翻译： 在由锐钛矿（5〜40重量％），沸石（50〜90％），粘结材料（5〜40重量％）的混合物形成的复合体形式的氨的存在下，将氮氧化物选择性还原为氮的催化剂 0至30％，以及任选的选自钒，钼和铜的氧化物的促进剂，其量为至少0.1重量％。

    Ethylene oxide catalyst
    9.
    发明授权
    Ethylene oxide catalyst 失效
    乙烯氧化物催化剂

    公开(公告)号：US5145824A

    公开(公告)日：1992-09-08

    申请号：US804494

    申请日：1991-12-09

    申请人： John E. Buffum ,  Ruth M. Kowaleski ,  William H. Gerdes

    发明人： John E. Buffum ,  Ruth M. Kowaleski ,  William H. Gerdes

    IPC分类号： B01J23/50 ,  B01J21/06 ,  B01J21/12 ,  B01J23/00 ,  B01J23/66 ,  B01J23/68 ,  B01J27/055 ,  B01J27/25 ,  C07B61/00 ,  C07D301/10 ,  C07D303/04

    CPC分类号： C07D301/10 ,  B01J23/688 ,  B01J21/066 ,  Y02P20/52

    摘要： The invention relates to ethylene oxide catalysts containing silver, alkali metal promoters, rhenium promoters and optionally rhenium co-promoters selected from sulfur, molybdenum, tungsten, chromium and mixtures thereof supported on a carrier consisting of at least 85 percent by weight of alpha alumina, from about 0.01 to about 6 percent by weight (measured as the oxide) of an added alkaline earth metal in the form of an oxide, from about 0.01 to about 5 percent by weight (measured as the dioxide) of added silicon in the form of an oxide and from zero to about 10 percent by weight (measured as the dioxide) of added zirconium in the form of an oxide. The invention also relates to an ethylene oxide process using the above catalyst.

    摘要翻译： 本发明涉及含有银的环氧乙烷催化剂，碱金属助催化剂，铼促进剂和任选的选自硫，钼，钨，铬及其混合物的铼助催化剂，其负载在由至少85重量％的α-氧化铝， 以氧化物形式的添加的碱土金属的约0.01至约6重量％（以氧化物计），加入的硅的约0.01至约5重量％（以二氧化物计），其形式为 氧化物和以氧化物形式的添加的锆的0至约10重量％（作为二氧化物测量）。 本发明还涉及使用上述催化剂的环氧乙烷方法。