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公开(公告)号：US06864333B2
公开(公告)日：2005-03-08
申请号：US09914305
申请日：2000-12-22
IPC分类号： C08F4/602 , C07D495/04 , C07F17/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F210/18 , C08F4/52
CPC分类号： C07D495/04 , C07F17/00 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/16 , C08F210/18 , C08F4/65927 , C08F2500/17 , C08F210/06 , C08F210/14 , C08F2500/25 , C08F236/20
摘要： Ethylene based polymers having high molecular weights can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of catalysts comprising single carbon bridged metallocenes, which has a particular ligand system containing a heteroatom.
摘要翻译： 通过在包含具有特定的含有杂原子的配体体系的单碳桥联茂金属的催化剂的存在下进行聚合反应，可以在工业感兴趣的温度下以高收率获得具有高分子量的乙烯基聚合物。
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公开(公告)号：US06822106B2
公开(公告)日：2004-11-23
申请号：US10700095
申请日：2003-11-03
IPC分类号： C08F464
CPC分类号： C07F17/00 , C07F7/0805 , C07F7/0814 , C08F4/65912 , C08F10/02 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F4/65927 , C08F210/06 , C08F2500/20 , C08F2500/17 , C08F210/14 , C08F2500/25
摘要： Ethylene based polymers having high molecular weights can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of catalysts comprising silicon bridged metallocenes having a particular ligand system containing a heteroatom.
摘要翻译： 通过在包含具有特定的含有杂原子的配体体系的硅桥连金属茂的催化剂的存在下进行聚合反应，可以在工业感兴趣的温度下以高产率获得具有高分子量的乙烯基聚合物。
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公开(公告)号：US06787619B2
公开(公告)日：2004-09-07
申请号：US09914411
申请日：2001-08-28
IPC分类号： C08F464
CPC分类号： C07F17/00 , C07F7/0805 , C07F7/0814 , C08F4/65912 , C08F10/02 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F4/65927 , C08F210/06 , C08F2500/20 , C08F2500/17 , C08F210/14 , C08F2500/25
摘要： Ethylene based polymers having high molecular weights can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of catalysts comprising silicon bridged metallocenes having a particular ligand system containing a heteroatom.
摘要翻译： 通过在包含具有特定的含有杂原子的配体体系的硅桥连金属茂的催化剂的存在下进行聚合反应，可以在工业感兴趣的温度下以高产率获得具有高分子量的乙烯基聚合物。
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4.发明申请PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS WITH NARROW MOLECULAR WEIGHT DISTRIBUTION 审中-公开制备具有窄分子量分布的乙烯聚合物的方法公开(公告)号：US20120130031A1
公开(公告)日：2012-05-24
申请号：US13387106
申请日：2010-08-02
申请人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
发明人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
IPC分类号： C08F4/76
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6494 , C08F2500/12 , C08F2500/04 , C08F210/06
摘要： Process for the preparation of ethylene polymers having narrow MWD characterized by a F/E ratio lower than 35 carried out in the presence of a catalyst system comprising (a) a solid catalyst component comprising Ti atoms that are substantially in the +4 oxidation state, Mg, Cl, and optionally OR groups and internal donors in which R is a C1-C20 hydrocarbon group, in which the OR/Ti molar ratio is equal to or lower than 0.35 and the internal donor/Ti ratio is lower than 1, (b) an aluminum alkyl compound and (c) a compound selected from alkoxybenzenes of specified formula.
摘要翻译： 制备具有窄MWD的乙烯聚合物的方法，其特征在于在催化剂体系存在下进行F / E比低于35的乙烯聚合物，其包含（a）包含基本上处于+4氧化态的Ti原子的固体催化剂组分， Mg，Cl和任选的OR基团和其中R是C1-C20烃基的内给体，其中OR / Ti摩尔比等于或低于0.35，内给体/ Ti比低于1（ b）烷基铝化合物和（c）选自具有规定式的烷氧基苯的化合物。
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公开(公告)号：US07879959B2
公开(公告)日：2011-02-01
申请号：US11887528
申请日：2006-03-15
IPC分类号： C08F4/50
CPC分类号： C08F110/02 , C08F210/16 , C08F4/6565 , C08F4/6548 , C08F2500/12 , C08F210/08
摘要： Catalyst components for the (co)polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio in the range 0.1-1.5, a Mg/Ti molar ratio of less than 8, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.
摘要翻译： 含有Ti，Mg，卤素，ORI基团的乙烯（共）聚合的催化剂组分，其中RI是任选含有杂原子的C 1 -C 12烃基，ORI / Ti摩尔比在0.1-1.5范围内，Mg / Ti 摩尔比小于8，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，其特征在于特定的SS-NMR图案，特别适用于制备窄MWD晶体乙烯聚合物。
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公开(公告)号：US07834117B2
公开(公告)日：2010-11-16
申请号：US11887527
申请日：2006-03-15
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6543 , C08F4/6565 , C08F210/08 , C08F2500/12
摘要： A process for preparing crystalline ethylene (co)polymers comprising (co)polymerizing ethylene in the presence of carried out in the presence catalyst system comprising (a) a solid catalyst component comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio of at least 0.5, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight, and showing a specific pattern of the SS-NMR; and (b) an aluminum alkyl compound as a cocatalyst. The process allows to obtain in good yields ethylene polymers with narrow MWD.
摘要翻译： 在包含（a）包含Ti，Mg，卤素，ORI基团的固体催化剂组分的情况下，在存在催化剂体系的情况下，制备结晶乙烯（共）聚合物的方法，包括（共）聚合乙烯，其中RI是C1 -C12烃基，任选地含有杂原子，ORI / Ti摩尔比至少为0.5，相对于所述固体催化剂组分的总重量，钛的量高于4重量％，并且显示了 SS-NMR; 和（b）作为助催化剂的烷基铝化合物。 该方法允许以良好的产率获得具有窄MWD的乙烯聚合物。
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公开(公告)号：US20080064836A1
公开(公告)日：2008-03-13
申请号：US11982706
申请日：2007-11-01
IPC分类号： C08F4/44
CPC分类号： C08L23/0815 , C08F10/00 , C08F210/00 , C08F210/16 , C08F255/00 , C08F255/02 , C08L23/10 , C08L23/16 , C08L51/06 , C08L2314/02 , C08F4/6555 , C08F4/6494 , C08F4/651 , C08L2666/06 , C08L2666/02 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F2500/20 , C08F2500/11 , C08F210/06 , C08F2500/17 , C08F2500/04
摘要： Process for the preparation of ethylene copolymers comprising the copolymerization of ethylene with olefins CH2═CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms carried out in the presence of a catalyst comprising (i) a solid catalyst component comprising Mg, Ti, halogen and specific 1,3-diethers of formula (I) in which R is a C1-C10 hydrocarbon group, R1 is methyl or ethyl, optionally containing a heteroatom, and R2 is a C4-C12 linear alkyl optionally containing a heteroatom, and (ii) an organo-Al compound. The obtained copolymers are endowed with good comonomer distribution.
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8.发明申请公开(公告)号：US20120077944A1
公开(公告)日：2012-03-29
申请号：US13376000
申请日：2010-06-16
IPC分类号： C08F4/646
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6543 , C08F4/6555 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Catalyst components for the polymerization of olefins CH2═CHR wherein R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, comprising Mg, Ti, Cl and a compound (L) or its derivatives, selected from condensed cyclic structures which are formed by at least an aromatic ring and which are substituted with at least two hydroxy groups, said Cl and Ti atoms being in an amount such as to have a molar ratio ranging from 5 to 50.
摘要翻译： 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，Cl和化合物（L）或其衍生物，其选自稠合的环状结构，其由 至少一个芳环，并被至少两个羟基取代，所述Cl和Ti原子的量为使其摩尔比为5-50。
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9.发明授权公开(公告)号：US08071499B2
公开(公告)日：2011-12-06
申请号：US12448289
申请日：2007-12-11
CPC分类号： C08F10/02 , C08F110/06 , C08F210/06 , C08F4/6557 , C08F4/6555 , C08F2500/12 , C08F2500/18 , C08F210/16
摘要： A catalyst component comprising Ti, Mg, Al, Cl, and optionally ORI groups in which RI is a C1-C20 hydrocarbon group, optionally containing heteroatoms, up to an amount such as to give a molar ORI/Ti ratio lower than 0.5, characterized by the fact that substantially all the titanium atoms are in valence state of 4, that the porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1 μm, is at least 0.3 cm3/g, and by the fact that the Cl/Ti molar ratio is lower than 29.The said catalysts are characterized by high morphological stability under the low molecular weight ethylene polymerization conditions while at the same time maintaining characteristics of high activity.
摘要翻译： 包含Ti，Mg，Al，Cl和任选的ORI基团的催化剂组分，其中RI是任选含有杂原子的C 1 -C 20烃基，直到一定量使ORI / Ti摩尔比低于0.5，表征 通过基本上所有的钛原子都处于4的价态，由汞法测量并且由于半径等于或小于1μm的孔的孔隙率（PF）至少为0.3cm 3 / g， 以及Cl / Ti摩尔比低于29的事实。所述催化剂的特征在于在低分子量乙烯聚合条件下的高形态稳定性，同时保持高活性的特性。
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公开(公告)号：US07371806B2
公开(公告)日：2008-05-13
申请号：US10503104
申请日：2003-05-30
IPC分类号： C08F210/02
CPC分类号： C08L23/0815 , C08F10/00 , C08F210/00 , C08F210/16 , C08F255/00 , C08F255/02 , C08L23/10 , C08L23/16 , C08L51/06 , C08L2314/02 , C08F4/6555 , C08F4/6494 , C08F4/651 , C08L2666/06 , C08L2666/02 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F2500/20 , C08F2500/11 , C08F210/06 , C08F2500/17 , C08F2500/04
摘要： Process for the preparation of ethylene copolymers comprising the copolymerization of ethylene with olefins CH2═CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms carried out in the presence of a catalyst comprising (i) a solid catalyst component comprising Mg, Ti, halogen and specific 1,3-diethers of formula (I) in which R is a C1-C10 hydrocarbon group, R1 is methyl or ethyl, optionally containing a heteroatom, and R2 is a C4-C12 linear alkyl optionally containing a heteroatom, and (ii) an organo-Al compound. The obtained copolymers are endowed with good comonomer distribution.
摘要翻译： 制备乙烯共聚物的方法，包括乙烯与烯烃-CH 2 -CHR的共聚合，其中R是具有1-12个碳原子的烃基，在催化剂存在下进行，所述催化剂包含（i ）包含Mg，Ti，卤素和式（I）的特定1,3-二醚的固体催化剂组分，其中R是C 1 -C 10烃基， R 1是任选地含有杂原子的甲基或乙基，R 2是任选地含有杂原子的C 4 -C 12直链烷基，和（ii）有机铝化合物 。 所得共聚物具有良好的共聚单体分布。
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