摘要:
A fuel cell system of the invention includes a tubular switching member 70 with slits 70a to shift their position and thereby vary an opening area of outlets of oxidizing gas conduits 36 in respective unit fuel cells 30 constituting a fuel cell stack 20. The system further includes a drive roller 74 and a stepping motor 79 that function to change over the position of the slits 70a. An electronic control unit controls rotation of the stepping motor 79 to actuate the tubular switching member 70 first to narrow the opening area of the outlets of the oxidizing gas conduits 36 to or toward 0 and then to widen the opening area of the outlets of the oxidizing gas conduits 36, thereby generating pulsation in the oxidizing gas conduits 36. Water droplets flocculated in the oxidizing gas conduits 36 are thus discharged to the outlets with high efficiency. The structure of the embodiment does not require any bypass in the respective unit fuel cells 30. The characteristic structure of the invention uses the frame of the unit fuel cell 30 equivalent to the existing one and does not substantially increase the size of the fuel cell stack 20.
摘要:
A hydrazone compound represented by a General Formula (1) below, a hydrazone compound for forming a metal complex, which is represented by the General Formula (1) below and forms a metal complex by coordination to at least one metal species, a ligand for forming a metal complex including the hydrazone compound, and a monomer for manufacturing a polymer compound including the hydrazone compound: wherein, Py represents a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group.
摘要:
A fuel cell has an electrolyte, an anode provided on one side of the electrolyte and a cathode provided on the other side of the electrolyte, and a fuel passage which is formed so as to contact the anode and through which fuel flows. A substance having an ion-conducting property is mixed in with the fuel that flows through the fuel passage. For example, fuel is supplied to the fuel passage from a fuel supply apparatus, while a substance having an ion-conducting property is supplied to the fuel passage from an ion-conducting substance supply apparatus.
摘要:
A catalyst for electrodes in solid-polymer fuel cells which comprises metal oxide particles themselves. It can be used as a substituent for the carbon particles having platinum deposited thereon and platinum metal particles which are presently in general use as, e.g., a catalyst for electrodes in fuel cells, and has a possibility that the amount of platinum to be used can be greatly reduced as compared with the conventional carbon particles having platinum deposited thereon, etc.The catalyst comprises fine transition-metal oxide particles having, in the main phase, a perovskite structure represented by the general formula ABO3 (wherein A represents one or more elements selected among lanthanum, strontium, cerium, calcium, yttrium, erbium, praseodymium, neodymium, samarium, europium, silicon, magnesium, barium, niobium, lead, bismuth, and antimony; and B represents one or more elements selected among iron, cobalt, manganese, copper, titanium, chromium, nickel, and molybdenum), the fine oxide particles having lattice constants satisfying the following relationship (1): 1.402
摘要:
A fuel cell includes a diffusion layer formed in a sheet having a small thickness. The fuel cell is assembled with a tension imposed on the sheet in an in-plane direction of the sheet. The tension is imposed on the diffusion layer from a frame disposed outside the fuel cell. The tension is of such a magnitude as to prevent a portion of the sheet positioned corresponding to a gas passage of a separator from being deformed when the fuel cell is assembled and has a tightening force thereby applied thereto. The tension is adjustable according to a fuel cell operating condition. These structures can prevent a separator rib from pushing into a membrane, maintaining the gas passability of the diffusion layer well.
摘要:
The present invention provides a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity in an alkaline form, and stably keeps high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state. The invention is useful in an electrochemical system using the solid electrolyte, such as a fuel cell.The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, and also a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a solution including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.
摘要:
The present invention provides a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity in an alkaline form, and stably keeps high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state. The invention is useful in an electrochemical system using the solid electrolyte, such as a fuel cell.The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, and also a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a solution including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.
摘要:
A fuel cell system of the invention includes outer-conduit water absorbing members that are arranged outside oxidizing gas conduits of respective unit fuel cells, and a changeover mechanism that changes over the status of the outer-conduit water absorbing members between an absorption state in which the outer-conduit water absorbing members absorb moisture in the oxidizing gas conduits and a non-absorption state in which the outer-conduit water absorbing members do not absorb the moisture in the oxidizing gas conduits. Control of this changeover mechanism effectively regulates the moisture level in the oxidizing gas conduits.
摘要:
A metal hydride is supplied into a reactor while being converted into fine particles. By injecting water from an injector, the metal hydride is hydrolyzed to generate hydrogen. The water supplied to the reactor is water generated by a fuel cell. This allows omission or a size reduction of a water tank for the hydrolysis, and therefore allows a size reduction of the system as a whole. It is possible to adopt a construction in which waste heat from the fuel cell is supplied to pyrolyze the metal hydride, a construction in which heat generated by the hydrolysis is used to pyrolyze another metal hydride, etc.
摘要:
A catalyst obtained by calcining a hydrazone metal complex in which at least one catalytic metal species is coordinated to a hydrazone compound represented by a General Formula (1) below, a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below as a repeating unit, and a catalyst obtained by calcining a hydrazone polymer metal complex in which at least one catalytic metal species is coordinated to a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below: wherein, Py represents a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group.