摘要:
A combustion air supply apparatus 9 of alternating heat exchange type supplies combustion air and discharges combustion exhaust gas at a flow velocity of 80 to 200 m/sec. A burner assembly 4 is configured in such a manner that low-caloric fuel gas is pre-heated with heat of pre-combusting high-caloric fuel gas before the low-caloric fuel gas reaches a mixing starting space CA in the combustion chamber where the pre-combusting high-caloric fuel gas and the low-caloric fuel gas come to burn together in a full scale in the mixing starting space CA. When an air amount of the combustion air supplied through the high-temperature air supply ports of the plurality of fuel gas combustion apparatuses is defined as Q1 and an air amount of the pre-combustion air to be mixed with the high-caloric fuel gas, supplied from the fuel gas combustion apparatuses, is defined as Q2, a total air amount (Q1+Q2) is 1.02 to 1.10 times more than a theoretical air amount QS required for combustion, and a ratio of Q2/(Q1+Q2) is 0.011 to 0.047.
摘要:
In a burning air feeding device (9) of alternating heat-exchanging type, the feed of burning air and the discharge of a burned exhaust gas are performed at the speeds of 80 to 200 m/sec. A burner structure (4) is constituted such that a low-calorie fuel gas is preheated with the heat of a precombustion high-calorie fuel gas till the low-calorie fuel gas reaches a mixing starting zone (CA), and such that the precombustion high-calorie fuel gas and the low-calorie fuel gas are burned together in the mixing starting zone (CA). The sum (Q1+Q2) of an air quantity (Q1) fed from the hot air feeding ports of a plurality of fuel gas burning devices and an air quantity (Q2) of a precombustion air to be mixed with the high-calorie fuel gas in the plural fuel gas burning devices is set to 1.02 to 1.10 times as high as the stoichiometric air quantity (Qs) necessary for the combustion, and the ratio (Q2/(Q1+Q2)) is set within the range of 0.011 to 0.047.
摘要:
A synthesis gas production apparatus (reformer) to be used for a synthesis gas production step in a GTL (gas-to-liquid) process is prevented from being contaminated by metal components. A method of suppressing metal contamination of a synthesis gas production apparatus operating for a GTL process that includes a synthesis gas production step of producing synthesis gas by causing natural gas and gas containing steam and/or carbon dioxide to react with each other for reforming in a synthesis gas production apparatus in which, at the time of separating and collecting a carbon dioxide contained in the synthesis gas produced in the synthesis gas production step and recycling the separated and collected carbon dioxide as source gas for the reforming reaction in the synthesis gas production step, a nickel concentration in the recycled carbon dioxide is not higher than 0.05 ppmv.
摘要:
A synthesis gas production apparatus (reformer) to be used for a synthesis gas production step in a GTL (gas-to-liquid) process is prevented from being contaminated by metal components. A method of suppressing metal contamination of a synthesis gas production apparatus operating for a GTL process that includes a synthesis gas production step of producing synthesis gas by causing natural gas and gas containing steam and/or carbon dioxide to react with each other for reforming in a synthesis gas production apparatus in which, at the time of separating and collecting a carbon dioxide contained in the synthesis gas produced in the synthesis gas production step and recycling the separated and collected carbon dioxide as source gas for the reforming reaction in the synthesis gas production step, a nickel concentration in the recycled carbon dioxide is not higher than 0.05 ppmv.
摘要:
Heavy hydrocarbons contained in FT off gas of a GTL process are removed by bringing the FT off gas into contact with absorption oil, by introducing the FT off gas into a distillation tower, by cooling the FT off gas or by driving the FT off gas into an adsorbent. A burner tip for heating a reformer tube, using FT off gas as fuel, is prevented from being plugged by the deposition of heavy hydrocarbons contained in the FT off gas.
摘要:
Disclosed are a catalyst for producing a synthesis gas using a carbon-containing organic compound as a raw material and a process for producing carbon monoxide. The catalyst for producing a synthesis gas is composed of a carrier formed of a metal oxide and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier and is characterized in that the catalyst has a specific surface area of 25 m2/g or less, in that the electronegativity of the metal ion of the carrier metal oxide is 13.0 or less and in that the amount of the supported catalytic metal is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide. The process for producing carbon monoxide includes a step of reacting a carbon-containing organic compound with carbon dioxide in a pressurized condition to produce a synthesis gas, and a step of concentrating carbon monoxide in the thus obtained synthesis gas and is characterized in that the above-described catalyst is used as a catalyst in the synthesis gas producing step.
摘要:
It is avoided that the sulfur compounds originating from the castable is mixed into produced synthesis gas, the mixed sulfur compounds are separated and collected with carbon dioxide, the collected carbon dioxide is recycled as raw material gas and then the sulfur compounds is directly supplied to the reformer to consequently degrade the reforming catalyst in the reformer by sulfur poisoning. The carbon dioxide separated and collected in the carbon dioxide removal step is introduced into the desulfurization apparatus of the desulfurization step or the sulfur compounds adsorption apparatus before being recycled to the reformer to remove the sulfur compounds.
摘要:
Provided is a method for producing hydrogen aimed at storage and transportation, by which hydrogen for storage and transportation that is necessary for smoothly performing an organic chemical hydride method can be industrially produced efficiently at low cost. The method is a method for producing hydrogen aimed at storage and transportation in an organic chemical hydride method, in which: the hydrogenation process of an aromatic compound uses, as a hydrogen source for the reaction of the aromatic compound, a reaction gas is produced by a reforming reaction and adjusted a hydrogen concentration from 30 to 70 vol % by a shift reaction; and a hydrogenated aromatic compound is separated from a reaction mixture obtained in the hydrogenation process, which is followed by purification.
摘要:
A situation where sulfur compounds originating from a castable are mixed into synthesis gas produced by way of a reforming reaction and the mixed sulfur compounds are separated and collected with carbon dioxide and further fed into a reformer to thereby degrade the reforming catalyst of the reformer by sulfur poisoning is avoided. Purge gas that is steam or steam-containing gas is made to flow into the piping to be used for a synthesis gas production apparatus and dried out to remove the sulfur compounds contained in the castable prior to the start-up of operation of the synthesis gas production apparatus, in order to prevent the sulfur compounds from being released by hot synthesis gas.
摘要:
It is avoided that the sulfur compounds originating from the castable is mixed into produced synthesis gas, the mixed sulfur compounds are separated and collected with carbon dioxide, the collected carbon dioxide is recycled as raw material gas and then the sulfur compounds is directly supplied to the reformer to consequently degrade the reforming catalyst in the reformer by sulfur poisoning. The carbon dioxide separated and collected in the carbon dioxide removal step is introduced into the desulfurization apparatus of the desulfurization step or the sulfur compounds adsorption apparatus before being recycled to the reformer to remove the sulfur compounds.