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    Method of melt blending curable polymer compositions using silicone hydrides
    1.
    发明授权
    Method of melt blending curable polymer compositions using silicone hydrides 失效
    使用硅氧烷氢化物熔融共混固化的聚合物组合物的方法

    公开(公告)号：US08011913B2

    公开(公告)日：2011-09-06

    申请号：US12040487

    申请日：2008-02-29

    申请人： Tonson Abraham ,  Edward Blok ,  Kuo-Shein Shen ,  Norman Glenn Barber

    发明人： Tonson Abraham ,  Edward Blok ,  Kuo-Shein Shen ,  Norman Glenn Barber

    IPC分类号： B29C47/00 ,  B29C35/02 ,  C08G77/12

    CPC分类号： C08F8/42 ,  C08L21/00 ,  C08L23/16 ,  C08L83/04 ,  C08L83/00

    摘要： Provided in one aspect is a method of melt blending comprising providing an extruder possessing addition points from a zero point to a 100 point the length of the extruder; adding at least one thermoplastic and at least one curable polymer at the zero to 10 point of the extruder; adding at least one silicone hydride at the 5 to 30 point of the extruder; adding at least one metal catalyst at the 20 to 60 point of the extruder, with the proviso that the metal catalyst is added at least 5 points farther down the extruder than the silicone hydride. Provided in another aspect is a hydrosilylation curative composition comprising a silicone hydride having the formula wherein H is hydrogen, and each R′ is independently selected from hydrogen and C1 to C10 alkyl groups; R″ is selected from C1 to C10 alkyl groups; n is an integer from 5 to 45; and m is an integer from 5 to 45.

    摘要翻译： 在一方面提供一种熔融共混方法，其包括提供挤出机，该挤出机具有从挤压机的零点到100点的添加点; 在挤出机的零点至10点加入至少一种热塑性和至少一种可固化聚合物; 在挤出机的5至30℃加入至少一种硅氢化合物; 在挤出机的20至60℃加入至少一种金属催化剂，条件是金属催化剂在挤出机上比硅氢化合物加入至少5点。 另一方面提供了一种氢化硅烷化固化剂组合物，其包含具有下式的硅氢化合物，其中H是氢，并且每个R'独立地选自氢和C 1至C 10烷基; R“选自C1至C10烷基; n为5-45的整数; m为5〜45的整数。

    Method of Melt Blending Curable Polymer Compositions Using Silicone Hydrides
    2.
    发明申请
    Method of Melt Blending Curable Polymer Compositions Using Silicone Hydrides 失效
    使用硅氢化合物熔融混合可固化聚合物组合物的方法

    公开(公告)号：US20090221753A1

    公开(公告)日：2009-09-03

    申请号：US12040487

    申请日：2008-02-29

    申请人： Tonson Abraham ,  Edward Blok ,  Kuo-Shein Shen ,  Norman Glenn Barber

    发明人： Tonson Abraham ,  Edward Blok ,  Kuo-Shein Shen ,  Norman Glenn Barber

    IPC分类号： C08L47/00 ,  C08F8/00 ,  C08L27/22 ,  C07F7/08

    CPC分类号： C08F8/42 ,  C08L21/00 ,  C08L23/16 ,  C08L83/04 ,  C08L83/00

    摘要： Provided in one aspect is a method of melt blending comprising providing an extruder possessing addition points from a zero point to a 100 point the length of the extruder; adding at least one thermoplastic and at least one curable polymer at the zero to 10 point of the extruder; adding at least one silicone hydride at the 5 to 30 point of the extruder; adding at least one metal catalyst at the 20 to 60 point of the extruder, with the proviso that the metal catalyst is added at least 5 points farther down the extruder than the silicone hydride. Provided in another aspect is a hydrosilylation curative composition comprising a silicone hydride having the formula wherein H is hydrogen, and each R′ is independently selected from hydrogen and C1 to C10 alkyl groups; R″ is selected from C1 to C10 alkyl groups; n is an integer from 5 to 45; and m is an integer from 5 to 45.

    摘要翻译： 在一方面提供一种熔融共混方法，其包括提供挤出机，该挤出机具有从挤压机的零点到100点的添加点; 在挤出机的零点至10点加入至少一种热塑性和至少一种可固化聚合物; 在挤出机的5至30℃加入至少一种硅氢化合物; 在挤出机的20至60℃加入至少一种金属催化剂，条件是金属催化剂在挤出机上比硅氢化合物加入至少5点。 另一方面提供了一种氢化硅烷化固化剂组合物，其包含具有下式的硅氢化合物，其中H是氢，并且每个R'独立地选自氢和C 1至C 10烷基; R“选自C1至C10烷基; n为5-45的整数; m为5〜45的整数。

    Soft thermoplastic elastomers
    3.
    发明授权
    Soft thermoplastic elastomers 有权
    软质热塑性弹性体

    公开(公告)号：US07276559B2

    公开(公告)日：2007-10-02

    申请号：US11012753

    申请日：2004-12-15

    申请人： Tonson Abraham ,  Kuo-Shein Shen ,  Norman G. Barber

    发明人： Tonson Abraham ,  Kuo-Shein Shen ,  Norman G. Barber

    IPC分类号： C08L23/00 ,  C08L23/04 ,  C08L9/00

    CPC分类号： C08L23/16 ,  C08L23/0815 ,  C08L23/10 ,  C08L2205/02 ,  C08L2312/00 ,  C08L2666/06

    摘要： This invention relates to a soft thermoplastic vulcanizate composition comprising: a) from about 2-10 wt %, based upon total polymer content weight a)+b)+c), of a thermoplastic polyethylene or polypropylene homopolymer, or ethylene-propylene copolymer, or copolymer that includes ethylene or propylene together with one or more C4 to C20 α-olefins, said thermoplastic having at least 25% crystallinity by DSC; b) from about 15 to about 36 wt. %, based upon total polymer content weight a)+b)+c), of an ethylene-α-olefin random or block copolymer thermoplastic having less than 5% crystallinity by DSC; c) from about 60 to about 80 wt. %, based upon total polymer content weight a)+b)+c), of a cross-linked elastomer; and d) from about 50 to about 65 wt %, based upon total composition weight a)+b)+c)+d), of a process oil; wherein said thermoplastic vulcanizate composition has a Shore A Hardness of less than 35. The invention compositions may also comprise from about 0 to about 40 wt. %, based upon the total composition weight, of conventional additives.

    摘要翻译： 软质热塑性硫化橡胶组合物本发明涉及一种软质热塑性硫化橡胶组合物，其包含：a）约2-10重量％，基于热塑性聚乙烯或聚丙烯均聚物或乙烯 - 丙烯共聚物的总聚合物含量重量a）+ b）+ c） 或共聚物，其包括乙烯或丙烯与一种或多种C 4至C 20α-烯烃，所述热塑性材料通过DSC具有至少25％的结晶度; b）约15至约36重量％ ％，基于通过DSC具有小于5％结晶度的乙烯-α-烯烃无规或嵌段共聚物热塑性聚合物的总重量a）+ b）+ c）的总重量％ c）约60至约80wt。 ％，基于交联弹性体的总聚合物含量重量a）+ b）+ c）; 和d）基于加工油的总组合物重量a）+ b）+ c）+ d）的约50至约65重量％ 其中所述热塑性硫化橡胶组合物的肖氏A硬度小于35.本发明组合物还可以包含约0至约40wt。 ％，基于总组合物重量，常规添加剂。

    Soft thermoplastic elastomers
    4.
    发明申请
    Soft thermoplastic elastomers 有权
    软质热塑性弹性体

    公开(公告)号：US20050277735A1

    公开(公告)日：2005-12-15

    申请号：US11012753

    申请日：2004-12-15

    申请人： Tonson Abraham ,  Kuo-Shein Shen ,  Norman Barber

    发明人： Tonson Abraham ,  Kuo-Shein Shen ,  Norman Barber

    IPC分类号： C08L23/10 ,  C08L37/00

    CPC分类号： C08L23/16 ,  C08L23/0815 ,  C08L23/10 ,  C08L2205/02 ,  C08L2312/00 ,  C08L2666/06

    摘要： This invention relates to a soft thermoplastic vulcanizate composition comprising: a) from about 2-10 wt %, based upon total polymer content weight a)+b)+c), of a thermoplastic polyethylene or polypropylene homopolymer, or ethylene-propylene copolymer, or copolymer that includes ethylene or propylene together with one or more C4 to C20 α-olefins, said thermoplastic having at least 25% crystallinity by DSC; b) from about 15 to about 36 wt. %, based upon total polymer content weight a)+b)+c), of an ethylene-α-olefin random or block copolymer thermoplastic having less than 5% crystallinity by DSC; c) from about 60 to about 80 wt. %, based upon total polymer content weight a)+b)+c), of a cross-linked elastomer; and d) from about 50 to about 65 wt %, based upon total composition weight a)+b)+c)+d), of a process oil; wherein said thermoplastic vulcanizate composition has a Shore A Hardness of less than 35. The invention compositions may also comprise from about 0 to about 40 wt. %, based upon the total composition weight, of conventional additives.

    摘要翻译： 软质热塑性硫化橡胶组合物本发明涉及一种软质热塑性硫化橡胶组合物，其包含：a）约2-10重量％，基于热塑性聚乙烯或聚丙烯均聚物或乙烯 - 丙烯共聚物的总聚合物含量重量a）+ b）+ c） 或共聚物，其包括乙烯或丙烯与一种或多种C 4至C 20α-烯烃，所述热塑性材料通过DSC具有至少25％的结晶度; b）约15至约36重量％ ％，基于通过DSC具有小于5％结晶度的乙烯-α-烯烃无规或嵌段共聚物热塑性聚合物的总重量a）+ b）+ c）的总重量％ c）约60至约80wt。 ％，基于交联弹性体的总聚合物含量重量a）+ b）+ c）; 和d）基于加工油的总组合物重量a）+ b）+ c）+ d）的约50至约65重量％ 其中所述热塑性硫化橡胶组合物的肖氏A硬度小于35.本发明组合物还可以包含约0至约40wt。 ％，基于总组合物重量，常规添加剂。

    Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders
    5.
    发明申请
    Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders 有权
    通过动态硫化在多螺杆挤出机中制备热塑性弹性体

    公开(公告)号：US20060293457A1

    公开(公告)日：2006-12-28

    申请号：US11167339

    申请日：2005-06-27

    申请人： Hari Nadella ,  Jianya Cheng ,  Ronald DeYoung ,  Kuo-Shein Shen

    发明人： Hari Nadella ,  Jianya Cheng ,  Ronald DeYoung ,  Kuo-Shein Shen

    IPC分类号： C08F8/00

    CPC分类号： B29C47/38 ,  B29C47/0009 ,  B29C47/402 ,  B29C47/42 ,  B29C47/6031 ,  B29C47/605 ,  B29C47/6056 ,  C08L23/10 ,  C08L23/16 ,  C08L2312/08 ,  C08L2666/06

    摘要： The invention relates to a method of preparing a thermoplastic vulcanizate comprising: a) melt processing a blend of thermoplastic polymer and vulcanizable elastomer in a multi-screw extruder having at least three intermeshing screws, wherein said screws have 3-170 mixing zones, and said extruder having a L/D ratio of 15-100, and a screw profile that has 3 to 17 meshes per L/D; b) adding at least one curing agent to the melt-processed blend of a) in at least one location in the first 46% of the length of said extruder, or adding at least one curing agent to the melt-processed blend of a) in a second extruder, so as to initiate curing of the blend: and, curing at least partially said elastomer by reactive melt processing. Improved processing, reaction kinetics and efficiencies are achieved, as well as thermoplastic vulcanizate products having decreased weight gain when placed in mineral oils.

    摘要翻译： 本发明涉及一种制备热塑性硫化橡胶的方法，包括：a）在具有至少三个啮合螺钉的多螺杆挤出机中熔融加工热塑性聚合物和可硫化弹性体的共混物，其中所述螺杆具有3-170个混合区，并且所述 L / D比为15-100的挤出机和每L / D具有3至17目的螺杆型材; b）在所述挤出机的长度的前46％的至少一个位置向a）的熔融加工混合物中加入至少一种固化剂，或向熔融加工的混合物中加入至少一种固化剂，a） 在第二挤出机中，以引发共混物的固化;以及通过反应性熔体加工至少部分地固化所述弹性体。 实现了改进的加工，反应动力学和效率，以及当放置在矿物油中时具有降低的重量增加的热塑性硫化产品。

    Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders
    8.
    发明授权
    Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders 有权
    通过动态硫化在多螺杆挤出机中制备热塑性弹性体

    公开(公告)号：US07655728B2

    公开(公告)日：2010-02-02

    申请号：US11167339

    申请日：2005-06-27

    申请人： Hari P. Nadella ,  Jianya Cheng ,  Ronald DeYoung ,  Kuo-Shein Shen

    发明人： Hari P. Nadella ,  Jianya Cheng ,  Ronald DeYoung ,  Kuo-Shein Shen

    IPC分类号： C08L23/00 ,  C08L23/10 ,  C08F8/00

    CPC分类号： B29C47/38 ,  B29C47/0009 ,  B29C47/402 ,  B29C47/42 ,  B29C47/6031 ,  B29C47/605 ,  B29C47/6056 ,  C08L23/10 ,  C08L23/16 ,  C08L2312/08 ,  C08L2666/06

    摘要： The invention relates to a method of preparing a thermoplastic vulcanizate comprising: a) melt processing a blend of thermoplastic polymer and vulcanizable elastomer in a multi-screw extruder having at least three intermeshing screws, wherein said screws have 3-170 mixing zones, and said extruder having a L/D ratio of 15-100, and a screw profile that has 3 to 17 meshes per L/D; b) adding at least one curing agent to the melt-processed blend of a) in at least one location in the first 46% of the length of said extruder, or adding at least one curing agent to the melt-processed blend of a) in a second extruder, so as to initiate curing of the blend: and, curing at least partially said elastomer by reactive melt processing. Improved processing, reaction kinetics and efficiencies are achieved, as well as thermoplastic vulcanizate products having decreased weight gain when placed in mineral oils.

    摘要翻译： 本发明涉及一种制备热塑性硫化橡胶的方法，包括：a）在具有至少三个啮合螺钉的多螺杆挤出机中熔融加工热塑性聚合物和可硫化弹性体的共混物，其中所述螺杆具有3-170个混合区，并且所述 L / D比为15-100的挤出机和每L / D具有3至17目的螺杆型材; b）在所述挤出机的长度的前46％的至少一个位置向a）的熔融加工混合物中加入至少一种固化剂，或向熔融加工的混合物中加入至少一种固化剂，a） 在第二挤出机中，以引发共混物的固化;以及通过反应性熔体加工至少部分地固化所述弹性体。 实现了改进的加工，反应动力学和效率，以及当放置在矿物油中时具有降低的重量增加的热塑性硫化产品。