Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same
    5.
    发明授权
    Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same 失效
    用于脱硝的​​热处理活性炭,其制造方法,使用其的脱硝方法和使用其的脱硝系统

    公开(公告)号:US07655204B2

    公开(公告)日:2010-02-02

    申请号:US12292273

    申请日:2008-11-14

    IPC分类号: B01D53/56

    摘要: This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.

    摘要翻译: 本发明涉及一种除去从锅炉等排出的废气中存在的氮氧化物(NOx)的技术。 当废气的温度为100℃以下时,通过在非氧化性气氛中将600〜1200℃的原料活性炭进行热处理而除去含氧的热处理活性炭 优选使用其表面存在的官能团,从而将原子表面氧/表面碳比降低至0.05以下。 当废气温度超过100℃时,通过在非氧化性气氛中将原料活性炭在600〜1200℃下热处理而生成的热处理活性炭,并用硫酸或 优选使用硝酸赋予其氧化性含氧官能团。

    Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same
    6.
    发明申请
    Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same 失效
    用于脱硝的​​热处理活性炭,其制造方法,使用其的脱硝方法和使用其的脱硝系统

    公开(公告)号:US20090081097A1

    公开(公告)日:2009-03-26

    申请号:US12292273

    申请日:2008-11-14

    IPC分类号: B01D53/56

    摘要: This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.

    摘要翻译: 本发明涉及一种除去从锅炉等排出的废气中存在的氮氧化物(NOx)的技术。 当废气的温度为100℃以下时,通过在非氧化性气氛中将600〜1200℃的原料活性炭进行热处理而除去含氧的热处理活性炭 优选使用其表面存在的官能团,从而将原子表面氧/表面碳比降低至0.05以下。 当废气温度超过100℃时,通过在非氧化性气氛中将原料活性炭在600〜1200℃下热处理而生成的热处理活性炭,并用硫酸或 优选使用硝酸赋予其氧化性含氧官能团。

    Heat-treated active carbons for use in denitration, processes for
producing same denitration method using same, and denitration systems
using same
    7.
    发明授权
    Heat-treated active carbons for use in denitration, processes for producing same denitration method using same, and denitration systems using same 失效
    用于脱硝的​​热处理活性炭,使用相同脱硝方法的方法以及使用其的脱硝系统

    公开(公告)号:US6127312A

    公开(公告)日:2000-10-03

    申请号:US817659

    申请日:1997-04-22

    IPC分类号: B01D53/86 B01J21/18 C01B31/08

    摘要: This invention relates to a technique for removing nitrogen oxides (NO.sub.x) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100.degree. C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200.degree. C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100.degree. C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200.degree. C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.

    摘要翻译: PCT No.PCT / JP96 / 02737第 371日期1997年04月22日 102(e)1997年4月22日PCT PCT 1996年9月24日PCT公布。 公开号WO97 / 12671 日期1997年04月10日本发明涉及一种除去从锅炉等排出的排气中存在的氮氧化物(NOx)的技术。 当废气的温度为100℃以下时,通过在非氧化性气氛中在600〜1200℃下热处理原料活性炭而生成的热处理活性炭,以除去含氧的 优选使用其表面存在的官能团,从而将原子表面氧/表面碳比降低至0.05以下。 当废气的温度超过100℃时,将热处理的活性炭在600-2200℃下在非氧化性气氛中热处理,并将其表面用硫酸或 优选使用硝酸赋予其氧化性含氧官能团。

    Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same
    8.
    发明授权
    Heat-treated active carbons for use in denitration, processes for producing same, denitration method using same, and denitration system using same 有权
    用于脱硝的​​热处理活性炭,其制造方法,使用其的脱硝方法和使用其的脱硝系统

    公开(公告)号:US07465429B2

    公开(公告)日:2008-12-16

    申请号:US10081208

    申请日:2002-02-25

    IPC分类号: B01J8/02

    摘要: This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600. to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.

    摘要翻译: 本发明涉及一种除去从锅炉等排出的废气中存在的氮氧化物(NOx)的技术。 当废气的温度为100℃以下时,通过在非氧化性气氛中将600〜1200℃的原料活性炭进行热处理而除去含氧的热处理活性炭 优选使用其表面存在的官能团,从而将原子表面氧/表面碳比降低至0.05以下。 当废气的温度超过100℃时,通过在非氧化性气氛中将原料活性炭在600〜1200℃下热处理而生成的热处理活性炭,并用硫酸使其表面活化 或硝酸以赋予氧化性的含氧官能团。

    Exhaust gas treating systems
    9.
    发明授权
    Exhaust gas treating systems 失效
    废气处理系统

    公开(公告)号:US06814948B1

    公开(公告)日:2004-11-09

    申请号:US09642009

    申请日:2000-08-21

    IPC分类号: B01D5360

    摘要: An active carbon for use in the treatment of exhaust gas can be obtained by heat-treating a starting active carbon fiber derived from polyacrylonitrile, pitch or the like or a starting particulate active carbon in a non-oxidizing atmosphere. The heat-treating temperature is preferably in the range of 600 to 1,200 ° C. for use in the desulfurization of exhaust gas, and in range of 600 to 1,000° C. for use in the denitration of exhaust gas. By using the resulting heat-treated active carbon for the purpose of desulfurization, the sulfur oxide concentration in exhaust gas can be reduced to 5 ppm or below. Moreover, by using the heat-treated active carbon in combination with conventional denitration based on selective catalytic reduction, the nitrogen oxide concentration in exhaust gas can be reduced to 1 ppm or below.

    摘要翻译: 用于废气处理的活性炭可以通过在非氧化性气氛中热处理由聚丙烯腈,沥青等衍生的起始活性炭纤维或起始粒状活性炭来获得。 在废气脱硫中的热处理温度优选为600〜1200℃,在废气脱硝中为600〜1000℃。 通过使用得到的经热处理的活性炭进行脱硫,排气中的硫氧化物浓度可以降低到5ppm以下。 此外,通过使用经热处理的活性炭与基于选择性催化还原的常规脱硝组合,废气中的氮氧化物浓度可以降低至1ppm或更低。

    Exhaust gas denitration method
    10.
    发明授权
    Exhaust gas denitration method 失效
    废气脱硝方法

    公开(公告)号:US06383463B1

    公开(公告)日:2002-05-07

    申请号:US09214657

    申请日:1999-01-07

    IPC分类号: B01D5354

    CPC分类号: B01D53/8631

    摘要: A process for the denitration of combustion exhaust gas from combustion equipment by passing the exhaust gas through an ammonia reduction denitrator, comprises providing a bypass having a low-temperature denitrator installed therein; while the temperature of the exhaust gas is not high enough to allow the ammonia reduction denitrator to function properly, as encountered immediately after starting the combustion equipment, passing the exhaust gas through the bypass to perform the denitration thereof by means of the low-temperature denitrator; when the ammonia reduction denitrator has come to function properly, closing the bypass to perform the denitration of the exhaust gas by means of the ammonia reduction denitrator; and regenerating a catalyst within said low-temperature denitrator while the by-pass is closed.

    摘要翻译: 一种通过使废气通过氨还原脱硝器将来自燃烧设备的燃烧废气脱硝的方法,包括提供其中安装有低温脱硝器的旁路; 而排气的温度不够高以使得氨还原脱硝机能正常工作,如在启动燃烧设备之后立即遇到的那样,废气通过旁路通过低温脱硝器进行脱硝 ; 当氨还原脱硝机功能正常时,关闭旁路,通过氨还原脱硝机进行排气脱硝; 并且在旁路关闭的同时在所述低温脱硝机内再生催化剂。