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1.发明授权Method for the preparation of an organosiloxane oligomer and a novel organosiloxane oligomer thereby 失效由此制备有机硅氧烷低聚物和新型有机硅氧烷低聚物的方法
公开(公告)号：US4727172A
公开(公告)日：1988-02-23
申请号：US905576
申请日：1986-09-09
IPC分类号： C07F7/08
CPC分类号： C07F7/0852 , C07F7/0874
摘要： An efficient method is proposed for the preparation of an organosiloxane oligomer represented by the general formula YSi(R.sup.1).sub.n (--O--SiR.sub.3).sub.3-n, in which each of the groups denoted by R and R.sup.1 is a halogen-substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, Y is a hydrogen atom or a monovalent group selected from methyl, phenyl, vinyl, chloromethyl and 3-(meth)acryloxypropyl groups and n is zero, 1 or 2, by the reaction of an organosilicon halomagnesium salt of the formula R.sub.3 Si--O--MgX, in which X is a halogen atom, and an organosilane compound of the general formula YSi(R.sup.1).sub.n (Z).sub.3-n, in which Z is a halogen atom or a lower alkoxy group. In particular, tetrasiloxane compounds represented by the general formula Y.sup.1 Si[--O--Si(CH.sub.3).sub.2 (CH.sub.2 CH.sub.2 CF.sub.3)].sub.3, in which Y.sup.1 is a hydrogen atom, chloromethyl group or 3-methacryloxypropyl group, are each a novel compound not known in the prior art.
摘要翻译： 提出了制备由通式YSi（R1）n（-O-SiR 3）3-n表示的有机硅氧烷低聚物的有效方法，其中由R和R 1表示的每个基团是卤素取代或未取代的 具有1至8个碳原子的一价烃基，Y是氢原子或选自甲基，苯基，乙烯基，氯甲基和3-（甲基）丙烯酰氧基丙基的一价基团，并且n为0,1或2，通过 其中X为卤素原子的式R3Si-O-MgX的有机硅卤镁盐和通式YSi（R1）n（Z）3-n的有机硅烷化合物，其中Z为卤素原子或低级 烷氧基。 特别地，由通式Y1Si [-O-Si（CH3）2（CH2CH2CF3）] 3表示的四硅氧烷化合物，其中Y 1为氢原子，氯甲基或3-甲基丙烯酰氧基丙基，均为未知的新化合物 现有技术
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公开(公告)号：US4649185A
公开(公告)日：1987-03-10
申请号：US798757
申请日：1985-11-15
摘要： The contact lens of the invention is shaped of a poly(trimethylvinylsilane) resin having an average molecular weight of at least 200,000 or a copolymer based thereon. The contact lens has a very high oxygen permeability comparable to conventional transparent silicone rubbers so as to ensure a long time of continued wearing of the lens on the cornea with no adverse physiological influences and the material still has much better mechanical workability for precision shaping into a lens form than the transparent silicone rubbers.
摘要翻译： 本发明的隐形眼镜成型为平均分子量至少为200,000的聚（三甲基乙烯基硅烷）树脂或基于其的共聚物。 隐形眼镜具有与传统的透明硅橡胶相当的非常高的氧透过率，以便确保镜片在角膜上持续磨损的长时间，没有不利的生理影响，并且该材料仍然具有更好的机械加工性，用于精确成形为 透镜形式比透明硅橡胶。
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公开(公告)号：US4593112A
公开(公告)日：1986-06-03
申请号：US723669
申请日：1985-04-16
CPC分类号： C07F7/16 , C07F7/0896
摘要： A tert-hydrocarbyl, e.g. tert-butyl, silyl compound can be synthesized easily according to the method of the invention in which a tert-hydrocarbylmagnesium halide as a Grignard reagent is reacted with a silane compound having at least one silicon-bonded hydrogen atom and at least one silicon-bonded halogen atom simultaneously in a molecule in a suitable organic solvent so that the halogen atom in the latter reactant is replaced with the tert-hydrocarbyl group in the former reactant to give the desired tert-hydrocarbyl silyl compound in a high yield without the safety problem in the conventional method using a tert-alkyl lithium as the reactant.
摘要翻译： 叔烃基，例如 可以根据本发明的方法容易地合成叔丁基甲硅烷基化合物，其中作为格氏试剂的叔烃基卤化镁与具有至少一个与硅键合的氢原子的硅烷化合物和至少一个硅键合的硅烷化合物反应 卤素原子在合适的有机溶剂中在分子中同时进行，使得后一反应物中的卤素原子被前反应物中的叔烃基取代，以高产率得到所需的叔烃基甲硅烷基化合物，而没有安全问题 使用叔烷基锂作为反应物的常规方法。
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4.发明授权Vinylsilyl group-containing monodisperse polymeric compound and a method for the preparation thereof 失效含有乙烯基甲硅烷基的单分散高分子化合物及其制备方法
公开(公告)号：US4758640A
公开(公告)日：1988-07-19
申请号：US861739
申请日：1986-05-07
IPC分类号： C08F30/00 , C08F2/04 , C08F2/06 , C08F4/46 , C08F4/50 , C08F30/08 , C08F290/00 , C08F299/00 , C08F299/08 , G03C5/08 , G03F7/004 , G03F7/038 , G03F7/075 , C08F230/08
CPC分类号： G03F7/0758 , C08F30/08
摘要： The invention provides a novel polymeric compound having crosslinkability by irradiation with actinic rays, e.g. ultraviolet light, and useful as a polymeric base ingredient of a negative type photoresist composition with high sensitivity and resistance against dry etching. The polymer is obtained by the anionic living polymerization of a vinylsilyl group-containing styrene derivative of the formulaCH.sub.2 .dbd.CH--C.sub.6 H.sub.4 --CH.sub.2).sub.n SiR.sub.2 --CH.dbd.CH.sub.2,in which R is a monovalent hydrocarbon group, e.g. methyl and phenyl, and n is an integer of 0 to 3, in a specific solvent in the presence of a specific polymerization initiator so that the polymerization takes place only at the styrenic vinyl groups leaving the silicon-bonded vinyl groups unpolymerized. Quite unexpectedly, the polymer has a very uniform monodisperse distribution of the molecular weight.
摘要翻译： 本发明提供了通过用光化射线照射具有交联性的新型聚合物，例如 紫外光，并且可用作具有高灵敏度和抗干蚀刻性的负型光致抗蚀剂组合物的聚合基底成分。 该聚合物通过式CH 2 = CH-C 6 H 4 -CH 2）n SiR 2 -CH = CH 2的含乙烯基甲硅烷基的苯乙烯衍生物的阴离子活性聚合获得，其中R是一价烃基，例如， 甲基和苯基，n为0〜3的整数，在特定的溶剂中，在特定的聚合引发剂的存在下，仅在苯乙烯基的乙烯基上进行聚合，离开与硅键合的乙烯基未聚合。 非常出人意料地，聚合物具有非常均匀的单分散分子量分布。
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公开(公告)号：US4588832A
公开(公告)日：1986-05-13
申请号：US682267
申请日：1984-12-17
IPC分类号： C07F7/08
CPC分类号： C07F7/0827
摘要： The invention provides a novel and economical route for the synthetic preparation of a 1-alkynyl trihydrocarbyl silane compound. The method comprises the steps of reacting metallic sodium with a hydrocarbyl-substituted acetylene or allene compound to form a substituted sodium acetylide and reacting the acetylide with a trihydrocarbyl monohalogenosilane in the reaction mixture which is admixed with a polar organic solvent such as dimethylformamide.
摘要翻译： 本发明提供了用于合成制备1-炔基三烃基硅烷化合物的新颖且经济的途径。 所述方法包括使金属钠与烃基取代的乙炔或二烯化合物反应以形成取代的乙炔化钠，并将该乙炔化物与三烃基一卤代硅烷反应在与极性有机溶剂如二甲基甲酰胺混合的反应混合物中。
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公开(公告)号：US4869747A
公开(公告)日：1989-09-26
申请号：US651599
申请日：1984-09-17
CPC分类号： A01N55/00
摘要： A novel method for accelerating growth of a plant in agriculture and forestry is proposed in which an organosilicon compound .omega.-carboxyalkylsilicon sesquioxide, e.g. 2-carboxyethylsilicon sesquioxide, of the unit formulaHOOC(CH.sub.2).sub.n SiO.sub.1.5,in which n is a positive integer of 1 to 4, is applied to the plant directly or to the soil in which the plant is growing. The metal salts or complexes of the above compound as well as the precursor compounds thereof readily convertible to the silsesquioxide compound by hydrolysis are also effective.
摘要翻译： 提出了一种用于加速农业和林业中植物生长的新方法，其中有机硅化合物ω-羧甲基硅氧烷倍半氧化物，例如， 其中n为1〜4的正整数的单元式HOOC（CH 2）n SiO 1.5的2-羧乙基硅氧烷倍半氧化物直接施用于植物或植物生长的土壤。 上述化合物的金属盐或络合物及其通过水解容易地转化为二氧化硅化合物的前体化合物也是有效的。
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7.发明授权Poly(dimethylsilmethylene) methylacetylene compound and a method for the preparation thereof 失效聚（二甲基亚甲硅烷基）甲基乙炔化合物及其制备方法
公开(公告)号：US4539417A
公开(公告)日：1985-09-03
申请号：US658597
申请日：1984-10-09
CPC分类号： C07F7/0809 , C08G77/60
摘要： The invention provides a novel organosilicon compound poly(dimethylsilmethylene) methylacetylene compound of the formula MeC.tbd.C--SiMe.sub.2 --CH.sub.2 --SiMe.sub.2).sub.n Me, in which Me is a methyl group and n is a positive integer of 1 to 25. The compound is synthesized by reacting a propynylmagnesium halide of the formula MeC.tbd.CMgX, in which X is a halogen atom, or (propynyl dimethylsilyl)methylmagnesium chloride of the formula MeC.tbd.C--SiMe.sub.2 --CH.sub.2 MgCl with chloromethyl dimethyl chlorosilane in the presence of metallic magnesium and hydrolyzing the reaction product. Specifically, 1-propynyl-1,1,3,3,3-pentamethyl disilmethylene, i.e. the inventive compound with n=1, is synthesized by reacting (propynyl dimethylsilyl)methylmagnesium chloride with trimethyl chlorosilane.
摘要翻译： 本发明提供了一种新颖的有机硅化合物，具有式MeC 3BOND C-SiMe2-CH2-SiMe2）nMe的聚（二甲基亚甲硅烷基）甲基乙炔化合物，其中Me是甲基，n是1至25的正整数。该化合物被合成 通过在金属镁的存在下使式MeC 3BOND CMgX（其中X是卤素原子）的丙炔基卤化镁或式MeC 3BOND C-SiMe2-CH2MgCl的（丙炔基二甲基甲硅烷基）甲基氯化镁与氯甲基二甲基氯硅烷反应，并水解 反应产物。 具体地，1-丙炔基-1,1,3,3,3-五甲基二亚甲基，即n = 1的本发明化合物，通过（丙炔基二甲基甲硅烷基）甲基氯化镁与三甲基氯硅烷反应合成。
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公开(公告)号：US4883569A
公开(公告)日：1989-11-28
申请号：US154691
申请日：1988-02-11
CPC分类号： C07F7/0801 , C07F7/14 , C07F7/1876
摘要： Cycloalkyl silane compound such as cyclohexyl methyl dichlorosilane can be efficiently prepared by the photochemically induced hydrosilylation reaction. For example, an equimolar mixture of cyclohexene and methyl dichlorosilane with admixture of a catalytic amount of an alcoholic solution of, chloroplatinic acid, is irradiated at a temperature up to 70.degree. C. with ultraviolet light so that the hydrosilylation reaction takes place and proceeds almost to completeness without deactivation of the platinum catalyst to give the desired product in a yield of 90% or even higher.
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9.发明授权(Phenyl dimethyl carbinyl) silane compound and a method for the preparation thereof 失效（苯基二甲基卡必）硅烷化合物及其制备方法
公开(公告)号：US4748262A
公开(公告)日：1988-05-31
申请号：US91885
申请日：1987-09-01
申请人： Toshinobu Ishihara , Minoru Takamizawa , Mikio Endo , Toru Kubota
发明人： Toshinobu Ishihara , Minoru Takamizawa , Mikio Endo , Toru Kubota
CPC分类号： C07F7/12 , C07F7/1832
摘要： The invention provides organosilane compounds of a novel class having one or two (phenyl dimethyl carbinyl) groups bonded to the silicon atom as represented by the general formula (PhMe.sub.2 C).sub.p R.sub.q X.sub.r Si, in which Ph is a phenyl group, Me is a methyl group, R is a monovalent hydrocarbon group selected from the class consisting of alkyl, alkenyl and aryl groups, X is a halogen atom or an alkoxy group, p is 1 or 2, q is zero, 1 or 2 and r is zero, 1, 2 or 3 with the proviso that p+q+r=4. The compound can be prepared by the reaction of a Grignard reagent PhMe.sub.2 C. MgY, in which Y is a halogen atom, with a silane compound represented by the general formula R.sub.q SiX.sub.4-q in an organic solvent.
摘要翻译： 本发明提供了具有如下通式（PhMe2C）pRqXrSi所表示的具有一个或两个与硅原子键合的（苯基二甲基碳酰基）基团的有机硅烷化合物，其中Ph是苯基，Me是甲基，R 是选自烷基，烯基和芳基的一价烃基，X是卤素原子或烷氧基，p是1或2，q是0,1或2，r是0,1,2或者 3，条件是p + q + r = 4。 化合物可以通过格氏试剂PhMe2C的反应来制备。 其中Y为卤原子的MgY与通式为RqSiX4-q表示的硅烷化合物在有机溶剂中反应。
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公开(公告)号：US4657991A
公开(公告)日：1987-04-14
申请号：US787328
申请日：1985-10-15
IPC分类号： C08L83/00 , C04B35/571 , C08G79/00 , C08L83/02 , C08L83/16 , D01F9/10 , C08F283/00
CPC分类号： C08G79/00 , C04B35/571 , C08L83/16
摘要： The precursor composition of silicon carbide fibers provided by the invention has greatly improved spinnability and can be spun at a very high spinning velocity to give a green filament which has a much larger tensile strength than those of conventional precursor materials and is capable of giving silicon carbide fibers having increased tensile strength by the infusibilization and calcination of the green filament of the composition under tension. The composition comprises from 80 to 99.9 parts by weight of a polycarbosilane polymer and from 20 to 0.01 part by weight of a silmethylene polymer having a degree of polymerization larger than the specified lower limit.
摘要翻译： 由本发明提供的碳化硅纤维的前体组合物大大提高了可纺性，并且可以以非常高的纺丝速度纺丝，得到具有比常规前体材料高的拉伸强度的绿色长丝，并且能够提供碳化硅 纤维通过在张力下的组合物的绿色细丝的不熔化和煅烧而具有增加的拉伸强度。 该组合物包含80-99.9重量份的聚碳硅烷聚合物和20至0.01重量份具有大于规定下限的聚合度的硅亚甲基聚合物。
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