摘要:
A method for testing a precursor of a secondary cell with high reliability and high efficiency to judge the precursor to be acceptable or defective. The current flowing when a test voltage is applied between a pair of electrodes is measured before an electrolyte is placed between the electrodes. If a current the current value of which exceeds a predetermined reference current value (13) is detected during the time from the start of application of a voltage to a normal secondary cell precursor until the current becomes constant, the precursor is determined to be defective.
摘要:
A method for testing a precursor of a secondary cell with high reliability and high efficiency to judge the precursor to be acceptable or defective. The current flowing when a test voltage is applied between a pair of electrodes is measured before an electrolyte is placed between the electrodes. If a current the current value of which exceeds a predetermined reference current value (13) is detected during the time from the start of application of a voltage to a normal secondary cell precursor until the current becomes constant, the precursor is determined to be defective.
摘要:
A lithium ion secondary battery with improved safety against both internal short-circuiting and overcharge is provided. This lithium ion secondary battery includes a positive electrode comprising a composite lithium oxide, a negative electrode, and a non-aqueous electrolyte. At least one of the positive electrode and the negative electrode has a porous film, comprising an inorganic oxide filler and a binder, on the surface facing the other electrode, and the electrode surface having the porous film partially has a protruded part. This protruded part may be a protruded part formed on the porous film itself or a protruded part formed on an electrode mixture layer. Further, a separator can also be incorporated therein. Instead of the above-mentioned porous film, the separator can be provided with a porous film.
摘要:
An object of the present invention is to provide an electrode for a lithium ion secondary battery that can ensure a high level of safety even when exposed to severe conditions such as a nail penetration test or crush test, and exhibit excellent output characteristics.The present invention relates to an electrode for a lithium ion secondary battery having a material mixture containing active material particles capable of reversibly absorbing and desorbing lithium, and a current collector that carries the material mixture, wherein a surface of the current collector has recessed portions, and an area occupied by the recessed portions accounts for not less than 30% of an a material mixture carrying area of the current collector. The present invention further relates to an electrode for a lithium ion secondary battery wherein, in a cut surface obtained by simultaneously cutting a material mixture and a current collector vertically to an electrode plane, the maximum depth of recessed portions is not less than 1 μm, or a difference between an average thickness of a current collector and a maximum thickness of the current collector is not less than 0.35 μm.
摘要:
An object of the present invention is to provide an electrode for a lithium ion secondary battery that can ensure a high level of safety even when exposed to severe conditions such as a nail penetration test or crush test, and exhibit excellent output characteristics.The present invention relates to an electrode for a lithium ion secondary battery having a material mixture containing active material particles capable of reversibly absorbing and desorbing lithium, and a current collector that carries the material mixture, wherein a surface of the current collector has recessed portions, and an area occupied by the recessed portions accounts for not less than 30% of an a material mixture carrying area of the current collector. The present invention further relates to an electrode for a lithium ion secondary battery wherein, in a cut surface obtained by simultaneously cutting a material mixture and a current collector vertically to an electrode plane, the maximum depth of recessed portions is not less than 1 μm, or a difference between an average thickness of a current collector and a maximum thickness of the current collector is not less than 0.35 μm.
摘要:
A lithium ion secondary battery with improved safety against both internal short-circuiting and overcharge is provided. This lithium ion secondary battery includes a positive electrode comprising a composite lithium oxide, a negative electrode, and a non-aqueous electrolyte. At least one of the positive electrode and the negative electrode has a porous film, comprising an inorganic oxide filler and a binder, on the surface facing the other electrode, and the electrode surface having the porous film partially has a protruded part. This protruded part may be a protruded part formed on the porous film itself or a protruded part formed on an electrode mixture layer. Further, a separator can also be incorporated therein. Instead of the above-mentioned porous film, the separator can be provided with a porous film.
摘要:
An electrode group for a battery including a positive electrode and a negative electrode wound into a spiral with a separator interposed therebetween, wherein the positive electrode includes a positive electrode current collector and positive electrode material mixture layers formed on both sides of the positive electrode current collector, the negative electrode includes a negative electrode current collector and negative electrode material mixture layers formed on both sides of the negative electrode current collector, a lead is connected to at least one of the positive electrode current collector and the negative electrode current collector, and at least one of step portions having difference in level formed in the electrode group by lengthwise ends of the positive electrode, the negative electrode and the separator and the periphery of the lead, respectively, is covered with an insulating member arranged on an inner circumference side or an outer circumference side of a turn of the electrode group.
摘要:
A lithium-containing composite oxide represented by the formula 1: LixNi1-y-z-v-wCoyAlzM1vM2wO2 is used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The element M1 is at least one selected from the group consisting of Mn, Ti, Y, Nb, Mo, and W. The element M2 includes at least two selected from the group consisting of Mg, Ca, Sr, and Ba, and the element M2 includes at least Mg and Ca. The formula 1 satisfies 0.97≦x≦1.1, 0.05≦y≦0.35, 0.005≦z≦0.1, 0.0001≦v≦0.05, and 0.0001≦w≦0.05. The primary particles have a mean particle size of 0.1 μm or more and 3 μm or less, and the secondary particles have a mean particle size of 8 μm or more and 20 μm or less.
摘要翻译:作为非水电解质二次电池用正极活性物质,使用由式1表示的含锂复合氧化物:LixNi1-y-z-v-wCoyAlzM1vM2wO2。 元素M1是选自Mn,Ti,Y,Nb,Mo和W中的至少一种元素。元素M2包括选自Mg,Ca,Sr和Ba中的至少两种元素,并且 元素M2至少包括Mg和Ca。 式1满足0.97 <= x <= 1.1,0.05 <= y <=0.35,0.005≤z≤0.1,0.0001≤v≤0.05,0.0001≤w≤0.05。 初级粒子的平均粒径为0.1μm以上3μm以下,二次粒子的平均粒径为8μm以上且20μm以下。
摘要:
The present invention provides a positive electrode active material for a non-aqueous electrolyte-based secondary battery, composed of a lithium/nickel composite oxide with high capacity, low cost and excellent heat stability, and a high safety non-aqueous electrolyte-based secondary battery. A positive electrode active material, comprising lithium/nickel composite oxide powders obtained by water washing fired powders having the following composition formula (1), followed by filtering and drying: LiNi1-aMaO2 (1) (wherein, M represents at least one kind of an element selected from transition metal elements other than Ni, group 2 elements, or group 13 elements; and “a” satisfies 0.01≦a≦0.5), characterized in that specific surface area of the lithium/nickel composite oxide powders after water washing is 0.3 to 2.0 m2/g.
摘要翻译:本发明提供一种非水电解质型二次电池用正极活性物质,由具有高容量,低成本,优异的热稳定性的锂/镍复合氧化物构成,高安全性非水电解质二次电池 电池。 一种正极活性物质,其包含通过水洗洗涤粉末得到的锂/镍复合氧化物粉末,其具有以下组成式(1),然后过滤和干燥:<?在线公式描述=“在线配方”末端 =“lead”?> LiNi 1-a M a O 2(1)<?in-line-formula description =“In- (式中,M表示选自Ni以外的过渡金属元素,第2族元素或第13族元素中的至少一种元素,“a”满足0.01 <= a < = 0.5),其特征在于,水洗后的锂/镍复合氧化物粉末的比表面积为0.3〜2.0m 2 / g。
摘要:
The present invention provides a positive electrode active material for a non-aqueous electrolyte-based secondary battery, composed of a lithium/nickel composite oxide with high capacity, low cost and excellent heat stability, an industrially suitable production method therefor, and a high safety non-aqueous electrolyte-based secondary battery. A lithium/nickel composite oxide is produced by the following steps (a) to (c): (a) Nickel hydroxide or nickel oxyhydroxide having a specified component is prepared at a temperature of 600 to 1100° C., under air atmosphere. (b) Fired powders are prepared after mixing said nickel oxide and a lithium compound, and then by firing at a maximal temperature range of 650 to 850° C., under oxygen atmosphere. (c) Obtained fired powders are washed with water within a time satisfying the following equation (2) and then filtered and dried. A