公开(公告)号：US5639825A

公开(公告)日：1997-06-17

申请号：US317777

申请日：1994-10-04

申请人： Toshiro Nanbu ,  Hirotoshi Kawaguchi ,  Hisao Furukawa ,  Yasushi Kato

发明人： Toshiro Nanbu ,  Hirotoshi Kawaguchi ,  Hisao Furukawa ,  Yasushi Kato

IPC分类号： C08L43/04 ,  C08L101/06 ,  C08L101/10 ,  C09D133/06 ,  C09D201/10 ,  C08F230/08

CPC分类号： C08L101/10 ,  C08L101/06 ,  C08L43/04 ,  C09D133/066 ,  C09D201/10

摘要： When a thermosetting composition comprising(A) a resin having hydroxyl group,(B) a hydrolyzable silyl group-containing polymer,(C) a hydrolyzable silicon compound and(D) a curing catalyst is used, coating materials having no problem as to bad-smelling can be obtained and the coating films formed therefrom are improved in physical properties such as adhesion, solvent resistance and hardness.

摘要翻译： 当使用包含（A）具有羟基的树脂（B）可水解的含甲硅烷基的聚合物，（C）可水解的硅化合物和（D）固化催化剂）的热固性组合物时，没有问题的涂料 可以获得耐磨性，并且由其形成的涂膜改善了诸如粘合性，耐溶剂性和硬度的物理性能。

公开(公告)号：US5399607A

公开(公告)日：1995-03-21

申请号：US189710

申请日：1994-02-01

申请人： Toshiro Nanbu ,  Hirotoshi Kawaguchi ,  Yasushi Kato ,  Hisao Furukawa

发明人： Toshiro Nanbu ,  Hirotoshi Kawaguchi ,  Yasushi Kato ,  Hisao Furukawa

IPC分类号： C08L33/06 ,  C08L43/04 ,  C08L83/04 ,  C08L101/06 ,  C08L101/10 ,  C09D133/06 ,  C09D143/04 ,  C09D201/10 ,  C08K5/05 ,  C08F230/08

CPC分类号： C09D143/04 ,  C08L101/06 ,  C08L101/10 ,  C08L33/066 ,  C08L43/04 ,  C08L83/04 ,  C09D133/066 ,  C09D201/10 ,  C08G77/42 ,  C08L33/06

摘要： A one component composition suitable for use as coatings which are excellent in storage stability and coating workability, which comprises:(A) an acrylic resin having hydroxyl group,(B) an alkoxysilyl group-containing acrylic copolymer having a group represented by the formula: ##STR1## wherein R.sup.1 is an alkyl group having 1 to 10 carbon atoms, R.sup.2 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms selected from the group consisting of an alkyl group, an aryl group and an aralkyl group, and a is 0, 1 or 2,(C) a curing catalyst, andat least one member selected from the group consisting of (D) a dehydrating agent and (E) an alkyl alcohol.

摘要翻译： 一种适合用作保存稳定性和涂布加工性优异的涂料的单组分组合物，其包括：（A）具有羟基的丙烯酸树脂，（B）具有下式表示的基团的含烷氧基甲硅烷基丙烯酸共聚物： 其中，R 1为碳原子数1〜10的烷基，R 2为氢原子或碳原子数1〜10的选自烷基，芳基和芳烷基的一价烃基， 和（A）为0,1或2，（C）固化催化剂和选自（D）脱水剂和（E）烷基醇中的至少一种。

公开(公告)号：US5344880A

公开(公告)日：1994-09-06

申请号：US13186

申请日：1993-01-29

申请人： Toshiro Nambu ,  Hirotoshi Kawaguchi ,  Hisao Furukawa ,  Yasushi Kato

发明人： Toshiro Nambu ,  Hirotoshi Kawaguchi ,  Hisao Furukawa ,  Yasushi Kato

IPC分类号： C08L33/06 ,  C08L43/04 ,  C08L83/04 ,  C08L83/06 ,  C08L83/10

CPC分类号： C08L33/066 ,  C08L43/04 ,  C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/26 ,  C08G77/28 ,  C08G77/70

摘要： A composition including (A) a hydroxyl group-containing acrylic resin, (B) an acrylic copolymer containing an alkoxysilyl group having the formula (I): ##STR1## (C) a polyorganosiloxane and (D) a curing catalyst. The composition can give the film with excellent weatherability, stain resistance, acid resistance, water repellency and durability and with no bad-smelling odor.

摘要翻译： 包含（A）含羟基的丙烯酸树脂的组合物，（B）含有式（I）的烷氧基​​甲硅烷基的丙烯酸共聚物：（I）（C）聚有机硅氧烷和（D）固化催化剂。 该组合物可以赋予该膜具有优异的耐候性，耐污性，耐酸性，防水性和耐久性，并且没有不良气味。

公开(公告)号：US5063114A

公开(公告)日：1991-11-05

申请号：US505393

申请日：1990-04-06

申请人： Toshiro Nambu ,  Hirotoshi Kawaguchi ,  Hisao Furukawa ,  Yasushi Kato

发明人： Toshiro Nambu ,  Hirotoshi Kawaguchi ,  Hisao Furukawa ,  Yasushi Kato

IPC分类号： C08L43/04 ,  C08L83/04 ,  C09D133/06

CPC分类号： C09D133/066 ,  C08L43/04 ,  C08L83/04 ,  Y10T428/2949 ,  Y10T428/2958 ,  Y10T428/31663

摘要： A coated material obtained by applying a coat containing a metallic powder and/or a coloring pigment to a substrate and further applying a topcoat clear coating thereon, wherein said topcoat clear coating is a heat-hardening coat which contains a composition comprising a hydroxyl group-containing resin, a hydrolyzable silyl group-containing polymer and a hardening catalyst as the main component. This coated material is excellent in, for example, appearance, acid resistance, staining resistance, adhesiveness and hardness.

公开(公告)号：US5459205A

公开(公告)日：1995-10-17

申请号：US132922

申请日：1993-10-07

申请人： Hisao Furukawa ,  Naotami Ando ,  Yasushi Kato

发明人： Hisao Furukawa ,  Naotami Ando ,  Yasushi Kato

IPC分类号： C08F230/08 ,  C08F283/00 ,  C08F299/08 ,  C08F20/00 ,  C07F7/04

CPC分类号： C08F230/08 ,  C08F283/004 ,  C08F299/08

摘要： A curable resin comprising units of at least one prepolymer selected from the group consisting of a prepolymer (C) and a prepolymer (F); the prepolymer (C) having the formula (I): ##STR1## and the prepolymer (F) having the formula (III): ##STR2## The curable resin has the excellent flexibility, solvent resistance and adhesion to organic materials and the properties thereof can be controlled accordingly to desire, in addition to the excellent curability at ordinary temperature, adhesion to inorganic materials and weatherability.

公开(公告)号：US5136029A

公开(公告)日：1992-08-04

申请号：US422719

申请日：1989-10-17

申请人： Hisao Furukawa ,  Katsuhiko Isayama ,  Yasushi Kato

发明人： Hisao Furukawa ,  Katsuhiko Isayama ,  Yasushi Kato

IPC分类号： C07F7/18 ,  C08F2/38 ,  C08F4/04 ,  C08F8/42

CPC分类号： C08F8/42 ,  C07F7/182 ,  C08F4/04 ,  Y10S534/03

摘要： A hydrolyzable silyl group-containing azo compound is represented by the following general formula (I): ##STR1## wherein A represents a group originating from an azo compound having one or more active hydrogen groups;R.sup.1 represents a monovalent organic group;R.sup.2 represents a divalent organic group;X represents a hydrolyzable group;Y represents --O--, --S--, ##STR2## m is an integer of 1 to 3; and n is an integer of 1 or 2;and process for producing the same is disclosed. The hydrolyzable silyl group-containing azo compound is used to prepare a hydrolyzable silyl group-containing vinyl polymer produced by polymerizing vinyl monomer as a radical polymerization initiator.

公开(公告)号：US5110888A

公开(公告)日：1992-05-05

申请号：US423327

申请日：1989-10-18

申请人： Hisao Furukawa ,  Yasushi Kato ,  Jo Kawamura

发明人： Hisao Furukawa ,  Yasushi Kato ,  Jo Kawamura

IPC分类号： C08F8/32 ,  C09D133/14

CPC分类号： C09D133/14 ,  C08F8/32

摘要： A resin composition comprising 5 to 100% by weight of a vinyl copolymer comprising 0.1 to 99% by weight of units having the formula (I): ##STR1## The composition of the invention is excellent in weatherability.

公开(公告)号：US4539359A

公开(公告)日：1985-09-03

申请号：US520685

申请日：1983-08-05

申请人： Yasushi Kato ,  Hisao Furukawa

发明人： Yasushi Kato ,  Hisao Furukawa

IPC分类号： C08F8/42 ,  C08K5/52 ,  C08L57/00 ,  C08L57/06 ,  C09D133/04 ,  C09D143/04 ,  C09D157/06 ,  C09D201/02 ,  C09J11/06 ,  C09J157/06 ,  C09K3/10 ,  C08F8/40

CPC分类号： C09D143/04

摘要： A one component moisture curable composition containing (A) a hydrolyzable silyl group-containing vinyl polymer and (B) an acid phosphoric compound having ##STR1## linkage in the molecule as a hardener, which has excellent recoatability, curing property and adhesion to other paint films and is particularly suitable as a coating composition for use in multicoat coating.

摘要翻译： 含有（A）含水解性甲硅烷基的乙烯基聚合物和（B）分子中具有“IMAGE”键的酸性磷酸化合物作为硬化剂的单组分湿气固化组合物，其具有优异的可再涂性，固化性能和与其它涂料的粘合性 并且特别适用于用于多涂层的涂料组合物。

公开(公告)号：US4518726A

公开(公告)日：1985-05-21

申请号：US365937

申请日：1982-04-05

申请人： Yasushi Kato ,  Hisao Furukawa

发明人： Yasushi Kato ,  Hisao Furukawa

IPC分类号： B32B15/082 ,  C08L1/00 ,  C08L43/04 ,  C09D5/38 ,  C09D133/06 ,  C09D157/06 ,  C09D3/12 ,  C08L83/06 ,  C09D3/82

CPC分类号： C09D133/06 ,  C09D157/06 ,  C09D5/38 ,  C08L1/00 ,  C08L43/04

摘要： A metallic base paint comprising a blend consisting essentially of (A) a silyl group containing vinyl type resin having a backbone substantially comprising a polyvinyl type polymer chain and containing at least one silicon atom attached to a hydrolyzable group at a terminal or in a side chain in its molecule; (B) metal powder; and one or more of the following: (C) acrylic resin; (D) cellulosic compound; (E) reactive silicon compound. This paint can be cured at low temperatures, with setting time, and provides a coated surface of uniform metallic luster.

摘要翻译： 一种金属基漆，其包含基本上由（A）含有甲硅烷基的乙烯基型树脂组成的混合物，所述乙烯基类树脂具有主要包含聚乙烯基型聚合物链的骨架，并且在末端或侧链上连接至可水解基团的至少一个硅原子 在其分子中 （B）金属粉末; 和一种或多种以下物质：（C）丙烯酸树脂; （D）纤维素化合物; （E）反应性硅化合物。 该涂料可以在低温下固化，具有凝固时间，并提供均匀金属光泽的涂层表面。

公开(公告)号：US4507437A

公开(公告)日：1985-03-26

申请号：US564905

申请日：1983-12-23

申请人： Yasushi Kato ,  Hisao Furukawa

发明人： Yasushi Kato ,  Hisao Furukawa

IPC分类号： C08K5/00 ,  C08K5/17 ,  C08K5/52 ,  C08K5/521 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08L101/10 ,  C09D201/02 ,  C09D201/10 ,  C09J11/06 ,  C09J201/10 ,  C09K3/10 ,  C08F8/00

CPC分类号： C08K5/521

摘要： A moisture curable composition comprising (I) a hydrolyzable silyl group-containing vinyl polymer and (II) a combined curing catalyst system of (a) an organic phosphorus-containing compound such as an organic acid phosphate, an organic acid phosphite, or an acid titanium phosphate such as those known as titanate coupling agent and (b) an amine compound. The composition has well balanced pot life and curability and provides a cured product having an excellent appearance, and the curability can be arbitrarily controlled according to the purposes by selecting the ratio of the components (a) and (b).

摘要翻译： 一种防湿固化组合物，其包含（I）含水解性甲硅烷基的乙烯基聚合物和（II）（a）有机磷化合物如有机磷酸酯，有机酸亚磷酸酯或酸的组合固化催化剂体系 磷酸钛如钛酸酯偶联剂和（b）胺化合物。 该组合物具有良好的适用期和固化性，并且提供具有优异外观的固化产物，并且可以通过选择组分（a）和（b）的比例根据目的任意控制固化性。