公开(公告)号：US5321107A

公开(公告)日：1994-06-14

申请号：US143244

申请日：1993-10-29

申请人： Toshiyuki Tsutsui ,  Kazunori Okawa ,  Akinori Toyota

发明人： Toshiyuki Tsutsui ,  Kazunori Okawa ,  Akinori Toyota

IPC分类号： C08F4/648 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/943

摘要： In accordance with the present invention, there are provided an olefin polymerization catalyst formed from:[A] a compound of a transition metal belonging to Group IV B of the periodic table,[B] an aluminoxane, and[C] water,an olefin polymerization catalyst formed from [D] an organoaluminum compound in addition to the above-mentioned [A], [B] and [D] components, and processes for the polymerization of olefins using the above-mentioned olefin polymerization catalysts, respectively.

公开(公告)号：US5340786A

公开(公告)日：1994-08-23

申请号：US151765

申请日：1993-11-15

申请人： Toshiyuki Tsutsui ,  Kazunori Okawa ,  Akinori Toyota

发明人： Toshiyuki Tsutsui ,  Kazunori Okawa ,  Akinori Toyota

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/648

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/943

摘要： In accordance with the present invention, there are provided an olefin polymerization catalyst formed from:[A] a compound of a transition metal belonging to Group IV B of the periodic table,[B] an aluminoxane, and[C] water,an olefin polymerization catalyst formed from [D] an organoaluminum compound in addition to the above-mentioned [A], [B] and [D] components, and processes for the polymerization of olefins using the above-mentioned olefin polymerization catalysts, respectively.

摘要翻译： 根据本发明，提供了由以下物质形成的烯烃聚合催化剂：[A]属于周期表第IVB族的过渡金属的化合物，[B]铝氧烷和[C]水，烯烃 除了上述[A]，[B]和[D]成分之外，由[D]有机铝化合物形成的聚合催化剂以及使用上述烯烃聚合催化剂聚合烯烃的方法。

公开(公告)号：US5807801A

公开(公告)日：1998-09-15

申请号：US856290

申请日：1997-05-14

申请人： Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

发明人： Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

IPC分类号： B01J31/00 ,  B01J37/00 ,  C08F4/60 ,  C08F4/648 ,  C08F4/655 ,  C08F4/656 ,  C08F10/00 ,  C08F9/02

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F210/18 ,  C08F4/65912 ,  Y10S526/943

摘要： Presence of a catalyst formed from (A) a transition metal compound comprising (A-1) a transition metal atom, (A-2) a hetero atom-containing ligand containing a heteroatom selected from oxygen, sulfur, nitrogen and phosphorus capable of forming a bond with the transition metal atom, and (A-3) a ligand having a conjugated .pi. electron through which the ligand can be bonded to the transition metal atom (A-1), and (B) an aluminoxane. The transition metal compound is pre-treated with (C) an organometallic compound, or (D) a halogen-containing inorganic compound of an element of Group III, IV or V of the periodic table in an organic solvent.

摘要翻译： 存在由（A）过渡金属化合物形成的催化剂，该过渡金属化合物包含（A-1）过渡金属原子，（A-2）含有能够形成的含氧，硫，氮和磷的杂原子的含杂原子的配体 与过渡金属原子的键，和（A-3）具有共轭π电子的配体，配体可以通过其与过渡金属原子（A-1）键合，和（B）铝氧烷。 过渡金属化合物在有机溶剂中用（C）有机金属化合物或（D）元素周期表第III，IV或V族元素的含卤素的无机化合物进行预处理。

公开(公告)号：US5218071A

公开(公告)日：1993-06-08

申请号：US900784

申请日：1992-06-22

申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16

CPC分类号： C08F10/06 ,  C08F210/08 ,  C08F210/16 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943

摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] a density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.

摘要翻译： 根据本发明，提供由乙烯衍生的结构单元（a）和衍生自碳原子数3〜20的α-烯烃的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物的[A]密度为 0.85差异0.92g / cm 3，[B]在135℃的十氢化萘中测得的特性粘度η为0.1Dd / g，[C]重均分子的比率（＆lt;上升＆Mw /＆lt;上升＆ 重量（＆Upbar＆Mw）与通过1.2差聚差4的GPC测定的数均分子量（＆amp; upbar＆Mn）和[D]在负载为10kg时MFR10的MFR 10与MFR 2的比（MFR 10 / MFR 2）在2.16 kg，在190℃为8分钟，分子量分布窄，流动性好。

公开(公告)号：US5008356A

公开(公告)日：1991-04-16

申请号：US359131

申请日：1989-05-31

申请人： Naoshi Ishimaru ,  Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

发明人： Naoshi Ishimaru ,  Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F210/00 ,  C08F210/06 ,  C08F210/14 ,  C08F232/00

CPC分类号： C08F232/00 ,  C08F210/00 ,  C08F210/06 ,  C08F210/14 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： A cyclo-olefinic random copolymer composed of an alpha-olefin component having 3 to 20 carbon atoms and a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclo-olefin component, and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and an olefinic random copolymer composed of (A) an olefin component having 3 to 20 carbon atoms and (B) a cyclic polyene component and as required, (C) a cyclo-olefin component,(i) said copolymer containing 5 to 99 mole % of recurring units derived from said alpha-olefin component (A) having 3 to 20 carbon atoms and 1 to 95 mole % of recurring units derived from said cyclic polyene component (B) and 0 to 90 mole % of recurring units derived from said cyclo-olefin component (C), and(ii) said copolymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.01 to 10 dl/g; and a process for production thereof. Also provided is a process for producing a cyclo-olefinic random copolymer, which comprises copolymerizing an alpha-olefin and a cyclo-olefin in the presence of a catalyst formed from(A) a compound of a transition metal of Group IVB of the periodic table having as a ligand a multidentate coordination compound in which at least two conjugated cycloalkadienyl groups or substituted products thereof are bonded via a lower alkylene group, and(B) an aluminoxane.

公开(公告)号：US5654248A

公开(公告)日：1997-08-05

申请号：US433545

申请日：1995-05-02

申请人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

发明人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

IPC分类号： C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/10 ,  C08F110/02 ,  B01J31/00 ,  B01J37/00

CPC分类号： C08F10/10 ,  C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925

摘要： A prepolymerized solid catalyst for gaseous phase or slurry polymerization of alpha olefins is disclosed. The catalyst comprises a porous carrier having a particle size of 20 to 200 microns onto which has been deposited an aluminoxane and a transition metal compound having at least one cycloalkadienyl group, the transition metal being from group 4 of the Periodic Table. The transition metal is present in an amount of 0.003 to 3 mmol/gm of carrier, and the aluminum to transition metal atomic ratio is from 15 to 1000. This catalyst is then prepolymerized with 0.2 to 30 gm of an alpha olefin per gram of catalyst to form the final prepolymerized solid catalyst having an intrinsic viscosity of 0.2 to 20 dl/gm as measured in decalin at 135 deg C.

摘要翻译： 公开了一种用于α-烯烃的气相或淤浆聚合的预聚合固体催化剂。 催化剂包括粒径为20-200微米的多孔载体，其上沉积有铝氧烷和具有至少一个环二烯基的过渡金属化合物，过渡金属来自元素周期表第4族。 过渡金属的存在量为0.003至3mmol / gm的载体，铝与过渡金属的原子比为15至1000.然后将该催化剂与每克催化剂0.2至30gm的α-烯烃预聚合 以形成在135℃萘烷中测得的特性粘度为0.2-20dl / gm的最终预聚固体催化剂

公开(公告)号：US6063726A

公开(公告)日：2000-05-16

申请号：US862174

申请日：1997-05-22

申请人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

发明人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

IPC分类号： C08F4/02 ,  C08F4/655 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/10 ,  C08F110/02 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F10/10 ,  C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  Y10S526/901 ,  Y10S526/943

摘要： The invention relates to a polymerization catalyst for alpha-olefins and a process for polymerizing alpha-olefins. The catalyst comprises a component having a transition metal compound supported on a carrier and an aluminoxane. The carrier may be pre-treated with an organometallic compound, a halogen-containing silicon compound or an aluminoxane. Alternatively, the above two catalyst components are subjected to preliminary polymerization of olefins. The catalyst of this invention enables the production of a spherical polymer having a good particle size distribution, an excellent bulk density and a narrow molecular weight distribution in a slurry polymerization method or a vapor-phase polymerization method, particulary the vapor-phase polymerization method. When applied to the copolymerization of at least two olefins, the catalyst has excellent polymerization activity such that an olefin copolymer having a narrow molecular weight distribution and a narrrow composition distribution is obtained.

摘要翻译： 本发明涉及α-烯烃的聚合催化剂和α-烯烃的聚合方法。 催化剂包含负载在载体上的过渡金属化合物和铝氧烷的组分。 载体可以用有机金属化合物，含卤素的硅化合物或铝氧烷进行预处理。 或者，将上述两种催化剂组分进行烯烃的预聚合。 本发明的催化剂能够制备在淤浆聚合法或气相聚合法中具有良好的粒度分布，优异的堆积密度和窄分子量分布的球形聚合物，特别是气相聚合法。 当应用于至少两种烯烃的共聚时，催化剂具有优异的聚合活性，从而获得具有窄分子量分布和叙述组成分布的烯烃共聚物。

公开(公告)号：US6013743A

公开(公告)日：2000-01-11

申请号：US105221

申请日：1998-06-26

申请人： Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

发明人： Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

IPC分类号： C08F4/642 ,  C08F210/16 ,  C08F4/64

CPC分类号： C08F4/642 ,  C08F210/16 ,  Y10S526/943

摘要： A process for producing an alpha-olefin polymer, which comprises polymerizing an alpha-olefin in the presence of a catalyst formed from (A) a solid catalyst component comprising an inorganic carrier and deposited thereon a compound of a transition metal of Group IVB of the periodic table treated with an organometallic compound, and (B) an aluminoxane.

摘要翻译： 一种制备α-烯烃聚合物的方法，其包括在由（A）包含无机载体的固体催化剂组分形成的催化剂存在下聚合α-烯烃，并将其上沉积有第ⅣB族过渡金属的化合物 用有机金属化合物处理的周期表，和（B）铝氧烷。

公开(公告)号：US5700749A

公开(公告)日：1997-12-23

申请号：US396893

申请日：1995-03-01

申请人： Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

发明人： Toshiyuki Tsutsui ,  Akinori Toyota ,  Norio Kashiwa

IPC分类号： C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F210/18

CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F210/18 ,  C08F4/65912 ,  C08F4/65922 ,  Y10S526/904 ,  Y10S526/943

摘要： This invention relates to a process for polymerizing olefins using a catalyst composed of a transition metal catalyst component, an aluminoxane component and an organoaluminum component. In the process of this invention, the catalyst exhibits excellent polymerization activity with the use of a small amount of the aluminoxane xane. The polymerization process gives olefin polymers having a narrow molecular weight distribution and by the copolymerization of two or more olefins, gives olefin copolymers having a narrow molecular weight distribution and a narrow composition distribution.

摘要翻译： 本发明涉及使用由过渡金属催化剂组分，铝氧烷组分和有机铝组分组成的催化剂聚合烯烃的方法。 在本发明的方法中，使用少量的铝氧烷，催化剂表现出优异的聚合活性。 聚合方法得到具有窄分子量分布的烯烃聚合物和通过两种或更多种烯烃的共聚合得到具有窄分子量分布和窄组成分布的烯烃共聚物。

公开(公告)号：US5206199A

公开(公告)日：1993-04-27

申请号：US860014

申请日：1992-03-30

申请人： Mamoru Kioka ,  Norio Kashiwa ,  Toshiyuki Tsutsui ,  Akinori Toyota

发明人： Mamoru Kioka ,  Norio Kashiwa ,  Toshiyuki Tsutsui ,  Akinori Toyota

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/943

摘要： An olefin is polymerized or copolymerized under the presence of an olefin-polymerizing catalyst prepared from (A) a transition-metal compound or (A') a transition-metal compound loaded on a fine-particle carrier, said transition metal being selected from group IVB in the periodic table; (B) an aluminoxane; and (C) an organoaluminum compound represented by the general formula [I] or [II]:R.sup.1.sub.m Al(OR.sup.2).sub.3-m [I]R.sup.3.sub.n Al(OSiR.sup.4.sub.3).sub.3-n [II]wherein R.sup.1, R.sup.2, and R.sup.3 are selected from hydrocarbon radicals, R.sup.4 is selected from the group consisting of hydrocarbon, alkoxy, and aryloxy radicals, and m and n are positive numbers of 0

摘要翻译： 在由（A）过渡金属化合物或（A'）负载在细颗粒载体上的过渡金属化合物制备的烯烃聚合催化剂存在下，烯烃聚合或共聚，所述过渡金属选自 IVB在周期表中; （B）铝氧烷; 和（C）由通式[I]或[II]表示的有机铝化合物：R1mA1（OR2）3-m [I] R3nAl（OSiR43）3-n [II]其中R1，R2和R3选自 烃基，R 4选自烃，烷氧基和芳氧基，m和n是0