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1.发明授权Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom 有权含有碳纳米管的含有平行取向的碳纳米管的纤维材料，其制造方法以及由其衍生的复合材料公开(公告)号：US08999453B2
公开(公告)日：2015-04-07
申请号：US13019248
申请日：2011-02-01
IPC分类号： D01F9/12
CPC分类号： D01F9/12 , B05D2256/00 , C01B32/158 , C08L25/02 , D06M11/73 , Y02B10/30 , Y10T428/2933
摘要： Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.
摘要翻译： 本文描述了含有基本上平行排列的，注入碳纳米管的碳纳米管注入的纤维材料。 碳纳米管注入的纤维材料包含纤维材料和注入纤维材料的碳纳米管层，其中输入的碳纳米管基本上平行于纤维材料的纵向轴线排列，并且至少部分基本平行的， 对准的，注入的碳纳米管彼此交联，与纤维材料或两者交联。 例如，交联可以通过共价键或π-层叠相互作用发生。 碳纳米管注入的纤维材料可以进一步包含生长在基本平行排列的输入碳纳米管层上的另外的碳纳米管。 包含碳纳米管注入的纤维材料的复合材料和碳纳米管注入的纤维材料的制造方法也在本文中描述。
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2.发明申请METHOD AND APPARATUS FOR USING A VERTICAL FURNACE TO INFUSE CARBON NANOTUBES TO FIBER 审中-公开使用垂直炉将碳纳米管卷入纤维的方法和装置公开(公告)号：US20100260931A1
公开(公告)日：2010-10-14
申请号：US12757907
申请日：2010-04-09
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B32/164
摘要： A method for forming a CNT infused substrate comprises exposing a catalyst nanoparticle, a carbon feedstock gas, and a carrier gas to a CNT synthesis temperature, allowing a CNT to form on the catalyst nanoparticle, cooling the CNT, and exposing the cooled CNT to a surface of a substrate to form a CNT infused substrate.
摘要翻译： 用于形成CNT注入衬底的方法包括将催化剂纳米颗粒，碳原料气体和载气暴露于CNT合成温度，允许CNT在催化剂纳米颗粒上形成，冷却CNT，并将冷却的CNT暴露于 衬底的表面以形成CNT注入的衬底。
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3.发明申请SYSTEM AND METHOD FOR SURFACE TREATMENT AND BARRIER COATING OF FIBERS FOR IN SITU CNT GROWTH 审中-公开用于表面处理的纤维的表面处理和遮蔽涂层的系统和方法公开(公告)号：US20100224129A1
公开(公告)日：2010-09-09
申请号：US12713146
申请日：2010-02-25
CPC分类号： C01B32/16 , B01J21/185 , B01J23/745 , B01J35/0013 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/162 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , Y10S977/842 , Y10T428/2495 , Y10T428/25
摘要： A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application system for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
摘要翻译： 用于在纤维材料上合成碳纳米管（CNT）的系统包括：表面处理系统，其适于改变纤维材料的表面以接收要在其上生长碳纳米管的阻挡涂层，在表面下游的阻挡涂层施加系统 适于将阻挡涂层施加到经处理的纤维材料表面的处理系统，以及用于部分固化所施加的阻隔涂层以增强CNT生长催化剂纳米颗粒的接收的阻隔涂层施加系统下游的阻隔涂层固化体系。
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公开(公告)号：US20100221424A1
公开(公告)日：2010-09-02
申请号：US12714390
申请日：2010-02-26
申请人： Harry C. MALECKI , Tushar K. Shah
发明人： Harry C. MALECKI , Tushar K. Shah
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/164 , C01B2202/04
摘要： A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
摘要翻译： 合成碳纳米管（CNT）的方法包括以下步骤：提供生长室，所述生长室被加热到足够高的第一温度以促进碳纳米管的生长; 并使基底通过生长室; 以及将进料气体引入预加热到足以将至少一些进料气体解离成至少游离碳自由基的第二温度的生长室，从而引发碳纳米管在基材上的形成。
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公开(公告)号：US09163354B2
公开(公告)日：2015-10-20
申请号：US13234100
申请日：2011-09-15
IPC分类号： H01B7/18 , B05D5/12 , C08K3/04 , D02G3/36 , D02G3/02 , C08K3/08 , B82Y30/00 , B82Y40/00 , D06M11/74 , H05K9/00 , C01B31/02 , D06M101/40 , H01B5/10
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B31/0233 , C01B31/024 , C01B32/162 , C01B32/164 , D06M2101/40 , H01B5/105 , H05K9/0098 , Y10T428/2918
摘要： A wire includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes. An electromagnetic shield for a wire includes a plurality of carbon nanotube infused fibers, in which the infused carbon nanotubes are aligned radially about the fiber axes. The plurality of carbon nanotube infused fibers are arranged circumferentially about the wire with the fiber axes parallel to the wire. A self-shielded wire includes 1) a wire that includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes; and 2) an electromagnetic shield that includes a plurality of carbon nanotube infused fibers in which the carbon nanotubes are aligned radially about the fiber axes. The axes of the carbon nanotube infused fibers of the wire and the carbon nanotube infused fibers of the electromagnetic shield share are parallel.
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6.发明授权公开(公告)号：US08665581B2
公开(公告)日：2014-03-04
申请号：US13039025
申请日：2011-03-02
IPC分类号： H01G9/00
摘要： Electrical devices having electrodes containing carbon nanotubes infused to a substrate are described herein. The electrical devices contain at least a first electrode material containing a first plurality of carbon nanotubes infused to a first substrate and a second electrode material containing a second plurality of carbon nanotubes infused to a second substrate. The first electrode material and the second electrode material are wound in a spiral configuration about a central axis. The electrical devices can be supercapacitors, which also contain at least an electrolyte in contact with the first electrode material and the second electrode material, and a first separator material disposed between the first electrode material and the second electrode material. Methods and apparatuses for making the electrical devices are also disclosed herein.
摘要翻译： 本文描述了具有注入基底的碳纳米管的电极的电气装置。 电气装置至少包含第一电极材料，该第一电极材料含有注入第一衬底的第一组多个碳纳米管和含有第二组碳纳米管的第二电极材料，该第二电极材料注入第二衬底。 第一电极材料和第二电极材料围绕中心轴以螺旋形构造。 电气装置可以是超级电容器，其也至少包含与第一电极材料和第二电极材料接触的电解质，以及设置在第一电极材料和第二电极材料之间的第一分离器材料。 本文还公开了用于制造电气装置的方法和装置。
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公开(公告)号：US08580342B2
公开(公告)日：2013-11-12
申请号：US12714390
申请日：2010-02-26
申请人： Harry C. Malecki , Tushar K. Shah
发明人： Harry C. Malecki , Tushar K. Shah
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/164 , C01B2202/04
摘要： A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
摘要翻译： 合成碳纳米管（CNT）的方法包括以下步骤：提供生长室，所述生长室被加热至足够高的第一温度以促进碳纳米管的生长; 并使基底通过生长室; 以及将进料气体引入预加热到足以将至少一些进料气体解离成至少游离碳自由基的第二温度的生长室，从而引发碳纳米管在基材上的形成。
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8.发明授权Flame-resistant composite materials and articles containing carbon nanotube-infused fiber materials 有权耐火复合材料和含碳纳米管注入纤维材料的制品公开(公告)号：US08545963B2
公开(公告)日：2013-10-01
申请号：US12968187
申请日：2010-12-14
CPC分类号： B82Y30/00 , B32B5/12 , B32B5/16 , B32B5/26 , B32B2260/046 , B32B2262/101 , B32B2262/105 , B32B2262/106 , Y10T428/24 , Y10T428/24058 , Y10T428/24132 , Y10T428/249921 , Y10T428/249942 , Y10T428/25 , Y10T428/269
摘要： Flame-resistant composite materials containing carbon nanotubes are described herein. The flame-resistant composite materials contain an outer layer and at least one inner layer, containing a first polymer matrix and a second polymer matrix, respectively. The outer layer has an exterior surface and a first carbon nanotube-infused fiber material that contains a first fiber material and a first plurality of carbon nanotubes greater than about 50 μm in length. In some embodiments, the at least one inner layer also contains a second fiber material and/or a second carbon nanotube-infused fiber material containing a second fiber material and a second plurality of carbon nanotubes. When present, the second plurality of carbon nanotubes are generally shorter in length than the first plurality of carbon nanotubes. Alignment of the carbon nanotubes in the outer layer can transfer heat away from the composite material's inner layer(s). Flame-resistant articles containing carbon nanotube-infused fiber materials are also described.
摘要翻译： 本文描述了含有碳纳米管的耐火复合材料。 耐火复合材料包含分别含有第一聚合物基质和第二聚合物基质的外层和至少一个内层。 外层具有外表面和第一碳纳米管注入的纤维材料，其含有第一纤维材料和长度大于约50μm的第一多个碳纳米管。 在一些实施例中，至少一个内层还包含含有第二纤维材料和第二多个碳纳米管的第二纤维材料和/或第二碳纳米管输注的纤维材料。 当存在时，第二多个碳纳米管的长度通常比第一多个碳纳米管短。 外层中的碳纳米管的对准可以将热量从复合材料的内层传递出去。 还描述了含有碳纳米管输入的纤维材料的耐火物品。
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9.发明授权公开(公告)号：US08168291B2
公开(公告)日：2012-05-01
申请号：US12953434
申请日：2010-11-23
IPC分类号： B32B15/04
CPC分类号： C04B35/62889 , B82Y30/00 , C04B20/12 , C04B28/04 , C04B35/117 , C04B35/185 , C04B35/4682 , C04B35/5607 , C04B35/5611 , C04B35/5626 , C04B35/565 , C04B35/58014 , C04B35/58042 , C04B35/58071 , C04B35/584 , C04B35/6269 , C04B35/62849 , C04B35/62852 , C04B35/62857 , C04B35/62873 , C04B35/62876 , C04B35/62894 , C04B35/62897 , C04B35/76 , C04B35/803 , C04B35/806 , C04B35/82 , C04B2235/5224 , C04B2235/524 , C04B2235/5244 , C04B2235/5248 , C04B2235/5252 , C04B2235/5256 , C04B2235/526 , C04B2235/5264 , C04B2235/5268 , C04B2235/5272 , C04B2235/5288 , C04B2235/604 , C04B2235/75 , Y10S977/742 , Y10T428/249927 , Y10T428/249928 , C04B14/386 , C04B14/42 , C04B14/46 , C04B16/06 , C04B20/1014 , C04B20/1055 , C04B20/1062
摘要： In various embodiments, composite materials containing a ceramic matrix and a carbon nanotube-infused fiber material are described herein. Illustrative ceramic matrices include, for example, binary, ternary and quaternary metal or non-metal borides, oxides, nitrides and carbides. The ceramic matrix can also be a cement. The fiber materials can be continuous or chopped fibers and include, for example, glass fibers, carbon fibers, metal fibers, ceramic fibers, organic fibers, silicon carbide fibers, boron carbide fibers, silicon nitride fibers and aluminum oxide fibers. The composite materials can further include a passivation layer overcoating at least the carbon nanotube-infused fiber material and, optionally, the plurality of carbon nanotubes. The fiber material can be distributed uniformly, non-uniformly or in a gradient manner in the ceramic matrix. Non-uniform distributions may be used to form impart different mechanical, electrical or thermal properties to different regions of the ceramic matrix.
摘要翻译： 在各种实施方案中，本文描述了含有陶瓷基质和碳纳米管注入的纤维材料的复合材料。 说明性的陶瓷基质包括例如二元，三元和四元金属或非金属硼化物，氧化物，氮化物和碳化物。 陶瓷基体也可以是水泥。 纤维材料可以是连续的或短切的纤维，并且包括例如玻璃纤维，碳纤维，金属纤维，陶瓷纤维，有机纤维，碳化硅纤维，碳化硼纤维，氮化硅纤维和氧化铝纤维。 复合材料还可以包括至少覆盖碳纳米管注入的纤维材料和任选的多个碳纳米管的钝化层。 纤维材料可以均匀地，不均匀地或以梯度方式分布在陶瓷基体中。 可以使用不均匀分布来形成对陶瓷基体的不同区域的不同的机械，电或热特性。
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10.发明申请CNT-INFUSED FIBER AS A SELF SHIELDING WIRE FOR ENHANCED POWER TRANSMISSION LINE 有权CNT输送纤维作为增强型输电线自动屏蔽线公开(公告)号：US20110174519A1
公开(公告)日：2011-07-21
申请号：US13006368
申请日：2011-01-13
摘要： A wire includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes. An electromagnetic shield for a wire includes a plurality of carbon nanotube infused fibers, in which the infused carbon nanotubes are aligned radially about the fiber axes. The plurality of carbon nanotube infused fibers are arranged circumferentially about the wire with the fiber axes parallel to the wire. A self-shielded wire includes 1) a wire that includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes; and 2) an electromagnetic shield that includes a plurality of carbon nanotube infused fibers in which the carbon nanotubes are aligned radially about the fiber axes. The axes of the carbon nanotube infused fibers of the wire and the carbon nanotube infused fibers of the electromagnetic shield share are parallel.
摘要翻译： 导线包括多个碳纳米管输注的纤维，其中输入的碳纳米管平行于纤维轴排列。 用于电线的电磁屏蔽包括多个碳纳米管输注的纤维，其中注入的碳纳米管围绕纤维轴径向排列。 多个碳纳米管输入的纤维围绕导线周向布置，其中纤维轴线平行于线材。 自屏蔽线包括：1）包括多个碳纳米管输注纤维的导线，其中输入的碳纳米管平行于纤维轴排列; 和2）包括多个碳纳米管输注纤维的电磁屏蔽，其中碳纳米管围绕纤维轴径向排列。 碳纳米管的轴线注入线的纤维和电磁屏蔽共享的碳纳米管注入的纤维是平行的。
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