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1.发明授权Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom 有权含有碳纳米管的含有平行取向的碳纳米管的纤维材料，其制造方法以及由其衍生的复合材料公开(公告)号：US08999453B2
公开(公告)日：2015-04-07
申请号：US13019248
申请日：2011-02-01
IPC分类号： D01F9/12
CPC分类号： D01F9/12 , B05D2256/00 , C01B32/158 , C08L25/02 , D06M11/73 , Y02B10/30 , Y10T428/2933
摘要： Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.
摘要翻译： 本文描述了含有基本上平行排列的，注入碳纳米管的碳纳米管注入的纤维材料。 碳纳米管注入的纤维材料包含纤维材料和注入纤维材料的碳纳米管层，其中输入的碳纳米管基本上平行于纤维材料的纵向轴线排列，并且至少部分基本平行的， 对准的，注入的碳纳米管彼此交联，与纤维材料或两者交联。 例如，交联可以通过共价键或π-层叠相互作用发生。 碳纳米管注入的纤维材料可以进一步包含生长在基本平行排列的输入碳纳米管层上的另外的碳纳米管。 包含碳纳米管注入的纤维材料的复合材料和碳纳米管注入的纤维材料的制造方法也在本文中描述。
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2.发明申请SYSTEM AND METHOD FOR SURFACE TREATMENT AND BARRIER COATING OF FIBERS FOR IN SITU CNT GROWTH 审中-公开用于表面处理的纤维的表面处理和遮蔽涂层的系统和方法公开(公告)号：US20100224129A1
公开(公告)日：2010-09-09
申请号：US12713146
申请日：2010-02-25
CPC分类号： C01B32/16 , B01J21/185 , B01J23/745 , B01J35/0013 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/162 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , Y10S977/842 , Y10T428/2495 , Y10T428/25
摘要： A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application system for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
摘要翻译： 用于在纤维材料上合成碳纳米管（CNT）的系统包括：表面处理系统，其适于改变纤维材料的表面以接收要在其上生长碳纳米管的阻挡涂层，在表面下游的阻挡涂层施加系统 适于将阻挡涂层施加到经处理的纤维材料表面的处理系统，以及用于部分固化所施加的阻隔涂层以增强CNT生长催化剂纳米颗粒的接收的阻隔涂层施加系统下游的阻隔涂层固化体系。
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3.发明授权Glass substrates having carbon nanotubes grown thereon and methods for production thereof 有权具有碳纳米管生长的玻璃基板及其制造方法公开(公告)号：US08784937B2
公开(公告)日：2014-07-22
申请号：US13230751
申请日：2011-09-12
申请人： Brandon K. Malet , Tushar K. Shah
发明人： Brandon K. Malet , Tushar K. Shah
IPC分类号： C23C16/00 , C01B31/02 , D01F9/127 , C03C25/10 , C03C25/22 , C03C25/44 , B82Y30/00 , C23C16/26 , C23C16/458 , C23C16/54 , B05D3/10
CPC分类号： B05D3/10 , B01J21/185 , B01J23/75 , B01J35/06 , B01J37/0213 , B05D2203/35 , B05D2256/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/164 , C01B2202/34 , C03C17/28 , C03C25/1095 , C03C25/223 , C03C25/24 , C03C25/44 , C23C16/26 , C23C16/458 , C23C16/545 , D01F9/127 , Y10S977/843 , Y10S977/891 , Y10T428/25
摘要： Methods for growing carbon nanotubes on glass substrates, particularly glass fiber substrates, are described herein. The methods can include depositing a catalytic material or a catalyst precursor on a glass substrate; depositing a non-catalytic material on the glass substrate prior to, after, or concurrently with the catalytic material or catalyst precursor; and exposing the glass substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The glass substrate, particularly a glass fiber substrate, can be transported while the carbon nanotubes are being grown thereon. Catalyst precursors can be converted into a catalyst when exposed to carbon nanotube growth conditions. The catalytic material or catalyst precursor and the non-catalytic material can be deposited from a solution containing water as a solvent. Illustrative deposition techniques include, for example, spray coating and dip coating.
摘要翻译： 本文描述了在玻璃基底，特别是玻璃纤维基底上生长碳纳米管的方法。 所述方法可以包括在玻璃基底上沉积催化材料或催化剂前体; 在催化材料或催化剂前体之前，之后或同时在玻璃基板上沉积非催化材料; 并将玻璃基板暴露于碳纳米管生长条件，以便在其上生长碳纳米管。 玻璃基板，特别是玻璃纤维基板，可以在碳纳米管在其上生长的同时被输送。 当暴露于碳纳米管生长条件时，催化剂前体可以转化为催化剂。 催化剂材料或催化剂前体和非催化材料可以从含有水作为溶剂的溶液沉积。 示例性沉积技术包括例如喷涂和浸涂。
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4.发明授权Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof 有权具有生长在其上的碳纳米管的碳纤维基材及其生产方法公开(公告)号：US08815341B2
公开(公告)日：2014-08-26
申请号：US13231869
申请日：2011-09-13
申请人： Brandon K. Malet , Tushar K. Shah
发明人： Brandon K. Malet , Tushar K. Shah
CPC分类号： B82Y30/00 , B05D2256/00 , B82Y40/00 , C01B32/158 , C01B32/162 , C01B2202/34 , C01B2202/36 , C23C16/26 , C23C16/458 , C23C16/545 , Y10S977/843 , Y10S977/891 , Y10T428/30
摘要： Processes for growing carbon nanotubes on carbon fiber substrates are described herein. The processes can include depositing a catalyst precursor on a carbon fiber substrate, optionally depositing a non-catalytic material on the carbon fiber substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the carbon fiber substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions can convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The carbon fiber substrate can remain stationary or be transported while the carbon nanotubes are being grown. Optionally, the carbon fiber substrates can include a barrier coating and/or be free of a sizing agent. Carbon fiber substrates having carbon nanotubes grown thereon are also described.
摘要翻译： 本文描述了用于在碳纤维基底上生长碳纳米管的方法。 该方法可以包括将催化剂前体沉积在碳纤维基材上，任选地在碳纤维基材上沉积非催化材料，以及在沉积催化剂前体和任选的非催化材料之后，将碳纤维基材暴露于碳纳米管生长 条件，以便在其上生长碳纳米管。 碳纳米管生长条件可将催化剂前体转化成可用于生长碳纳米管的催化剂。 碳纤维基材可以在碳纳米管生长过程中保持静止或运输。 任选地，碳纤维基材可以包括阻隔涂层和/或不含上浆剂。 还描述了其上生长有碳纳米管的碳纤维基材。
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5.发明申请公开(公告)号：US20120070667A1
公开(公告)日：2012-03-22
申请号：US13231869
申请日：2011-09-13
申请人： Brandon K. Malet , Tushar K. Shah
发明人： Brandon K. Malet , Tushar K. Shah
CPC分类号： B82Y30/00 , B05D2256/00 , B82Y40/00 , C01B32/158 , C01B32/162 , C01B2202/34 , C01B2202/36 , C23C16/26 , C23C16/458 , C23C16/545 , Y10S977/843 , Y10S977/891 , Y10T428/30
摘要： Processes for growing carbon nanotubes on carbon fiber substrates are described herein. The processes can include depositing a catalyst precursor on a carbon fiber substrate, optionally depositing a non-catalytic material on the carbon fiber substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the carbon fiber substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions can convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The carbon fiber substrate can remain stationary or be transported while the carbon nanotubes are being grown. Optionally, the carbon fiber substrates can include a barrier coating and/or be free of a sizing agent. Carbon fiber substrates having carbon nanotubes grown thereon are also described.
摘要翻译： 本文描述了用于在碳纤维基底上生长碳纳米管的方法。 该方法可以包括将催化剂前体沉积在碳纤维基材上，任选地在碳纤维基材上沉积非催化材料，以及在沉积催化剂前体和任选的非催化材料之后，将碳纤维基材暴露于碳纳米管生长 条件，以便在其上生长碳纳米管。 碳纳米管生长条件可将催化剂前体转化成可用于生长碳纳米管的催化剂。 碳纤维基材可以在碳纳米管生长过程中保持静止或运输。 任选地，碳纤维基材可以包括阻隔涂层和/或不含上浆剂。 还描述了其上生长有碳纳米管的碳纤维基材。
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6.发明申请METHOD AND APPARATUS FOR USING A VERTICAL FURNACE TO INFUSE CARBON NANOTUBES TO FIBER 审中-公开使用垂直炉将碳纳米管卷入纤维的方法和装置公开(公告)号：US20100260931A1
公开(公告)日：2010-10-14
申请号：US12757907
申请日：2010-04-09
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B32/164
摘要： A method for forming a CNT infused substrate comprises exposing a catalyst nanoparticle, a carbon feedstock gas, and a carrier gas to a CNT synthesis temperature, allowing a CNT to form on the catalyst nanoparticle, cooling the CNT, and exposing the cooled CNT to a surface of a substrate to form a CNT infused substrate.
摘要翻译： 用于形成CNT注入衬底的方法包括将催化剂纳米颗粒，碳原料气体和载气暴露于CNT合成温度，允许CNT在催化剂纳米颗粒上形成，冷却CNT，并将冷却的CNT暴露于 衬底的表面以形成CNT注入的衬底。
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公开(公告)号：US20100221424A1
公开(公告)日：2010-09-02
申请号：US12714390
申请日：2010-02-26
申请人： Harry C. MALECKI , Tushar K. Shah
发明人： Harry C. MALECKI , Tushar K. Shah
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/164 , C01B2202/04
摘要： A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
摘要翻译： 合成碳纳米管（CNT）的方法包括以下步骤：提供生长室，所述生长室被加热到足够高的第一温度以促进碳纳米管的生长; 并使基底通过生长室; 以及将进料气体引入预加热到足以将至少一些进料气体解离成至少游离碳自由基的第二温度的生长室，从而引发碳纳米管在基材上的形成。
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公开(公告)号：US09163354B2
公开(公告)日：2015-10-20
申请号：US13234100
申请日：2011-09-15
IPC分类号： H01B7/18 , B05D5/12 , C08K3/04 , D02G3/36 , D02G3/02 , C08K3/08 , B82Y30/00 , B82Y40/00 , D06M11/74 , H05K9/00 , C01B31/02 , D06M101/40 , H01B5/10
CPC分类号： D06M11/74 , B82Y30/00 , B82Y40/00 , C01B31/0233 , C01B31/024 , C01B32/162 , C01B32/164 , D06M2101/40 , H01B5/105 , H05K9/0098 , Y10T428/2918
摘要： A wire includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes. An electromagnetic shield for a wire includes a plurality of carbon nanotube infused fibers, in which the infused carbon nanotubes are aligned radially about the fiber axes. The plurality of carbon nanotube infused fibers are arranged circumferentially about the wire with the fiber axes parallel to the wire. A self-shielded wire includes 1) a wire that includes a plurality of carbon nanotube infused fibers in which the infused carbon nanotubes are aligned parallel to the fiber axes; and 2) an electromagnetic shield that includes a plurality of carbon nanotube infused fibers in which the carbon nanotubes are aligned radially about the fiber axes. The axes of the carbon nanotube infused fibers of the wire and the carbon nanotube infused fibers of the electromagnetic shield share are parallel.
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9.发明授权公开(公告)号：US08665581B2
公开(公告)日：2014-03-04
申请号：US13039025
申请日：2011-03-02
IPC分类号： H01G9/00
摘要： Electrical devices having electrodes containing carbon nanotubes infused to a substrate are described herein. The electrical devices contain at least a first electrode material containing a first plurality of carbon nanotubes infused to a first substrate and a second electrode material containing a second plurality of carbon nanotubes infused to a second substrate. The first electrode material and the second electrode material are wound in a spiral configuration about a central axis. The electrical devices can be supercapacitors, which also contain at least an electrolyte in contact with the first electrode material and the second electrode material, and a first separator material disposed between the first electrode material and the second electrode material. Methods and apparatuses for making the electrical devices are also disclosed herein.
摘要翻译： 本文描述了具有注入基底的碳纳米管的电极的电气装置。 电气装置至少包含第一电极材料，该第一电极材料含有注入第一衬底的第一组多个碳纳米管和含有第二组碳纳米管的第二电极材料，该第二电极材料注入第二衬底。 第一电极材料和第二电极材料围绕中心轴以螺旋形构造。 电气装置可以是超级电容器，其也至少包含与第一电极材料和第二电极材料接触的电解质，以及设置在第一电极材料和第二电极材料之间的第一分离器材料。 本文还公开了用于制造电气装置的方法和装置。
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公开(公告)号：US08580342B2
公开(公告)日：2013-11-12
申请号：US12714390
申请日：2010-02-26
申请人： Harry C. Malecki , Tushar K. Shah
发明人： Harry C. Malecki , Tushar K. Shah
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/164 , C01B2202/04
摘要： A method for synthesizing carbon nanotubes (CNT) comprises the steps of providing a growth chamber, the growth chamber being heated to a first temperature sufficiently high to facilitate a growth of carbon nanotubes; and passing a substrate through the growth chamber; and introducing a feed gas into the growth chamber pre-heated to a second temperature sufficient to dissociate at least some of the feed gas into at least free carbon radicals to thereby initiate formation of carbon nanotubes onto the substrate.
摘要翻译： 合成碳纳米管（CNT）的方法包括以下步骤：提供生长室，所述生长室被加热至足够高的第一温度以促进碳纳米管的生长; 并使基底通过生长室; 以及将进料气体引入预加热到足以将至少一些进料气体解离成至少游离碳自由基的第二温度的生长室，从而引发碳纳米管在基材上的形成。
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