公开(公告)号：US20170275168A1

公开(公告)日：2017-09-28

申请号：US15496732

申请日：2017-04-25

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Fahad Ali RABBANI ,  Zuhair Omar Malaibari ,  Muataz Ali Atieh

IPC: C01B31/04 ,  C23C16/448 ,  C01F7/30 ,  C23C16/40 ,  C23C16/455

CPC classification number: C01B32/162 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/0233 ,  C01B32/16 ,  C01B2202/06 ,  C01B2202/10 ,  C01B2202/32 ,  C01F7/304 ,  C04B41/4531 ,  C23C16/01 ,  C23C16/30 ,  C23C16/4417 ,  C23C16/4486 ,  C23C16/46 ,  C23C16/463 ,  Y10S977/744 ,  Y10S977/752 ,  Y10S977/843 ,  Y10S977/846

Abstract: A vertical chemical vapor deposition (CVD) reactor and a method for synthesizing metal oxide impregnated carbon nanotubes. The CVD reactor includes a preheating zone portion and a reaction zone portion, and preferably an additional cooling zone portion and a product collector. The method includes (a) subjecting a liquid reactant solution comprising an organic solvent, a metallocene, and a metal alkoxide to atomization in the presence of a gas flow comprising a carrier gas and a support gas to form an atomized mixture, and (b) heating the atomized mixture to a temperature of 200° C.−1400° C., wherein the heating forms a metal oxide and at least one carbon source compound, wherein the metallocene catalyzes the formation of carbon nanotubes from the at least one carbon source compound and the metal oxide is incorporated into or on a surface of the carbon nanotubes to form the metal oxide impregnated carbon nanotubes.

公开(公告)号：US09493354B2

公开(公告)日：2016-11-15

申请号：US14770630

申请日：2014-01-28

Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.

Inventor： Takeshi Hikata ,  Soichiro Okubo ,  Risa Utsunomiya ,  Yugo Higashi ,  Jun-ichi Fujita ,  Katsuhisa Murakami

IPC: C23C16/46 ,  C01B31/02 ,  B01J23/745 ,  B01J23/74 ,  B01J35/00 ,  C23C16/26 ,  C23C16/04 ,  B82Y40/00

CPC classification number: C01B31/0233 ,  B01J23/74 ,  B01J23/745 ,  B01J35/0013 ,  B82Y40/00 ,  C01B31/0206 ,  C01B32/15 ,  C01B32/162 ,  C23C16/04 ,  C23C16/26 ,  C23C16/46

Abstract: A method for manufacturing a carbon nanostructure according to the present invention includes a preparation step of preparing a base body, an oxidization step and a step of growing a carbon nanostructure. In the step of preparing a base body, a base body with at least a part of a contact portion or an integral portion of a catalyst member and a separation member having been oxidized is prepared. In the step of growing a carbon nanostructure, a carbon nanostructure is grown in a separation interface region between the catalyst member and the separation member. The step of growing a carbon nanostructure includes at least one of a step of locally supplying a source gas to a portion of the catalyst member facing the separation interface region where the carbon nanostructure is being grown, and a step of locally heating the separation interface region.

Abstract translation: 本发明的碳纳米结构体的制造方法包括制备基体的准备工序，氧化工序和生长碳纳米结构体的工序。 在准备基体的步骤中，制备具有至少一部分接触部分或催化剂部件的整体部分和已被氧化的分离部件的基体。 在生长碳纳米结构的步骤中，在催化剂构件和分离构件之间的分离界面区域中生长碳纳米结构。 生长碳纳米结构的步骤包括以下步骤中的至少一种：将源气体局部供给到面向生长碳纳米结构的分离界面区域的催化剂构件的一部分的步骤，以及局部加热分离界面区域 。

公开(公告)号：US09399578B2

公开(公告)日：2016-07-26

申请号：US14348833

申请日：2013-01-09

Applicant: LG CHEM, LTD.

Inventor： Kyung Yeon Kang ,  Jin Do Kim ,  Sung Jin Kim ,  Jae Keun Yoon

IPC: B32B9/00 ,  C01B31/02 ,  B01J23/882 ,  B01J35/00 ,  B82Y30/00 ,  B82Y40/00 ,  B01J21/18 ,  B01J37/02 ,  B01J37/03

CPC classification number: C01B31/0233 ,  B01J21/185 ,  B01J23/75 ,  B01J23/882 ,  B01J35/002 ,  B01J35/0026 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/05 ,  C01B32/158 ,  C01B32/162 ,  C01B2202/34 ,  C01B2202/36 ,  Y10T428/2982 ,  Y10T428/30 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845

Abstract: Disclosed are carbon nanotubes and a method for manufacturing the same wherein the carbon nanotubes (CNTs) which comprise a three-component carbon nanotube catalyst containing a catalytic component and an active component and have a potato or spherical shape with a particle diameter distribution (Dcnt) of 0.5 to 1.0 can be manufactured at a high yield using an impregnated supported catalyst by simultaneously removing activity and a fine powder of the impregnated supported catalyst in an attempt to solve a drawback of conventional impregnation methods for producing CNTs, namely, the difficulty in improving a yield of CNTs.

Abstract translation: 公开了碳纳米管及其制造方法，其中包含含有催化组分和活性组分并具有粒径分布（Dcnt）的马铃薯或球形的三组分碳纳米管催化剂的碳纳米管（CNT） 可以通过同时除去活性的浸渍的负载型催化剂和浸渍的负载型催化剂的细粉末以高产率制造，以解决用于生产CNT的常规浸渍方法的缺点，即难以改进 CNT的产率。

公开(公告)号：US09334167B2

公开(公告)日：2016-05-10

申请号：US11920280

申请日：2006-05-11

Applicant: Sembukutiarachilage Ravi Silva ,  Ben Poul Jensen ,  Guan Yow Chen

Inventor： Sembukutiarachilage Ravi Silva ,  Ben Poul Jensen ,  Guan Yow Chen

IPC: C23C16/46 ,  C01B31/02 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: C01B31/0233 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C23C16/46 ,  Y10T428/265

Abstract: The present invention relates to a method of forming nanostructures or nanomaterials. The method comprises providing a thermal control barrier on a substrate and forming the nanostructures or nanomaterials. The method may, for example, be used to form carbon nanotubes by plasma enhanced chemical vapor deposition using a carbon containing gas plasma: The temperature of the substrate may be maintained at less than 350° C. while the carbon nanotubes are formed.

Abstract translation: 本发明涉及形成纳米结构或纳米材料的方法。 该方法包括在基底上提供热控制屏障并形成纳米结构或纳米材料。 该方法可以例如通过使用含碳气体等离子体的等离子体增强化学气相沉积来用于形成碳纳米管。当形成碳纳米管时，衬底的温度可以保持在低于350℃。

公开(公告)号：US09315386B2

公开(公告)日：2016-04-19

申请号：US14366366

申请日：2012-11-28

Applicant: Vladimir Zalmanovich Mordkovich ,  Aida Razimovna Karaeva ,  Maxim Alexandrovich Khaskov ,  Eduard Borisovich Mitberg

Inventor： Vladimir Zalmanovich Mordkovich ,  Aida Razimovna Karaeva ,  Maxim Alexandrovich Khaskov ,  Eduard Borisovich Mitberg

IPC: C01B31/02 ,  B01J19/24 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: C01B31/0233 ,  B01J19/2415 ,  B01J2219/00166 ,  B01J2219/19 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/164 ,  C01B2202/34

Abstract: The present invention is used to produce long carbon nanotubes used, for example, in automobile and/or aircraft industry. An object of the invention is to obtain bundles of multi-walled and well oriented nanotubes of sufficient length and provide stability of continuous nanotubes producing process. The method comprises introducing a carbon-bearing component, a promoter and a precursor of a carbon nanotube growth catalyst in a carrier gas stream to form a mixture of these components; passing said mixture through the a reactor heated to an operating temperature of 1000° C. to 1200° C. and removing nanotubes formed in the reactor into a product receiver. The mixture is fed in the reactor from the bottom upwards at a linear flow velocity of 50 mm/c to 130 mm/c. When the temperature in the reactor reaches said operating temperature, the linear flow velocity of the mixture is decreased to 4-10 mm/c, and the linear flow velocity is increased to 30-130 mm/c at the outlet of the reactor. The apparatus comprises means for introducing the carbon-bearing component, the promoter and the precursor of the carbon nanotube growth catalyst in the carrier gas stream, a vertical reactor with a working chamber, means for heating the working chamber to the operating temperature, means for delivering the mixture to the working chamber of the reactor and means for removing products from the working chamber. The chamber is made of three successive sections, namely a lower inlet 16 section, a middle 17 section and an upper outlet 18 section and the diameter of the lower section 16 is ⅕ to ⅓ of the diameter of the middle section 17, while the diameter of the upper section 18 is from ¼ to ⅓ of the diameter of the middle section 17.

Abstract translation: 本发明用于生产例如汽车和/或飞机工业中使用的长碳纳米管。 本发明的目的是获得具有足够长度的多壁和良好取向的纳米管束并提供连续的纳米管生产方法的稳定性。 该方法包括在载气流中引入碳载体组分，促进剂和碳纳米管生长催化剂的前体以形成这些组分的混合物; 将所述混合物通过加热至1000℃至1200℃的操作温度的反应器，并将形成在反应器中的纳米颗粒除去产品接收器。 将混合物从底部向上以50mm / c至130mm / c的线性流速进料到反应器中。 当反应器中的温度达到所述工作温度时，混合物的线性流速降低到4-10mm / c，在反应器出口处线性流速增加到30-130mm / c。 该装置包括用于将载气组分，促​​进剂和碳纳米管生长催化剂的前体引入载气流的装置，具有工作室的垂直反应器，用于将工作室加热至工作温度的装置， 将混合物输送到反应器的工作室，以及用于从工作室中除去产物的装置。 该室由三个连续的部分制成，即下部入口16部分，中部17部分和上部出口18部分，下部部分16的直径为中间部分17的直径的¼至1/3，而直径 上部18的直径为中间部分17的直径的1/4到1/3。

公开(公告)号：US09315385B2

公开(公告)日：2016-04-19

申请号：US12002853

申请日：2007-12-17

Applicant: Paul N. Arendt ,  Yuntian T. Zhu ,  Igor O. Usov ,  Xiefei Zhang

Inventor： Paul N. Arendt ,  Yuntian T. Zhu ,  Igor O. Usov ,  Xiefei Zhang

IPC: D01F9/12 ,  C01B31/02 ,  B82Y30/00 ,  B82Y40/00 ,  D06M10/00 ,  D06M101/40

CPC classification number: C01B31/0233 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/168 ,  C01B2202/08 ,  D06M10/008 ,  D06M2101/40

Abstract: A spun fiber of carbon nanotubes is exposed to ion irradiation. The irradiation exposure increases the specific strength of the spun fiber.

Abstract translation: 将碳纳米管的纺丝纤维暴​​露于离子照射。 照射暴露增加纺丝纤维的比强度。

公开(公告)号：US20150353360A1

公开(公告)日：2015-12-10

申请号：US14832386

申请日：2015-08-21

Applicant: KOREA KUMHO PETROCHEMICAL CO., LTD.

Inventor： Sang Kyu CHOI ,  Sang Hyo RYU ,  Ho Soo HWANG ,  Chung Heon JEONG ,  Dong Hoon OH ,  Yeon Ja LEE ,  Youngchan JANG

IPC: C01B31/02

CPC classification number: C01B31/0233 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J23/887 ,  B01J23/8875 ,  B01J23/8885 ,  B01J23/8898 ,  B01J35/0013 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/088 ,  B01J2523/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/06 ,  Y10S977/752 ,  Y10S977/843 ,  Y10T428/2918 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/72 ,  B01J2523/17 ,  B01J2523/69 ,  B01J2523/47 ,  B01J2523/43

Abstract: The present invention relates to a catalyst composition for the synthesis of multi-walled carbon nanotube having high apparent density in a manner of high yield. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Mo, ii) inactive support of Al and iii) optional co-catalyst at least one selected from Co, Ni, Ti, Mn, W, Sn or Cu. Further, the present invention affords multi-walled carbon nanotube having 5˜15 nm of fibrous diameter and 0.5˜4 μm bundle diameter.

Abstract translation: 本发明涉及以高产率合成具有高表观密度的多壁碳纳米管的催化剂组合物。 更具体地说，本发明涉及一种多组分金属催化剂组合物，其包括i）Fe和Mo的主要催化剂，ii）Al的无活性载体和iii）任选的助催化剂，选自Co，Ni，Ti，Mn， W，Sn或Cu。 此外，本发明提供纤维直径为5〜15nm，束直径为0.5〜4μm的多壁碳纳米管。

公开(公告)号：US09206050B2

公开(公告)日：2015-12-08

申请号：US11726371

申请日：2007-03-20

Applicant: Alimorad Rashidi ,  Bahman Amini Horri ,  Ali Mohajeri ,  Sasan Sadraei ,  Khairolah Jafari Jozani ,  Ali Nakhaeipor

Inventor： Alimorad Rashidi ,  Bahman Amini Horri ,  Ali Mohajeri ,  Sasan Sadraei ,  Khairolah Jafari Jozani ,  Ali Nakhaeipor

IPC: C01B31/02 ,  C23C16/00 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: C01B31/0233 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/164 ,  C01B32/17

Abstract: The present invention relates to a continuous process for producing carbon nanotubes (herein after also referred to as “CNTS”) of single, double and/or multi-wall type, with any possible desired diameter and with high purity. The preferred embodiment provides means for continuous supply of a catalyst during the process for producing the carbon nanotubes, according to which one can achieve the advantageous continuity of the process.

Abstract translation: 本发明涉及具有任何可能的期望直径和高纯度的用于生产单壁，双层和/或多壁型的碳纳米管（以下也称为“CNTS”）的连续方法。 优选的实施方案提供了用于在用于制备碳纳米管的方法期间连续供应催化剂的方法，根据该方法可以实现该方法的有利的连续性。

公开(公告)号：US09186656B2

公开(公告)日：2015-11-17

申请号：US13669343

申请日：2012-11-05

Applicant: Sang Kyu Choi ,  Sang Hyo Ryu ,  Ho Soo Hwang ,  Chung Heon Jeong ,  Dong Hoon Oh ,  Yeon Ja Lee ,  Youngchan Jang

Inventor： Sang Kyu Choi ,  Sang Hyo Ryu ,  Ho Soo Hwang ,  Chung Heon Jeong ,  Dong Hoon Oh ,  Yeon Ja Lee ,  Youngchan Jang

IPC: B01J23/00 ,  B01J23/10 ,  B01J23/883 ,  B01J37/03 ,  B01J37/08 ,  B01J23/889 ,  B01J23/881 ,  B01J23/882 ,  B01J23/885 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  B01J37/00 ,  B82Y40/00 ,  C01B31/02 ,  B82Y30/00

CPC classification number: C01B31/0233 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J23/887 ,  B01J23/8875 ,  B01J23/8885 ,  B01J23/8898 ,  B01J35/0013 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/03 ,  B01J37/088 ,  B01J2523/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/06 ,  Y10S977/752 ,  Y10S977/843 ,  Y10T428/2918 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/72 ,  B01J2523/17 ,  B01J2523/69 ,  B01J2523/47 ,  B01J2523/43

Abstract: The present invention relates to a catalyst composition for the synthesis of multi-walled carbon nanotube having high apparent density in a manner of high yield. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Mo, ii) inactive support of Al and iii) optional co-catalyst at least one selected from Co, Ni, Ti, Mn, W, Sn or Cu. Further, the present invention affords multi-walled carbon nanotube having 5˜15 nm of fibrous diameter and 0.5˜4 μm bundle diameter.

Abstract translation: 本发明涉及以高产率合成具有高表观密度的多壁碳纳米管的催化剂组合物。 更具体地说，本发明涉及一种多组分金属催化剂组合物，其包括i）Fe和Mo的主要催化剂，ii）Al的无活性载体和iii）任选的助催化剂，选自Co，Ni，Ti，Mn， W，Sn或Cu。 此外，本发明提供纤维直径为5〜15nm，束直径为0.5〜4μm的多壁碳纳米管。

公开(公告)号：US09067793B2

公开(公告)日：2015-06-30

申请号：US13225888

申请日：2011-09-06

Applicant: Yoshinori Ando ,  Xinluo Zhao ,  Sakae Inoue

Inventor： Yoshinori Ando ,  Xinluo Zhao ,  Sakae Inoue

IPC: C01B31/02 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: C01B31/0233 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/17 ,  C01B2202/02

Abstract: The present invention provides a method for producing a carbon nanotube having a high purity and a method for purifying an unpurified carbon nanotube or a carbon nanotube having a low purity. The method for producing a carbon nanotube comprises a step of providing a carbonaceous material containing a carbon nanotube and a step of adding an iron material and hydrogen peroxide to the carbonaceous material to thereby purity a carbon nanotube. It is preferred that an iron powder is used as the iron material. The iron powder is preferably used in a proportion of 0.5 to 20 parts by mass relative to 100 parts by mass of the whole carbonaceous material.

Abstract translation: 本发明提供一种纯度高的碳纳米管的制造方法以及纯化碳纳米管或纯度低的碳纳米管的纯化方法。 制造碳纳米管的方法包括提供含有碳纳米管的碳质材料和向碳质材料中添加铁物质和过氧化氢的步骤，从而纯化碳纳米管。 优选使用铁粉作为铁材料。 相对于100质量份的全部碳质材料，铁粉的使用比例优选为0.5〜20质量份。