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1.发明申请CARBON NANOTUBE-INFUSED FIBER MATERIALS CONTAINING PARALLEL-ALIGNED CARBON NANOTUBES, METHODS FOR PRODUCTION THEREOF, AND COMPOSITE MATERIALS DERIVED THEREFROM 有权含有平行对准的碳纳米管的碳纳米管输入的纤维材料，其生产方法及其衍生的复合材料公开(公告)号：US20110186775A1
公开(公告)日：2011-08-04
申请号：US13019248
申请日：2011-02-01
CPC分类号： D01F9/12 , B05D2256/00 , C01B32/158 , C08L25/02 , D06M11/73 , Y02B10/30 , Y10T428/2933
摘要： Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.
摘要翻译： 本文描述了含有基本上平行排列的，注入碳纳米管的碳纳米管注入的纤维材料。 碳纳米管注入的纤维材料包含纤维材料和注入纤维材料的碳纳米管层，其中输入的碳纳米管基本上平行于纤维材料的纵向轴线排列，并且至少部分基本平行的， 对准的，注入的碳纳米管彼此交联，与纤维材料或两者交联。 例如，交联可以通过共价键或π-层叠相互作用发生。 碳纳米管注入的纤维材料可以进一步包含生长在基本平行排列的输入碳纳米管层上的另外的碳纳米管。 包含碳纳米管注入的纤维材料的复合材料和碳纳米管注入的纤维材料的制造方法也在本文中描述。
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2.发明授权Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom 有权含有碳纳米管的含有平行取向的碳纳米管的纤维材料，其制造方法以及由其衍生的复合材料公开(公告)号：US08999453B2
公开(公告)日：2015-04-07
申请号：US13019248
申请日：2011-02-01
IPC分类号： D01F9/12
CPC分类号： D01F9/12 , B05D2256/00 , C01B32/158 , C08L25/02 , D06M11/73 , Y02B10/30 , Y10T428/2933
摘要： Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.
摘要翻译： 本文描述了含有基本上平行排列的，注入碳纳米管的碳纳米管注入的纤维材料。 碳纳米管注入的纤维材料包含纤维材料和注入纤维材料的碳纳米管层，其中输入的碳纳米管基本上平行于纤维材料的纵向轴线排列，并且至少部分基本平行的， 对准的，注入的碳纳米管彼此交联，与纤维材料或两者交联。 例如，交联可以通过共价键或π-层叠相互作用发生。 碳纳米管注入的纤维材料可以进一步包含生长在基本平行排列的输入碳纳米管层上的另外的碳纳米管。 包含碳纳米管注入的纤维材料的复合材料和碳纳米管注入的纤维材料的制造方法也在本文中描述。
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3.发明申请METAL SUBSTRATES HAVING CARBON NANOTUBES GROWN THEREON AND PROCESSES FOR PRODUCTION THEREOF 审中-公开含有碳纳米管的金属基材及其生产方法公开(公告)号：US20120058296A1
公开(公告)日：2012-03-08
申请号：US13223183
申请日：2011-08-31
申请人： Tushar K. SHAH , Brandon K. Malet , Jigar M. Patel
发明人： Tushar K. SHAH , Brandon K. Malet , Jigar M. Patel
CPC分类号： D01F9/127 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/34 , C01B2202/36 , C23C16/0272 , C23C16/26 , Y10T428/23979 , Y10T428/31678
摘要： Processes for growing carbon nanotubes on metal substrates are described herein. The processes include depositing a catalyst precursor on a metal substrate, optionally depositing a non-catalytic material on the metal substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the metal substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The metal substrate can remain stationary or be transported while the carbon nanotubes are being grown. Metal substrates having carbon nanotubes grown thereon are also described.
摘要翻译： 本文描述了用于在金属基底上生长碳纳米管的方法。 所述方法包括在金属基材上沉积催化剂前体，任选地在金属基材上沉积非催化材料，以及在沉积催化剂前体和任选的非催化材料之后，将金属底物暴露于碳纳米管生长条件下，以便 在其上生长碳纳米管。 碳纳米管生长条件将催化剂前体转化为可用于生长碳纳米管的催化剂。 金属基底可以在碳纳米管生长期间保持静止或运输。 还描述了其上生长有碳纳米管的金属基底。
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4.发明申请METAL SUBSTRATES HAVING CARBON NANOTUBES GROWN THEREON AND METHODS FOR PRODUCTION THEREOF 审中-公开含有碳纳米管的金属基材及其生产方法公开(公告)号：US20120058352A1
公开(公告)日：2012-03-08
申请号：US13042397
申请日：2011-03-07
申请人： Tushar K. SHAH , Brandon K. Malet , Jigar M. Patel
发明人： Tushar K. SHAH , Brandon K. Malet , Jigar M. Patel
CPC分类号： D01F9/127 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/34 , C01B2202/36 , C23C16/0272 , C23C16/26 , Y10T428/23979 , Y10T428/31678
摘要： The present disclosure describes methods for growing carbon nanotubes on metal substrates. The methods include depositing a catalytic material on a metal substrate to form a catalyst-laden metal substrate; optionally depositing a non-catalytic material on the metal substrate prior to, after, or concurrently with the catalytic material; conveying the catalyst-laden metal substrate through a carbon nanotube growth reactor having carbon nanotube growth conditions therein; and growing carbon nanotubes on the catalyst-laden metal substrate. The catalyst-laden metal substrate can optionally remain stationary while the carbon nanotubes are being grown. The catalytic material can be a catalyst or a catalyst precursor. The catalytic material and the optional non-catalytic material can be deposited on the metal substrate from one or more solutions by, for example, spray coating or dip coating techniques.
摘要翻译： 本公开描述了在金属基底上生长碳纳米管的方法。 所述方法包括在金属基底上沉积催化材料以形成载有催化剂的金属基底; 任选地在催化材料之前，之后或同时在金属基底上沉积非催化材料; 通过其中具有碳纳米管生长条件的碳纳米管生长反应器输送载有催化剂的金属基底; 并在载有催化剂的金属基底上生长碳纳米管。 当生长碳纳米管时，载有催化剂的金属基底可任选保持静止。 催化剂材料可以是催化剂或催化剂前体。 催化材料和任选的非催化材料可以通过例如喷涂或浸涂技术从一种或多种溶液沉积在金属基材上。
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5.发明申请公开(公告)号：US20100227134A1
公开(公告)日：2010-09-09
申请号：US12713147
申请日：2010-02-25
CPC分类号： C01B32/16 , B01J21/185 , B01J23/745 , B01J35/0013 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/162 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , Y10S977/842 , Y10T428/2495 , Y10T428/25
摘要： A method includes: (a) conformally depositing a barrier coating, provided in liquid form, on at least one surface of a substrate; (b) embedding a plurality of nanoparticles in the barrier coating to a selected depth; and (c) fully curing the barrier coating after embedding the plurality of nanoparticles; the embedded plurality of nanoparticles are in continuous contact with the cured barrier coating. The order in which the barrier coating and nanoparticles are deposited on the substrate can be switched or they can be deposited simultaneously. An article includes a substrate having a cured barrier coating conformally disposed on at least one surface of the substrate and a plurality of nanoparticles embedded to a selected depth in the barrier coating creating an embedded portion of each of the plurality of nanoparticles. The embedded portion of each of the plurality of nanoparticles in continuous contact with the cured barrier coating.
摘要翻译： 一种方法包括：（a）在衬底的至少一个表面上保形地沉积以液体形式提供的阻挡涂层; （b）将所述阻挡涂层中的多个纳米颗粒嵌入所选择的深度; 和（c）在嵌入所述多个纳米颗粒之后使所述阻隔涂层完全固化; 嵌入的多个纳米颗粒与固化的阻挡涂层持续接触。 阻挡涂层和纳米颗粒沉积在基底上的顺序可以被切换，或者它们可以同时沉积。 一种制品包括具有固化的阻挡涂层的基底，其被保形地设置在基底的至少一个表面上，并且多个纳米颗粒嵌入到阻挡涂层中的选定深度，形成多个纳米颗粒中每一个的嵌入部分。 多个纳米颗粒中的每一个的嵌入部分与固化的阻挡涂层连续接触。
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6.发明申请SYSTEM AND METHOD FOR SURFACE TREATMENT AND BARRIER COATING OF FIBERS FOR IN SITU CNT GROWTH 审中-公开用于表面处理的纤维的表面处理和遮蔽涂层的系统和方法公开(公告)号：US20100224129A1
公开(公告)日：2010-09-09
申请号：US12713146
申请日：2010-02-25
CPC分类号： C01B32/16 , B01J21/185 , B01J23/745 , B01J35/0013 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/162 , D06B1/02 , D06B3/10 , D06B19/00 , D06M11/74 , Y10S977/842 , Y10T428/2495 , Y10T428/25
摘要： A system for synthesizing carbon nanotubes (CNT) on a fiber material includes a surface treatment system adapted to modify the surface of the fiber material to receive a barrier coating upon which carbon nanotubes are to be grown, a barrier coating application system downstream of the surface treatment system adapted to apply the barrier coating to the treated fiber material surface, and a barrier coating curing system downstream of the barrier coating application system for partially curing the applied barrier coating to enhance reception of CNT growth catalyst nanoparticles.
摘要翻译： 用于在纤维材料上合成碳纳米管（CNT）的系统包括：表面处理系统，其适于改变纤维材料的表面以接收要在其上生长碳纳米管的阻挡涂层，在表面下游的阻挡涂层施加系统 适于将阻挡涂层施加到经处理的纤维材料表面的处理系统，以及用于部分固化所施加的阻隔涂层以增强CNT生长催化剂纳米颗粒的接收的阻隔涂层施加系统下游的阻隔涂层固化体系。
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7.发明授权Glass substrates having carbon nanotubes grown thereon and methods for production thereof 有权具有碳纳米管生长的玻璃基板及其制造方法公开(公告)号：US08784937B2
公开(公告)日：2014-07-22
申请号：US13230751
申请日：2011-09-12
申请人： Brandon K. Malet , Tushar K. Shah
发明人： Brandon K. Malet , Tushar K. Shah
IPC分类号： C23C16/00 , C01B31/02 , D01F9/127 , C03C25/10 , C03C25/22 , C03C25/44 , B82Y30/00 , C23C16/26 , C23C16/458 , C23C16/54 , B05D3/10
CPC分类号： B05D3/10 , B01J21/185 , B01J23/75 , B01J35/06 , B01J37/0213 , B05D2203/35 , B05D2256/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/164 , C01B2202/34 , C03C17/28 , C03C25/1095 , C03C25/223 , C03C25/24 , C03C25/44 , C23C16/26 , C23C16/458 , C23C16/545 , D01F9/127 , Y10S977/843 , Y10S977/891 , Y10T428/25
摘要： Methods for growing carbon nanotubes on glass substrates, particularly glass fiber substrates, are described herein. The methods can include depositing a catalytic material or a catalyst precursor on a glass substrate; depositing a non-catalytic material on the glass substrate prior to, after, or concurrently with the catalytic material or catalyst precursor; and exposing the glass substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The glass substrate, particularly a glass fiber substrate, can be transported while the carbon nanotubes are being grown thereon. Catalyst precursors can be converted into a catalyst when exposed to carbon nanotube growth conditions. The catalytic material or catalyst precursor and the non-catalytic material can be deposited from a solution containing water as a solvent. Illustrative deposition techniques include, for example, spray coating and dip coating.
摘要翻译： 本文描述了在玻璃基底，特别是玻璃纤维基底上生长碳纳米管的方法。 所述方法可以包括在玻璃基底上沉积催化材料或催化剂前体; 在催化材料或催化剂前体之前，之后或同时在玻璃基板上沉积非催化材料; 并将玻璃基板暴露于碳纳米管生长条件，以便在其上生长碳纳米管。 玻璃基板，特别是玻璃纤维基板，可以在碳纳米管在其上生长的同时被输送。 当暴露于碳纳米管生长条件时，催化剂前体可以转化为催化剂。 催化剂材料或催化剂前体和非催化材料可以从含有水作为溶剂的溶液沉积。 示例性沉积技术包括例如喷涂和浸涂。
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8.发明申请公开(公告)号：US20120070667A1
公开(公告)日：2012-03-22
申请号：US13231869
申请日：2011-09-13
申请人： Brandon K. Malet , Tushar K. Shah
发明人： Brandon K. Malet , Tushar K. Shah
CPC分类号： B82Y30/00 , B05D2256/00 , B82Y40/00 , C01B32/158 , C01B32/162 , C01B2202/34 , C01B2202/36 , C23C16/26 , C23C16/458 , C23C16/545 , Y10S977/843 , Y10S977/891 , Y10T428/30
摘要： Processes for growing carbon nanotubes on carbon fiber substrates are described herein. The processes can include depositing a catalyst precursor on a carbon fiber substrate, optionally depositing a non-catalytic material on the carbon fiber substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the carbon fiber substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions can convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The carbon fiber substrate can remain stationary or be transported while the carbon nanotubes are being grown. Optionally, the carbon fiber substrates can include a barrier coating and/or be free of a sizing agent. Carbon fiber substrates having carbon nanotubes grown thereon are also described.
摘要翻译： 本文描述了用于在碳纤维基底上生长碳纳米管的方法。 该方法可以包括将催化剂前体沉积在碳纤维基材上，任选地在碳纤维基材上沉积非催化材料，以及在沉积催化剂前体和任选的非催化材料之后，将碳纤维基材暴露于碳纳米管生长 条件，以便在其上生长碳纳米管。 碳纳米管生长条件可将催化剂前体转化成可用于生长碳纳米管的催化剂。 碳纤维基材可以在碳纳米管生长过程中保持静止或运输。 任选地，碳纤维基材可以包括阻隔涂层和/或不含上浆剂。 还描述了其上生长有碳纳米管的碳纤维基材。
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9.发明授权Carbon fiber substrates having carbon nanotubes grown thereon and processes for production thereof 有权具有生长在其上的碳纳米管的碳纤维基材及其生产方法公开(公告)号：US08815341B2
公开(公告)日：2014-08-26
申请号：US13231869
申请日：2011-09-13
申请人： Brandon K. Malet , Tushar K. Shah
发明人： Brandon K. Malet , Tushar K. Shah
CPC分类号： B82Y30/00 , B05D2256/00 , B82Y40/00 , C01B32/158 , C01B32/162 , C01B2202/34 , C01B2202/36 , C23C16/26 , C23C16/458 , C23C16/545 , Y10S977/843 , Y10S977/891 , Y10T428/30
摘要： Processes for growing carbon nanotubes on carbon fiber substrates are described herein. The processes can include depositing a catalyst precursor on a carbon fiber substrate, optionally depositing a non-catalytic material on the carbon fiber substrate, and after depositing the catalyst precursor and the optional non-catalytic material, exposing the carbon fiber substrate to carbon nanotube growth conditions so as to grow carbon nanotubes thereon. The carbon nanotube growth conditions can convert the catalyst precursor into a catalyst that is operable for growing carbon nanotubes. The carbon fiber substrate can remain stationary or be transported while the carbon nanotubes are being grown. Optionally, the carbon fiber substrates can include a barrier coating and/or be free of a sizing agent. Carbon fiber substrates having carbon nanotubes grown thereon are also described.
摘要翻译： 本文描述了用于在碳纤维基底上生长碳纳米管的方法。 该方法可以包括将催化剂前体沉积在碳纤维基材上，任选地在碳纤维基材上沉积非催化材料，以及在沉积催化剂前体和任选的非催化材料之后，将碳纤维基材暴露于碳纳米管生长 条件，以便在其上生长碳纳米管。 碳纳米管生长条件可将催化剂前体转化成可用于生长碳纳米管的催化剂。 碳纤维基材可以在碳纳米管生长过程中保持静止或运输。 任选地，碳纤维基材可以包括阻隔涂层和/或不含上浆剂。 还描述了其上生长有碳纳米管的碳纤维基材。
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公开(公告)号：US09085464B2
公开(公告)日：2015-07-21
申请号：US13414669
申请日：2012-03-07
申请人： Harry C. Malecki , Randy L. Gaigler , Corey A. Fleischer , Han Liu , Brandon K. Malet , Samuel J. Markkula
发明人： Harry C. Malecki , Randy L. Gaigler , Corey A. Fleischer , Han Liu , Brandon K. Malet , Samuel J. Markkula
IPC分类号： C23C16/00 , C01B31/02 , B82Y30/00 , B82Y40/00 , C23C16/52 , G01R27/08 , D04H1/00 , D04H3/00 , D04H5/00 , D04H13/00 , B32B17/12 , B32B18/00 , B32B27/04 , B32B27/12 , G01N27/04 , B82Y35/00
摘要： A quality control system for the manufacture of carbon nanostructure-laden substrates includes a resistance measurement module for continuously measuring resistance of the carbon nanostructure (CNS)-laden substrate.
摘要翻译： 用于制造载有碳纳米结构的基板的质量控制系统包括用于连续测量载有碳纳米结构（CNS）的基板的电阻的电阻测量模块。
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