Process for hydrotreating a residue stream with hydrogen recycle

    公开(公告)号:US11028326B2

    公开(公告)日:2021-06-08

    申请号:US15884219

    申请日:2018-01-30

    Applicant: UOP LLC

    Inventor: Ping Sun

    Abstract: The subject process enhances catalytic activity for demetallization and desulfurization of a residue feed stream by splitting a recycle hydrogen stream and feeding each of the split hydrogen streams to the first and second stages of demetallation and desulfurization, respectively, with interstage separation. The recycle hydrogen stream may first undergo scrubbing to remove acid gases and compression before recycle. The recycle hydrogen stream is taken from a first hot vapor stream from the first hydrotreating unit and a second hot vapor stream from the second hydrotreating unit.

    PROCESS AND APPARATUS FOR INTRODUCING CATALYST PRECURSOR INTO SLURRY HYDROCRACKING REACTOR

    公开(公告)号:US20230110405A1

    公开(公告)日:2023-04-13

    申请号:US17499670

    申请日:2021-10-12

    Applicant: UOP LLC

    Abstract: A SHC apparatus and process comprise a catalyst precursor reactor for providing a catalyst precursor stream in downstream communication with a source of molybdenum, a SHC feed line for providing a heavy hydrocarbon feed stream in downstream communication with a heater, and a SHC reactor in downstream communication with the SHC feed line and with the catalyst precursor reactor. A process for SHC, the process comprising preparing a catalyst precursor stream comprising molybdenum in a catalyst precursor reactor, mixing the catalyst precursor stream with a heavy hydrocarbon stream to provide a catalyst precursor concentrate stream, heating a hydrocracking hydrocarbon feed stream in a heater to provide a heated hydrocracking feed stream, mixing the catalyst precursor concentrate stream with the heated hydrocarbon stream to provide a SHC feed stream, and reacting the SHC feed stream in a SHC reactor.

    PROCESS FOR PVC-CONTAINING MIXED PLASTIC WASTE PYROLYSIS IN A REACTOR HANDLING THREE PHASES OF PRODUCTS

    公开(公告)号:US20220204861A1

    公开(公告)日:2022-06-30

    申请号:US17524326

    申请日:2021-11-11

    Applicant: UOP LLC

    Abstract: A process for pyrolysis of a mixed plastic stream that contains polyvinyl chloride (PVC) is provided in which the chloride from PVC is removed from an initial melting reactor that melts the mixed plastic stream. Chloride is removed in a vapor stream from the initial melting reactor with additional chloride removed from addition of sorbents to the pyrolysis reactor and in adsorbent beds downstream of the pyrolysis reactor. The pyrolysis reactor has a configuration comprising two cylindrical ring structures, an inner cylindrical ring structure within an outer cylindrical ring structure wherein a circulation liquid supply stream enters said pyrolysis reactor tangentially relative to a ring edge of said two cylindrical ring structures and wherein solid particles move in a downward direction to a bottom of the pyrolysis reactor.

    PROCESS FOR PVC-CONTAINING MIXED PLASTIC WASTE PYROLYSIS

    公开(公告)号:US20220010213A1

    公开(公告)日:2022-01-13

    申请号:US17367336

    申请日:2021-07-03

    Applicant: UOP LLC

    Abstract: A process for pyrolysis of a mixed plastic stream that contains polyvinyl chloride (PVC) is provided in which the chloride from PVC is removed from an initial melting reactor that heats the mixed plastic stream to a sufficient temperature to produce HCl but at a low enough temperature to avoid production of organochlorides. Chloride is primarily removed in a vapor stream from the initial melting reactor, while additional chloride removal may be removed downstream from the melting reactor by the use of sorbent addition to the pyrolysis reactor and by subsequent adsorbent beds.

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