摘要:
The present invention relates to a process for the preparation of hydrogen peroxide from oxygen or oxygen-delivering substances and hydrogen or hydrogen-delivering substances in the presence of at least one catalyst containing a metal-organic framework material, wherein said framework material comprises pores and a metal ion and an at least bidentate organic compound, said bidentate organic compound being coordinately bound to the metal ion. The invention further relates to a novel material consisting of said metal organic framework material wherein the material is brought in contact with at least one additional metal.
摘要:
The present invention relates to a process for the alkoxylation of a monool with at least one alkoxylating agent to an alkoxylated alcohol wherein a catalyst is employed which comprises a metallo-organic framework material of metal ions and at least bidentate coordinately bound organic ligands.
摘要:
Process for hydrogenating an organic compound having at least one carbonyl group, in which the organic compound is contacted, in the presence of hydrogen, with a shaped body which is producible in a process in which (i) an oxidic material comprising copper oxide and aluminum oxide and at least one of the oxides of iron, lanthanum, tungsten, molybdenum, titanium, zirconium, tin or manganese, and if appropriate additionally tin oxide and/or manganese oxide, is provided, (ii) pulverulent metallic copper, copper flakes, pulverulent cement, graphite or a mixture thereof are added to the oxidic material, (iii) the mixture resulting from (ii) is shaped to a shaped body and (iv) the shaped body is treated with water or steam.
摘要:
A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one further group which is not a carboxy group and which is capable of forming a hydrogen bridge linkage.
摘要:
The present invention relates to a method of storing a liquefied gas in a container containing a metal-organic framework material, the container filled with such a gas, a process for filling container and the use of the container to release the gas.
摘要:
The present invention relates to an integrated process for the synthesis of propylene oxide, which comprises at least the following steps: (i) dehydrogenation of propane to give a substream T (0) comprising at least propane, propene and hydrogen; (ii) fractionation of the substream T (0) to give at least one gaseous hydrogen-rich substream T (2) and a substream T (1) comprising at least propene and propane; (iii) synthesis of hydrogen peroxide using the substream T (2), giving a substream T (4) which is rich in hydrogen peroxide and a gaseous substream T (6); (iv) fractionation of the substream T (1) to give at least one propane-rich substream T (5) and at least one propene-rich substream T (3); (v) reaction of the at least one substream T (3) with substream T (4) to give propylene oxide.
摘要:
The present invention is directed to temperature modulated refractive index measurement. In accordance with the invention a method for determination of the complex temperature coefficient of the refractive index of a sample is provided, wherein the determination of the complex temperature coefficient of the refractive index of the sample is based on a refractive index measurement. Furthermore, the refractive index of the sample is measured over a period of time, wherein the temperature of the sample is modulated over said period of time and the complex temperature coefficient of the refractive index is calculated on the basis of the refractive index measurement over the period of time and the temperature modulation over the period of time. Additionally, a measurement system, in particular comprising a temperature control system and a processing system to carry out the above method, is disclosed.
摘要:
The present invention relates to a process for preparing alkylaromatics by reacting aromatic compounds with C1-C14-alkanes in the presence of a heterogeneous catalyst, which comprises using as the catalyst a crystalline, micro- and/or mesoporous solid comprising silicon and at least one father element selected from the group consisting of the transition metals and the main group elements gallium and tin, and activating said catalysts by a reducing pretreatment. Furthermore, the present invention relates to a process for preparing alkylarylsulfonates by sulfonating and neutralizing the alkyl aromatic compounds.
摘要:
The present invention relates to a molding composition, comprising from 10 to 99.999% by weight of at least one polyoxymethylene as component (A1) and from 0.001 to 10% by weight, based on the weight of component (A1) present in the molding composition, of at least one zeolitic material whose pore diameter is in the range from 0.3 to 0.5 nm, determined to DIN 66134 and DIN 66135, where the size of the particles of the zeolitic material is in the range from 3 to 7 μm, determined to ISO 13320, and also to moldings that can be produced from this molding composition.
摘要翻译:本发明涉及一种模塑组合物,其包含10至99.999重量%的至少一种作为组分(A1)的聚甲醛和0.001至10重量%,基于模塑组合物中存在的组分(A1)的重量 的至少一种沸石材料,其孔径在0.3至0.5nm的范围内,根据DIN 66134和DIN 66135确定,其中沸石材料的颗粒的尺寸在3至7μm的范围内,确定为 ISO 13320,以及可以由该模塑组合物制造的模制品。