摘要:
Hydrophilic polyacrylonitrile filaments or fibres where at least one filament-forming synthetic polymer is wet spun in a spinning solvent and wherein the spinning solvent has added to it from 10 to 20% by weight of a substance which is readily miscible with the spinning solvent and a washing liquid and is a nonsolvent for the polymer to be spun.
摘要:
The invention relates to a process for the production of hydrophilic filaments or fibres having a sheath/core structure, a porosity of at least 10% and a water retention capacity of at least 10% and having a fibre swelling factor which is lower than the water retention capacity. The process is carried out by spinning a solution of a fibre forming synthetic polymer, especially an acrylonitrile polymer by the dry jet wet-spinning method wherein immediately on leaving the spinning jet and prior to coagulation in the precipitation bath the filaments or fibres are contacted with steam or with the vapor of another liquid which coagulates the filaments.
摘要:
The invention relates to a bi-component filament or fibre of a fibre-forming synthetic polymer having a core/sheath structure in at least one component and having a moisture absorption of at least 1.5% at 65% relative atmospheric humidity and at a temperature of 21.degree. C. and a moisture absorption of at least 5% at 90% relative atmospheric humidity and 21.degree. C. and a water-retention-power of at least 10% as well as to a process for the production thereof.
摘要:
The invention relates to a process for the production of hydrophilic filaments and fibres from a filament-forming synthetic polymer by a wet- or dry-spinning process which comprises introducing into the spinning solvent from 5 to 50% by weight of a substance with special properties defined herein and from 0.05 to 5% by weight of at least one surface-active compound as well as to hydrophilic filaments and fibres produced by such process.
摘要:
The invention relates to hygroscopic filaments and fibres of synthetic high polymers. The improved hygroscopicity compared with known synthetic fibres is due to the fact, that in a conventional dry-spun process a liquid is added to the spinning solvent which liquid has a higher boiling point than the spinning solvent used, which liquid is readily miscible both with the spinning solvent and water and which represents a non-solvent for the polymer to be spun.
摘要:
Described are a process for producing elastane yarn having a linear density of at least 2500 dtex by the wet spinning process and the thereby producible coarse linear density elastane yarn having a wide cross section and a low residual solvent content. The process comprises the steps of spinning an up to 35% strength by weight stable-viscosity elastane solution into a coagulation bath, washing and optionally drawing, drying by contact heating, setting, spin finishing and winding the yarn, the filaments leaving the coagulation bath passing around a diverting roller disposed just above the coagulation bath liquid, the as-spun filament linear density amounting to not more than 1% of the value of the final linear density, the jet stretch ratio being within the range from 0.5 to 50, the contact heating temperature being at least 220° C. and the contact time of the elastane yarn being at least 2 seconds.
摘要:
The invention relates to a process for preparing multifilament, wet-spun elastane threads with increased spinning output, which is achieved by largely removing entrained water from the filaments after leaving the spinning bath and then fixing the threads on at least two rollers at a temperature of at least 200.degree. C. for at least 3 seconds.
摘要:
A process for the dry spinning of synthetic polymers, in particular polyacylonitrile fibres, from solutions in high polar solvents, such as dimethylformamide, which are heated to 100.degree.-150.degree. C. shortly upstream of the spinneret and spun there by spinnerets having a certain shape, and in the spinning cell the specific energy supply is at least 0.090 kWh per m.sup.2 of heated cell area, the cell is charged with at least 70 m.sup.3 (S.T.P.) of hot air per hour, and the filaments are treated in the lower part of the cell with water or aqueous preparations, so that the temperature of the filaments which leave the cell is decreased below 110.degree. C. Under these conditions, the unexpectedly high spinning cell outputs of at least 20 kg of PAN solid per spinning cell per hour can be achieved without yellowing or self-ignition of the filaments occurring.
摘要:
Hollow acrylonitrile fibres and filaments are prepared by dry spinning the spinning dope through a nozzle having loop-shaped nozzle orifices, the solution having a viscosity equivalent to at least 120 falling ball seconds, measured at 80.degree. C., or at least 75 falling ball seconds, measured at 100.degree. C., wherein the nozzle orifice area of the profiling nozzle is smaller than 0.2 mm.sup.2 and the maximum width of the sides of the loop-shaped nozzle is 0.1 mm and the overlap between the two ends of the sides of the loop-shaped nozzle forms an angle of from 10.degree. to 30.degree. measured from the center of the nozzle and wherein the spinning air acts on the filaments in a transverse direction to the filament take-off and the air direction forms an angle of from 80.degree. to 100.degree. with a straight line passing through the opening between the sides.