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    Preparation of amines
    1.
    发明授权
    Preparation of amines 失效
    胺的制备

    公开(公告)号：US5817871A

    公开(公告)日：1998-10-06

    申请号：US921769

    申请日：1997-08-15

    申请人： Uwe Dingerdissen ,  Gunter Lauth ,  Andreas Henne ,  Peter Stops ,  Karsten Eller ,  Eugen Gehrer

    发明人： Uwe Dingerdissen ,  Gunter Lauth ,  Andreas Henne ,  Peter Stops ,  Karsten Eller ,  Eugen Gehrer

    IPC分类号： B01J27/18 ,  B01J27/182 ,  B01J27/185 ,  B01J27/188 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/05 ,  C07C211/06 ,  C07C211/07 ,  C07C211/08 ,  C07C211/35

    CPC分类号： C07C211/35 ,  C07C209/60 ,  C07C211/07 ,  C07C2101/08

    摘要： A process for preparing an amine by catalytic reaction of an olefin with ammonia or a primary or secondary amine by contacting a mixture of the reactants in a reactor at 200.degree. to 400.degree. C. and an elevated pressure up to 700 bar in the presence of a catalyst consisting essentially of an X-ray amorphous (non-crystalline) mesoporous catalyst, some of which may have a microporous non-crystalline content. The catalyst has the composition a MO.sub.2 * b Q.sub.2 O.sub.3 * c P.sub.2 O.sub.5 where Q is at least one of the trivalent elements aluminum, boron, chromium, iron or gallium, and M is at least one of the tetravalent elements silicon, titanium or germanium. The molar ratio of a:b is from 0.5:1 to 1000:1 and the molar ratio of c:b is from 0 to 2:1. As prepared and used in the process, this non-crystalline catalyst has a specific BET surface area of from 200 to 1000 m.sup.2 /g.

    摘要翻译： 通过使烯烃与氨或伯胺或仲胺进行催化反应来制备胺的方法，该方法是将反应物的混合物在200-400℃的反应器和高达700巴的升高的压力下反应， 主要由X射线无定形（非结晶）介孔催化剂组成的催化剂，其中一些可能具有微孔非晶体含量。 催化剂具有以下组成：MO2 * b Q2O3 * c P2O5其中Q是三价元素铝，硼，铬，铁或镓中的至少一种，M是四价元素硅，钛或锗中的至少一种。 a:b的摩尔比为0.5:1-1000:1，c:b的摩尔比为0-2:1。 在该方法中制备和使用时，该非结晶催化剂的BET比表面积为200-1000m2 / g。

    Preparation of amines from olefins over hexagonal faujasites
    2.
    发明授权
    Preparation of amines from olefins over hexagonal faujasites 失效
    在六边形八面体上由烯烃制备胺

    公开(公告)号：US5773660A

    公开(公告)日：1998-06-30

    申请号：US784548

    申请日：1997-01-21

    申请人： Karsten Eller ,  Rudolf Kummer ,  Eugen Gehrer

    发明人： Karsten Eller ,  Rudolf Kummer ,  Eugen Gehrer

    IPC分类号： B01J29/08 ,  C07B43/04 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C209/02

    CPC分类号： C07C209/60

    摘要： A process for preparing amines of the formula I ##STR1## where R.sup.1,R.sup.2,R.sup.3,R.sup.4,R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl, R.sup.1 and R.sup.2 are together a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene dichain, and R.sup.3 or R.sup.5 is C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl or together they are a C.sub.2 -C.sub.12 -alkylene dichain, by reacting olefins of the formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, with ammonia or primary or secondary amines of the formula III ##STR3## where R.sup.1 and R.sup.2 are each as defined above, at temperatures from 200.degree. to 350.degree. C. and pressures from 100 to 300 bar in the presence of a heterogeneous catalyst using a heterogeneous catalyst comprising hexagonal faujasite.

    摘要翻译： 制备式I的胺的方法其中R 1，R 2，R 3，R 4，R 5和R 6各自为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20 - 炔基，C 3 -C 20 - 环烷基，C 4 -C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基，芳基，C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基，R 1和R 2一起是饱和或不饱和的C 3 -C 9 - 亚烷基二烯基，R3或 R5是C21-C200-烷基或C21-C200-烯基，或者它们一起是C2-C12-亚烷基二烯，通过使式II的烯烃（II）反应，其中R3，R4，R5和R6各自定义 与式III（III）的氨或伯胺或仲胺，其中R 1和R 2各自如上定义，在200-350℃的温度和100-300巴的压力下，在存在 使用包含六边形八面沸石的多相催化剂的多相催化剂。

    Method for producing halogen-free reactive polyisobutene
    3.
    发明授权
    Method for producing halogen-free reactive polyisobutene 失效
    生产无卤素的反应性聚异丁烯的方法

    公开(公告)号：US06441110B1

    公开(公告)日：2002-08-27

    申请号：US09367194

    申请日：1999-08-06

    申请人： Christoph Sigwart ,  Thomas Narbeshuber ,  Karsten Eller ,  Manfred Barl ,  Rolf Fischer ,  Eugen Gehrer

    发明人： Christoph Sigwart ,  Thomas Narbeshuber ,  Karsten Eller ,  Manfred Barl ,  Rolf Fischer ,  Eugen Gehrer

    IPC分类号： C08F424

    CPC分类号： C08F110/10 ,  C08F10/10 ,  C08F4/24 ,  C08F4/20 ,  C08F4/025

    摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 50 mol % and an average molecular weight Mn of 280-10000 dalton by the cationic polymerization in the liquid phase of isobutene or hydrocarbon mixtures comprising isobutene comprises polymerizing at from −30° C. to +40° C. in the presence of a heterogeneous polymerisation catalyst comprising one or more oxides of the elements of transition groups V and VI of the Periodic Table of the Elements or in the presence of a heterogeneous polymerization catalyst comprising one or more oxidic compounds of one or more elements of transition groups V and VI of the Periodic Table of the Elements supported on a non-zeolitic oxidic support material which is not an oxygen-containing zirconium compound, the catalyst not containing a technically effective amount of halogen.

    摘要翻译： 通过在异丁烯或包含异丁烯的烃混合物的液相中的阳离子聚合制备末端双键含量大于50mol％，平均分子量Mn为280-10000dalton的无卤活性聚异丁烯的方法包括聚合 在-30℃至+ 40℃下，在包含元素周期表的过渡基团V和VI的元素的一种或多种氧化物的非均相聚合催化剂的存在下，或在非均相聚合 催化剂包含负载在不是含氧锆化合物的非沸石氧化载体材料上的元素周期表的一个或多个过渡基团V和VI元素的一种或多种氧化化合物，该催化剂不含技术上 有效量的卤素。

    Preparation of 1,1-diphenylethanes
    4.
    发明授权
    Preparation of 1,1-diphenylethanes 失效
    制备1,1-二苯基乙烷

    公开(公告)号：US5880321A

    公开(公告)日：1999-03-09

    申请号：US46692

    申请日：1998-03-24

    申请人： Eugen Gehrer ,  Karsten Eller ,  Gunther Effler

    发明人： Eugen Gehrer ,  Karsten Eller ,  Gunther Effler

    IPC分类号： C07C2/66 ,  C07C17/266 ,  C07C17/269 ,  C07C45/69 ,  C07C67/293 ,  C07C1/20

    CPC分类号： C07C2/66 ,  C07C17/266 ,  C07C17/269 ,  C07C45/69 ,  C07C2529/70

    摘要： In a process for preparing unsubstituted or substituted 1,1-diphenylethanes by catalytic reaction of benzene and styrene in the presence of a zeolite catalyst, it being possible for benzene and styrene each independently to have 1 to 5 substituents selected from halogen, C.sub.1-10 -alkyl, C.sub.1-10 -alkoxy, C.sub.1-10 -acyl, C.sub.1-10 -acyloxy or cyano, the zeolite catalyst is of the EMT or ZSM-20 type.

    摘要翻译： 在沸石催化剂存在下，通过苯和苯乙烯的催化反应制备未取代或取代的1,1-二苯基乙烷的方法中，苯和苯乙烯各自独立地具有1至5个选自卤素，C 1-10的取代基 - 烷基，C 1-10 - 烷氧基，C 1-10酰基，C 1-10 - 酰氧基或氰基，沸石催化剂为EMT或ZSM-20型。

    Catalytic preparation of condensation products of formaldehyde
    9.
    发明授权
    Catalytic preparation of condensation products of formaldehyde 失效
    催化制备甲醛缩合产物

    公开(公告)号：US5585496A

    公开(公告)日：1996-12-17

    申请号：US570557

    申请日：1995-12-11

    申请人： Joaquim H. Teles ,  Johann-Peter Melder ,  Eugen Gehrer ,  Wolfgang Harder ,  Klaus Ebel ,  Carsten Groening ,  Regina Meyer

    发明人： Joaquim H. Teles ,  Johann-Peter Melder ,  Eugen Gehrer ,  Wolfgang Harder ,  Klaus Ebel ,  Carsten Groening ,  Regina Meyer

    IPC分类号： B01J31/02 ,  C07B61/00 ,  C07C45/75 ,  C07C47/19 ,  C07C49/17 ,  C07D249/08 ,  C07D249/10 ,  C07D249/12 ,  C07D249/14 ,  C07D471/06

    CPC分类号： C07C45/75

    摘要： A process for the catalytical preparation of condensation products of formaldehyde, in which formaldehyde or a formaldehyde-forming compound is caused to undergo reaction using a catalyst which has been produced, in the presence of an auxiliary base, from a triazolium salt of formula I ##STR1## in which R.sup.1 and R.sup.3 are the same or different and stand for aliphatic groups having from 1 to 30 carbon atoms, optionally substituted aryl groups, optionally substituted aralkyl groups, and/or optionally substituted heteroaryl groups,R.sup.2 represents hydrogen, the hydroxymethylene group --CH.sub.2 OH or the hydroxy-hydroxymethylene-methylidyne group --CH(OH)(CH.sub.2 OH), andR.sup.4 denotes hydrogen, a halogen atom, a nitro or cyano group, an aliphatic group having from 1 to 30 carbon atoms, an optionally substituted aryl group, an optionally substituted aralkyl group, an optionally substituted heteroaryl group, an alkoxy group --OR.sup.5, a thioether group --SR.sup.6, an amino group --NR.sup.7 R.sup.8, an acyl group--COR.sup.9 or an ester group --COOR.sup.10, where R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 stand for radicals such as those stated above for R.sup.1, and R.sup.10 is a C.sub.1 -C.sub.10 alkyl group or an optionally substituted aryl or aralkyl group, orR.sup.3 and R.sup.4 together form a C.sub.3 -C.sub.5 alkylene or C.sub.3 -C.sub.5 alkenylene group or a C.sub.6 -C.sub.14 alkylene group, or a C.sub.7 -C.sub.14 aralkylene or C.sub.8 -C.sub.14 aralkenylene bridging member, andA is the equivalent of an anion having one or more negative charges for electrical neutralization of the charge on the triazolium cation.

    摘要翻译： 催化制备甲醛缩合产物的方法，其中使甲醛或形成甲醛的化合物在辅助碱存在下由式I的三唑鎓盐生产的催化剂进行反应， （I）其中R1和R3相同或不同，代表具有1至30个碳原子的脂族基团，任选取代的芳基，任选取代的芳烷基和/或任选取代的杂芳基，R 2表示氢， 羟基亚甲基-CH 2 OH或羟基 - 羟基亚甲基 - 亚甲基基团-CH（OH）（CH 2 OH），R 4表示氢，卤素原子，硝基或氰基，具有1至30个碳原子的脂族基团， 取代的芳基，任选取代的芳烷基，任选取代的杂芳基，烷氧基-OR 5，硫醚基-SR 6，氨基-NR 7 R 8，酰基-C COR 9或酯gr 其中R 5，R 6，R 7，R 8和R 9分别代表上述R 1的基团，R 10是C 1 -C 10烷基或任意取代的芳基或芳烷基，或者R 3和R 4一起形成 C3-C5亚烷基或C3-C5亚烯基或C6-C14亚烷基，或C7-C14亚芳基或C8-C14芳亚烷基桥连元件，A相当于具有一个或多个负电荷用于电中和的阴离子 的三唑鎓阳离子的电荷。