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27 条记录 (耗时 0.022 秒)

    Removal of halides from halide-containing nitrile mixtures
    2.
    发明授权
    Removal of halides from halide-containing nitrile mixtures 失效
    从含卤素腈混合物中除去卤化物

    公开(公告)号：US6153784A

    公开(公告)日：2000-11-28

    申请号：US24457

    申请日：1998-02-17

    申请人： Heinz-Josef Kneuper ,  Hans-Jurgen Weyer ,  Horst Neuhauser ,  Johann-Peter Melder ,  Andreas Henne ,  Karl-Heinz Ross ,  Rainer Becker

    发明人： Heinz-Josef Kneuper ,  Hans-Jurgen Weyer ,  Horst Neuhauser ,  Johann-Peter Melder ,  Andreas Henne ,  Karl-Heinz Ross ,  Rainer Becker

    IPC分类号： B01J27/18 ,  B01J31/02 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C253/14 ,  C07C253/34 ,  C07C255/04

    CPC分类号： C07C253/14 ,  C07C209/48 ,  C07C253/34

    摘要： Halides are removed from halide-containing nitrile mixtures by(a) thermally treating the halide-containing nitrile mixture,(b) subsequently adding a base to the thermally treated nitrile mixture and(c) subsequently separating off the base from the nitrile mixture.Amines are prepared by(A) reacting alkyl halides with metal cyanides in an at least two-phase reaction medium in the presence of halide-containing phase-transfer catalysts to give alkanenitriles,(B) separating off the resulting halide-containing alkanenitrile mixture phase and(C) further treating the halide-containing alkanenitrile mixture phase, as described in the stages(a)-(c) removing halides from halide-containing nitrile mixtures and(d) hydrogenating nitrites obtained in stage (c) to give amines, in the presence of suspended or fixed-bed catalysts.

    摘要翻译： 通过（a）热处理含卤素腈混合物，（b）随后向经热处理的腈混合物中加入碱，和（c）随后将腈与腈混合物分离，从卤化物腈混合物中除去卤化物。 胺通过（A）在卤化物相转移催化剂存在下在至少两相反应介质中将烷基卤与金属氰化物反应得到烷腈，（B）将所得的含卤素的烷腈混合物相分离 （C）进一步处理含卤化物的腈腈混合物相，如步骤（a） - （c）所述从卤化物腈混合物中除去卤化物，和（d）氢化阶段（c）中得到的亚硝酸盐，得到胺， 在悬浮或固定床催化剂存在下。

    Preparation of amines
    7.
    发明授权
    Preparation of amines 失效
    胺的制备

    公开(公告)号：US5817871A

    公开(公告)日：1998-10-06

    申请号：US921769

    申请日：1997-08-15

    申请人： Uwe Dingerdissen ,  Gunter Lauth ,  Andreas Henne ,  Peter Stops ,  Karsten Eller ,  Eugen Gehrer

    发明人： Uwe Dingerdissen ,  Gunter Lauth ,  Andreas Henne ,  Peter Stops ,  Karsten Eller ,  Eugen Gehrer

    IPC分类号： B01J27/18 ,  B01J27/182 ,  B01J27/185 ,  B01J27/188 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/05 ,  C07C211/06 ,  C07C211/07 ,  C07C211/08 ,  C07C211/35

    CPC分类号： C07C211/35 ,  C07C209/60 ,  C07C211/07 ,  C07C2101/08

    摘要： A process for preparing an amine by catalytic reaction of an olefin with ammonia or a primary or secondary amine by contacting a mixture of the reactants in a reactor at 200.degree. to 400.degree. C. and an elevated pressure up to 700 bar in the presence of a catalyst consisting essentially of an X-ray amorphous (non-crystalline) mesoporous catalyst, some of which may have a microporous non-crystalline content. The catalyst has the composition a MO.sub.2 * b Q.sub.2 O.sub.3 * c P.sub.2 O.sub.5 where Q is at least one of the trivalent elements aluminum, boron, chromium, iron or gallium, and M is at least one of the tetravalent elements silicon, titanium or germanium. The molar ratio of a:b is from 0.5:1 to 1000:1 and the molar ratio of c:b is from 0 to 2:1. As prepared and used in the process, this non-crystalline catalyst has a specific BET surface area of from 200 to 1000 m.sup.2 /g.

    摘要翻译： 通过使烯烃与氨或伯胺或仲胺进行催化反应来制备胺的方法，该方法是将反应物的混合物在200-400℃的反应器和高达700巴的升高的压力下反应， 主要由X射线无定形（非结晶）介孔催化剂组成的催化剂，其中一些可能具有微孔非晶体含量。 催化剂具有以下组成：MO2 * b Q2O3 * c P2O5其中Q是三价元素铝，硼，铬，铁或镓中的至少一种，M是四价元素硅，钛或锗中的至少一种。 a:b的摩尔比为0.5:1-1000:1，c:b的摩尔比为0-2:1。 在该方法中制备和使用时，该非结晶催化剂的BET比表面积为200-1000m2 / g。

    Process for preparation of diamines by catalytic amination of aminoalcohols
    8.
    发明授权
    Process for preparation of diamines by catalytic amination of aminoalcohols 失效
    通过氨基醇的催化胺化制备二胺的方法

    公开(公告)号：US5608113A

    公开(公告)日：1997-03-04

    申请号：US513632

    申请日：1995-08-10

    申请人： Rainer Becker ,  Volkmar Menger ,  Wolfgang Reif ,  Andreas Henne

    发明人： Rainer Becker ,  Volkmar Menger ,  Wolfgang Reif ,  Andreas Henne

    IPC分类号： B01J23/88 ,  B01J21/06 ,  B01J23/755 ,  B01J37/03 ,  C07B61/00 ,  C07C209/16 ,  C07C211/09

    CPC分类号： C07C209/16 ,  B01J21/066 ,  B01J23/755 ,  B01J37/03 ,  Y02P20/582

    摘要： In a process for preparing diamines from aminoalcohols and nitrogen compounds selected from the group consisting of ammonia and primary and secondary amines at from 80.degree. to 250.degree. C. and pressures of from 1 to 400 bar using hydrogen in the presence of a zirconium, copper, nickel catalyst, the catalytically active composition comprises from 20 to 85% by weight of oxygen-containing zirconium compounds, calculated as ZrO.sub.2, from 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, from 30 to 70% by weight of oxygen-containing compounds of nickel, calculated as NiO, from 0.1 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO.sub.3, and from 0 to 10% by weight of oxygen-containing compounds of aluminum and/or manganese, calculated as Al.sub.2 O.sub.3 and MnO.sub.2 respectively.

    摘要翻译： 在使用氢存在下，在锆存在下，使用氢气从80℃至250℃，压力为1至400巴的氨基和伯胺和仲胺从氨基醇和氮化合物中制备二胺的方法中， 镍催化剂，催化活性组合物包含20至85重量％的以ZrO 2计算的含氧锆化合物，1至30重量％的以CuO计的含氧化合物铜30至70 按NiO计的含镍化合物的重量百分比为0.1至5重量％的按MoO 3计算的含氧化合物的钼和0至10重量％的含氧化合物的铝和 /或锰，分别计算为Al2O3和MnO2。