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1.发明授权Integrated two step process for conversion of methane to liquid hydrocarbons of gasoline range 失效将甲烷转化为汽油范围的液态烃的综合两步法
公开(公告)号：US5336825A
公开(公告)日：1994-08-09
申请号：US912969
申请日：1992-07-10
CPC分类号： C07C2/76 , C07C2/84 , C07C2521/10 , C07C2523/02 , C07C2523/10 , C07C2529/40 , C07C2529/44 , Y10S585/943
摘要： This invention discloses an improved integrated two step process for conversion of methane to liquid hydrocarbons of gasoline range. The invention particularly comprises catalytic oxidative conversion of methane with free oxygen to ethylene and higher olefins containing gaseous product in the first step and catalytic conversion of the olefins from the product stream of the first step without separating them to liquid hydrocarbons of gasoline range in the second step, for the conversion of methane to liquid hydrocarbons. The process of the present invention could be used in the petroleum industry for the production of gasoline and liquid hydrocarbon fuels and aromatic hydrocarbons.
摘要翻译： 本发明公开了一种用于将甲烷转化为汽油范围的液体烃的改进的一体化二步法。 本发明特别包括在第一步骤中甲烷与游离氧的催化氧化转化为乙烯和含较高级烯烃的气态产物，并且将烯烃从第一步骤的产物流中进行催化转化，而不将它们分离成第二个汽油范围的液体烃 一步，用于将甲烷转化为液态烃。 本发明的方法可用于石油工业中用于生产汽油和液态烃燃料和芳烃。
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2.发明授权Composite catalysts containing transitional and alkaline earth metal oxides useful for oxidative conversion of methane (or natural gas) to carbon monoxide and hydrogen (or synthesis gas) 失效含有用于甲烷（或天然气）氧化转化为一氧化碳和氢气（或合成气））的过渡碱土金属氧化物的复合催化剂，
公开(公告)号：US5756421A
公开(公告)日：1998-05-26
申请号：US531125
申请日：1995-09-20
申请人： Vasant R. Choudhary , Amarjeet M. Rajput , Subhash D. Sansare , Bathula Prabhakar , Ajit S. Mamman
发明人： Vasant R. Choudhary , Amarjeet M. Rajput , Subhash D. Sansare , Bathula Prabhakar , Ajit S. Mamman
CPC分类号： B01J23/78 , B01J37/088 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/0495 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1241 , C01B2203/1619 , Y02P20/52
摘要： The invention relates to a process for the preparation of novel composite catalysts useful for the oxidative conversion of methane to synthesis gas. The catalysts are represented by the formula: T.sub.m AO.sub.n, wherein T is a transition metal or metals, m is equal to the T/A mole ratio and is from 0.01 to 100, A is an alkaline earth metal or metals, O is oxygen and n is the number of oxygen atoms needed to form a catalyst composite wherein each element of the composite has a complete set of valence electrons. The process includes mixing compounds containing the transition metal or metals in finely ground form with the compounds containing the alkaline earth metals or metals in finely ground form in a T/A mole ratio of about 0.01 to about 100, heating the mixture to dryness at a temperature of about 80.degree. to 250.degree. C., decomposing the dried mixture at a temperature of about 400.degree. to 1200.degree. C., powdering the decomposed mixture and forming catalyst pellets thus formed at a temperature of about 400.degree. to 1500.degree. C.
摘要翻译： 本发明涉及制备用于将甲烷氧化转化为合成气的新型复合催化剂的方法。 催化剂由下式表示：TmAOn，其中T是过渡金属或金属，m等于T / A摩尔比，为0.01至100，A为碱土金属或金属，O为氧和n 是形成催化剂复合物所需的氧原子的数目，其中复合材料的每个元素具有完整的价电子组。 该方法包括以细磨的形式将含有过渡金属或金属的化合物与含有碱土金属或金属的化合物以约0.01至约100的T / A摩尔比混合，将混合物在 温度在约80℃至250℃，在约400℃至1200℃的温度下分解干燥的混合物，粉碎分解的混合物并在约400℃至1500℃的温度下形成催化剂颗粒。
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3.发明授权Process for the production of synthesis gas by oxidative converson of methane (or natural gas) using composite catalyst containing transitional and alkine earth metal oxides 失效使用含有过渡金属和碱土金属氧化物的复合催化剂通过甲烷（或天然气）的氧化反应生产合成气的方法
公开(公告)号：US5338488A
公开(公告)日：1994-08-16
申请号：US943181
申请日：1992-09-10
申请人： Vasant R. Choudhary , Amarjeet M. Rajput , Subhash D. Sansare , Bathula Prabhakar , Ajit S. Mamman
发明人： Vasant R. Choudhary , Amarjeet M. Rajput , Subhash D. Sansare , Bathula Prabhakar , Ajit S. Mamman
CPC分类号： C01B3/40 , B01J23/78 , C01B3/386 , C01B2203/0261 , C01B2203/1011 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1241 , Y02P20/52
摘要： The invention relates to a process for the production of synthesis gas by oxidative conversion of methane using composite catalysts having the formula: T.sub.m AO.sub.n, wherein T is a transition metal or metals, m is the T/A mole ratio and is from 0.01 to 100, A is an alkaline earth metal or metals, O is oxygen and n is the number of oxygen atoms needed to form a catalyst composite wherein each element of the composite has a complete set of valence electrons. In a preferred embodiment, the process includes passing a gas containing methane and oxygen over the composite catalyst in a fixed bed reactor at a pressure in the range of 0.5-50 atm, and at a temperature in the range of 200.degree.-1000.degree. C., and recovering the synthesis gas.
摘要翻译： 本发明涉及一种通过使用具有下式的复合催化剂氧化甲烷来生产合成气的方法：TmAOn，其中T是过渡金属或金属，m是T / A摩尔比，为0.01至100， A是碱土金属或金属，O是氧，n是形成催化剂复合物所需的氧原子数，其中复合材料的每个元素具有完整的价电子。 在优选的实施方案中，该方法包括在固定床反应器中在0.5-50atm范围内的压力和200-1000℃的温度范围内将含有甲烷和氧气的气体通过复合催化剂 并回收合成气。
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4.发明授权
公开(公告)号：US5306854A
公开(公告)日：1994-04-26
申请号：US911448
申请日：1992-07-10
CPC分类号： C10G50/00 , C07C2/00 , C07C2/82 , C07C2529/44 , Y10S585/943
摘要： The invention discloses a two step process for conversion of natural gas to liquid hydrocarbons of gasoline range comprising oxidation pyrolysis of natural gas olefins containing gaseous products in the first stage and conversion of the olefins, formed in the first step, without separating them from the gaseous product stream to liquid hydrocarbons of gasoline range in the second step. The process of the invention could be used in petrolium industries for producing gasoline liquid hydrocarbon fuels and aromatic hydrocarbons. The present invention is commercially viable and energy efficient.
摘要翻译： 本发明公开了一种用于将天然气转化为汽油范围的液体烃的两步法，其包括在第一阶段含有气态产物的天然气烯烃的氧化热解和在第一步中形成的烯烃的转化，而不将其与气态 产品流到汽油的液态碳氢化合物范围在第二步。 本发明的方法可用于石油工业生产汽油液烃燃料和芳烃。 本发明具有商业可行性和能量效率。
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