Herbicide compositions containing a nitrile derivative as antidote
    2.
    发明授权
    Herbicide compositions containing a nitrile derivative as antidote 失效
    含有腈衍生物作为解毒剂的除草剂组合物

    公开(公告)号:US4787933A

    公开(公告)日:1988-11-29

    申请号:US65265

    申请日:1987-06-22

    CPC分类号: A01N25/32

    摘要: The invention relates to a herbicide composition comprising as herbicidally active ingredient an urea derivative and/or a thiolcargamate derivative and/or a chloroacetanilide derivative together with a nitrile derivative of the general formula (I), ##STR1## wherein R.sub.1 and R.sub.2 which are the same or different, stand for hydroger, halogen or a methyl, ethyl, allyl, vinyl, phenyl or benzyl group; orR.sub.1 and R.sub.2 together may stand for a benzylidene group; andR.sub.3 means chlorine or a methyl, phenyl, chlorophenyl, alkoxyphenyl, chlorophenylamino, anilino, anilinomethylene, N-alkylanilinomethylene, N,N-dialkylanilinomethylene, alkoxyanilinomethylene, benzylaminomethylene, cyclohexylaminomethylene, N-alkyl-cyclohexylaminomethylene, hexamethyleniminomethylene, phthalimidomethylene, nitrophthalimidomethylene, morpholinomethylene, piperidinomethylene, C.sub.1-3 alkylaminomethylene, allylaminomethylene or di(C.sub.1-3 alkyl)aminorethylene groupand/or together with a cyanopyridine and/or with a benzonitrile derivative optionally mono- or polysubstituted by halogen(s) or C.sub.1-3 alkoxy group(s) as antidote(s) in a mass ratio from 40:1 to 1:1 of the herbicidally active ingredient to the antidote nitrile derivative.

    摘要翻译: 本发明涉及一种除草剂组合物,其包含作为除草活性成分的尿素衍生物和/或硫氰酸酯衍生物和/或氯代乙酰苯胺衍生物以及通式(I)的腈衍生物,其中R1和R2 氢原子,卤素或甲基,乙基,烯丙基,乙烯基,苯基或苄基;它们相同或不同。 或者R 1和R 2可以一起代表亚苄基; 并且R 3表示氯或甲基,苯基,氯苯基,烷氧基苯基,氯苯基氨基,苯胺基,苯胺基亚甲基,N-烷基苯胺基亚甲基,N,N-二烷基苯胺基亚甲基,烷氧基亚氨基亚甲基,苄基亚氨基亚甲基,环己基氨基亚甲基,N-烷基 - 环己基亚氨基亚甲基,六亚甲基亚氨基亚甲基,邻苯二甲酰亚胺亚甲基,硝基邻苯二甲酰亚甲基,吗啉代亚甲基, 哌啶亚甲基,C 1-3烷基氨基亚甲基,烯丙基氨基亚甲基或二(C 1-3烷基)氨基亚乙基和/或与氰基吡啶和/或与任选被卤素或C 1-3烷氧基单取代或多取代的苄腈衍生物一起作为 解毒剂与除草剂腈衍生物的除草活性成分的质量比为40:1-1:1。

    Phosphoric acid monester salts
    4.
    发明授权
    Phosphoric acid monester salts 失效
    磷酸monester盐

    公开(公告)号:US4675431A

    公开(公告)日:1987-06-23

    申请号:US888267

    申请日:1986-07-18

    摘要: The invention relates to new compounds of the general formula I ##STR1## wherein R.sub.1 is a straight or branched chained alkyl having 1 to 13 carbon atoms, optionally substituted with halogen, alkoxyalkyl containing 1 to 5 carbon atoms in the alkoxy and 1 to 4 carbon atoms in the alkyl moiety or phenyl;R.sub.2 is alkyl having 6 to 20 carbon atoms; alkoxyalkyl, phenoxyalkyl, furfuryl, cyclopropyl-alkyl, cyclopentyl, cycloheptyl, thiazolyl, triazolyl, thiazolinyl, pyridinyl, picolyl, benzimidazolyl, piperonyl, pirimidinyl, chlorobenzothiazolyl, benzyl, phenyl substituted with chloro and/or amino, or amino and alkyl, or amino and nitro groups, alkenyl, alkinyl, aminoalkyl, dialkylamino-alkyl, alkylaminoalkyl, alkylphosphonateammoniumalkyl, 3,5-dichlorophenyl-hidantoinyl, or thiadiazolyl optionally substituted with alkyl;R.sub.3 is hydrogen, phenyl, benzyl, alkenyl, alkyl, hydroxy, alkoxy or alkoxyalkyl; orR.sub.2 and R.sub.3 together stand for a 3,5-dichlorophenyl-hidantoinyl group;R.sub.4 is hydrogen or alkyl optionally substituted with hydroxyl.The new phosphoric acid monoester salts of the general formula I show fungicidal activity. The fungicidal compositions containing said compounds as active ingredients are also within the scope of the invention. According to a further aspect of the invention there is provided a process for the preparation of the new compounds.

    摘要翻译: 本发明涉及通式I(I)的新化合物,其中R 1是具有1至13个碳原子的直链或支链链烷基,任选被卤素取代,烷氧基中含有1至5个碳原子的烷氧基烷基和1 至烷基部分中的4个碳原子或苯基; R2是具有6至20个碳原子的烷基; 烷氧基烷基,苯氧基烷基,糠基,环丙基 - 烷基,环戊基,环庚基,噻唑基,三唑基,噻唑啉基,吡啶基,吡啶甲基,苯并咪唑基,胡椒基,吡啶基,氯代苯并噻唑基,苄基,被氯和/或氨基取代的苯基,或氨基和烷基或氨基 硝基,烯基,炔基,氨基烷基,二烷基氨基 - 烷基,烷基氨基烷基,烷基膦酸铵烷基,3,5-二氯苯基 - 乙二酰基或任选被烷基取代的噻二唑基; R3是氢,苯基,苄基,烯基,烷基,羟基,烷氧基或烷氧基烷基; 或R 2和R 3一起代表3,5-二氯苯基 - 乙酰乙酰基; R4是氢或任选被羟基取代的烷基。 通式I的新型磷酸单酯盐显示出杀真菌活性。 含有所述化合物作为活性成分的杀真菌组合物也在本发明的范围内。 根据本发明的另一方面,提供了一种制备新化合物的方法。