Process for controlling morphology of Ziegler-Natta catalysts
    4.
    发明授权
    Process for controlling morphology of Ziegler-Natta catalysts 失效
    控制齐格勒 - 纳塔催化剂形态的方法

    公开(公告)号:US08063159B2

    公开(公告)日:2011-11-22

    申请号:US11778262

    申请日:2007-07-16

    IPC分类号: C08F4/00

    摘要: Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties.

    摘要翻译: 公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。 其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀,其中催化剂组分的平均粒径增加,并且颗粒尺寸 分布增加,可溶性含镁催化剂前体的浓度降低; 或沉淀剂,其中催化剂组分的平均粒度增加,并且随着沉淀剂浓度的增加,粒度分布增加。 使用本发明能够改善催化剂的一致性,而不管生产规模如何,催化剂形态定制成所需的聚合物形态。 新颖的催化剂组分可用于制备聚合物及其最终用途制品,具有期望的性能。

    Cocatalysts useful for improving polyethylene film properties
    6.
    发明申请
    Cocatalysts useful for improving polyethylene film properties 审中-公开
    可用于改善聚乙烯薄膜性能的助催化剂

    公开(公告)号:US20070004875A1

    公开(公告)日:2007-01-04

    申请号:US11471997

    申请日:2006-06-21

    IPC分类号: C08F2/00

    摘要: Commonly used triethyl aluminum and tri-isobutyl aluminum cocatalysts can be replaced in olefin polymerizations with a cocatalyst conforming to the formula AlRz(Xz)nLzm wherein Rz is a linear or branched organic moiety having at least 5 carbons and Xz is a linear or branched organic moiety having at least 5 carbons or heteroatom substituted organic moiety or a heterocyclic moiety having at least 4 atoms and can be anionic (n=2) or dianionic (n=1). Xz can also be hydrogen. The aluminum complex may also be in the form of an adduct complex where Lz is a Lewis base and m=1-3. The general formula is subject to the proviso that when n=2, each Xz may be the same or different and that both Xz moieties may not be hydrogen. Use of the invention enables production of a polyolefin film, such as polyethylene film, exhibiting improved bubble stability and other desirable properties.

    摘要翻译: 通常使用的三乙基铝和三异丁基铝助催化剂可以在烯烃聚合反应中用符合下列公式的助催化剂来代替:式中:“In-line formula”end =“lead”?> AlR (X z) 其中R z是具有至少5个碳的直链或支链有机部分,X是直链或支链的有机部分 具有至少5个碳原子或杂原子取代的有机部分的部分或具有至少4个原子的杂环部分,并且可以是阴离子(n = 2)或二阴离子(n = 1)。 X“Z”也可以是氢。 铝络合物也可以是加合物络合物的形式,其中L z是路易斯碱,m = 1-3。 通式为条件,当n = 2时,每个X Z可以相同或不同,并且两个X z可以不是氢。 使用本发明可以生产聚烯烃薄膜,如聚乙烯薄膜,具有改进的气泡稳定性和其它所需的性能。

    Cocatalysts useful for preparing polyethylene pipe
    7.
    发明申请
    Cocatalysts useful for preparing polyethylene pipe 审中-公开
    可用于制备聚乙烯管的助催化剂

    公开(公告)号:US20070003720A1

    公开(公告)日:2007-01-04

    申请号:US11471996

    申请日:2006-06-21

    IPC分类号: B32B27/08

    摘要: Commonly used triethyl aluminum and tri-isobutyl aluminum cocatalysts may be replaced in olefin polymerizations with a cocatalyst conforming to the formula AlRz(Xz)nLzm wherein Rz is a linear or branched organic moiety having at least 5 carbons and Xz is a linear or branched organic moiety having at least 5 carbons or heteroatom substituted organic moiety or a heterocyclic moiety having at least 4 atoms and may be anionic (n=2) or dianionic (n=1). Xz may also be hydrogen. The general formula is subject to the proviso that when n=2, each Xz may be the same or different and that both Xz moieties may not be hydrogen. The aluminum complex may also be in the form of an adduct complex where Lz is a Lewis base and m=1-3. Use of the invention enables production of a polyolefin pipe, such as polyethylene pipe, exhibiting improved processing, crack resistance and other desirable properties.

    摘要翻译: 通常使用的三乙基铝和三异丁基铝助催化剂可以用烯烃聚合反应替代,其中助催化剂符合式<?in-line-formula description =“In-line Formulas”end =“lead”?> AlR (X z) 其中R z是具有至少5个碳的直链或支链有机部分,X是直链或支链的有机部分 具有至少5个碳原子或杂原子取代的有机部分的部分或具有至少4个原子的杂环部分,并且可以是阴离子(n = 2)或二阴离子(n = 1)。 X 也可以是氢。 通式为条件,当n = 2时,每个X Z可以相同或不同,并且两个X z可以不是氢。 铝络合物也可以是加合物络合物的形式,其中L z是路易斯碱,m = 1-3。 使用本发明可以生产出聚烯烃管,如聚乙烯管,具有改善的加工性,抗裂性和其它所需的性能。

    Process for Controlling Morphology of Ziegler-Natta Catalysts
    8.
    发明申请
    Process for Controlling Morphology of Ziegler-Natta Catalysts 审中-公开
    控制齐格勒 - 纳塔催化剂形态的方法

    公开(公告)号:US20120064268A1

    公开(公告)日:2012-03-15

    申请号:US13272279

    申请日:2011-10-13

    摘要: Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. The process enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

    摘要翻译: 公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。 该方法能够改善催化剂的一致性,而不管生产规模如何,催化剂形态定制成所需的聚合物形态。 新颖的催化剂组分可用于制备聚合物及其最终用途制品,具有期望的性能。 要强调的是,该摘要被提供以符合要求摘要的规则,这将允许搜索者或其他读者快速确定技术公开的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围或含义。

    Process for Controlling Morphology of Ziegler-Natta Catalysts
    10.
    发明申请
    Process for Controlling Morphology of Ziegler-Natta Catalysts 失效
    控制齐格勒 - 纳塔催化剂形态的方法

    公开(公告)号:US20090023875A1

    公开(公告)日:2009-01-22

    申请号:US11778262

    申请日:2007-07-16

    IPC分类号: B01J37/03 C08F4/12

    摘要: Disclosed is a process for making a Ziegler-Natta catalyst having controlled particle size and distribution. It comprises altering the precipitation of a catalyst component from a catalyst synthesis solution including a soluble magnesium containing catalyst precursor by controlling the concentration of either the soluble magnesium containing catalyst precursor, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased, with a decreased concentration of the soluble magnesium containing catalyst precursor; or of the precipitating agent, wherein the average particle size of the catalyst component is increased, and the particle size distribution increased with an increased concentration of the precipitating agent. Use of the invention enables improved catalyst consistency regardless of production scale and customizing of catalyst morphology to desired polymer morphology. The novel catalyst components may be used to prepare polymers, and end-use articles therefrom, having desirable properties. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

    摘要翻译: 公开了一种制备具有受控粒度和分布的齐格勒 - 纳塔催化剂的方法。 其包括通过控制可溶性含镁催化剂前体的浓度来改变催化剂组分从包括可溶性镁的催化剂前体的催化剂合成溶液中的沉淀,其中催化剂组分的平均粒径增加,并且颗粒尺寸 分布增加,可溶性含镁催化剂前体的浓度降低; 或沉淀剂,其中催化剂组分的平均粒度增加,并且随着沉淀剂浓度的增加,粒度分布增加。 使用本发明能够改善催化剂的一致性,而不管生产规模如何,催化剂形态定制成所需的聚合物形态。 新颖的催化剂组分可用于制备聚合物及其最终用途制品,具有期望的性能。 要强调的是,该摘要被提供以符合要求摘要的规则,这将允许搜索者或其他读者快速确定技术公开的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围或含义。