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    PRODUCTION OF LUBRICANT BASE OILS FROM BIOMASS
    2.
    发明申请
    PRODUCTION OF LUBRICANT BASE OILS FROM BIOMASS 有权
    从生物量生产润滑油基础油

    公开(公告)号：US20140142356A1

    公开(公告)日：2014-05-22

    申请号：US14054288

    申请日：2013-10-15

    申请人： Virginia M. Roberts ,  Michel Daage ,  Kun Wang

    发明人： Virginia M. Roberts ,  Michel Daage ,  Kun Wang

    IPC分类号： C10G3/00

    CPC分类号： C10G3/50 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J29/703 ,  B01J29/7046 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7661 ,  B01J29/7692 ,  C10G3/44 ,  C10G3/45 ,  C10G45/02 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10 ,  C10G45/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P30/20

    摘要： Systems and methods are provided for processing a feed derived from a biomass source that contains nitrogen in the form of fatty amides, e.g., derived from hydrothermal processing of a biomass source feed, while reducing/minimizing the amount of heteroatom removal performed during subsequent/concurrent hydroprocessing. Optionally, the feed can also contain free fatty acids. This is accomplished in part by first exposing the feed to a catalyst comprising a rare earth oxide, alkali oxide, and/or alkaline earth oxide, which can remove the nitrogen heteroatoms from the compounds within the feed or can convert the nitrogen to a form readily removed in subsequent hydroprocessing. The catalyst may also suitable for catalyzing coupling (such as condensation) or conversion reactions of amides, carboxylic acids, carboxylic acid derivatives, and/or other molecules in the feed suitable for participating in the coupling reaction.

    摘要翻译： 提供了用于处理源自生物质源的饲料的系统和方法，所述饲料含有脂肪酰胺形式的氮，例如衍生自生物质源饲料的水热处理，同时减少/最小化在随后/同时进行的杂原子除去量 加氢处理。 任选地，饲料还可以含有游离脂肪酸。 这部分是通过首先将进料暴露于包含稀土氧化物，碱金属氧化物和/或碱土金属氧化物的催化剂来完成的，所述催化剂可以从进料内的化合物中除去氮杂原子，或者可以容易地将氮转化为形式 在随后的加氢处理中被去除。 该催化剂也可适用于催化偶联（如缩合）或酰胺，羧酸，羧酸衍生物和/或其他分子的转化反应，适于参与偶联反应。

    Production of lubricant base oils from biomass
    3.
    发明授权
    Production of lubricant base oils from biomass 有权
    从生物质生产润滑油基础油

    公开(公告)号：US09221725B2

    公开(公告)日：2015-12-29

    申请号：US13917743

    申请日：2013-06-14

    申请人： Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

    发明人： Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

    IPC分类号： C07C1/00 ,  C07C1/207 ,  C10G29/22 ,  C10G3/00 ,  C11C3/00 ,  B01J21/12 ,  B01J23/02 ,  B01J23/10

    CPC分类号： C07C1/2076 ,  B01J21/12 ,  B01J23/02 ,  B01J23/10 ,  C10G3/44 ,  C10G3/50 ,  C10G29/22 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/10 ,  C11C3/00 ,  Y02E50/13 ,  Y02P30/20

    摘要： Methods are provided for processing glycerides to form lubricant boiling range molecules in a single reactor and/or a single reaction zone. The glycerides are exposed to catalysts that are stable under the conditions present in the reaction zones during conversion of glycerides to fatty ketones via a coupling reaction in the presence of a first catalyst, and the subsequent deoxygenation and isomerization of the ketones in the presence of a second dewaxing catalyst. The glyceride-containing feedstock can further include free fatty acids or fatty acid derivatives that can also be used for formation of ketones and subsequent deoxygenation and isomerization. In some configuration, the processing can occur in a single reaction zone containing mixed beds of the first and second catalyst. Such configurations can be used to control the ratio of diesel boiling range molecules versus lubricant boiling range molecules generated by the methods.

    摘要翻译： 提供了用于处理甘油酯以在单个反应器和/或单个反应区中形成润滑剂沸程分子的方法。 将甘油酯暴露于在第一催化剂存在下通过偶联反应将甘油酯转化成脂肪酮的反应区中存在的条件下稳定的催化剂，以及随后在存在下的酮的脱氧和异构化 第二脱蜡催化剂。 含甘油酯的原料还可以包括游离脂肪酸或脂肪酸衍生物，其还可用于形成酮和随后的脱氧和异构化。 在一些配置中，处理可以发生在包含第一和第二催化剂的混合床的单个反应区中。 这种配置可用于控制柴油沸程分子与通过该方法产生的润滑剂沸程分子的比例。

    PRODUCTION OF LUBRICANT BASE OILS FROM BIOMASS
    4.
    发明申请
    PRODUCTION OF LUBRICANT BASE OILS FROM BIOMASS 有权
    从生物量生产润滑油基础油

    公开(公告)号：US20140024869A1

    公开(公告)日：2014-01-23

    申请号：US13917743

    申请日：2013-06-14

    申请人： Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

    发明人： Virginia M. Roberts ,  Michel Daage ,  Paul D. Oldenburg ,  Suzzy C. Ho ,  Kun Wang ,  Bradley R. Fingland

    IPC分类号： C07C1/207

    CPC分类号： C07C1/2076 ,  B01J21/12 ,  B01J23/02 ,  B01J23/10 ,  C10G3/44 ,  C10G3/50 ,  C10G29/22 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/10 ,  C11C3/00 ,  Y02E50/13 ,  Y02P30/20

    摘要： Methods are provided for processing glycerides to form lubricant boiling range molecules in a single reactor and/or a single reaction zone. The glycerides are exposed to catalysts that are stable under the conditions present in the reaction zones during conversion of glycerides to fatty ketones via a coupling reaction in the presence of a first catalyst, and the subsequent deoxygenation and isomerization of the ketones in the presence of a second dewaxing catalyst. The glyceride-containing feedstock can further include free fatty acids or fatty acid derivatives that can also be used for formation of ketones and subsequent deoxygenation and isomerization. In some configuration, the processing can occur in a single reaction zone containing mixed beds of the first and second catalyst. Such configurations can be used to control the ratio of diesel boiling range molecules versus lubricant boiling range molecules generated by the methods.

    摘要翻译： 提供了用于处理甘油酯以在单个反应器和/或单个反应区中形成润滑剂沸程分子的方法。 将甘油酯暴露于在第一催化剂存在下通过偶联反应将甘油酯转化成脂肪酮的反应区中存在的条件下稳定的催化剂，以及随后在存在下的酮的脱氧和异构化 第二脱蜡催化剂。 含甘油酯的原料还可以包括游离脂肪酸或脂肪酸衍生物，其还可用于形成酮和随后的脱氧和异构化。 在一些配置中，处理可以发生在包含第一和第二催化剂的混合床的单个反应区中。 这种配置可用于控制柴油沸程分子与通过该方法产生的润滑剂沸程分子的比例。