Making of micro-miniature electronic components by selective oxidation
    1.
    发明授权
    Making of micro-miniature electronic components by selective oxidation 失效
    通过选择性氧化制造微型电子元件

    公开(公告)号:US3867148A

    公开(公告)日:1975-02-18

    申请号:US43165674

    申请日:1974-01-08

    CPC classification number: H01L21/31683 H01L21/00 Y10S430/143

    Abstract: A micro-miniature electronic component and particularly an electromask of high resolution is made by first applying a metal layer, of a composition, such as titanium, capable of being etched by an etchant at a relatively high rate and capable of becoming relatively etchant resistant on oxidation, over a major surface of a substrate. A desired component pattern is then defined, preferably by selective exposure with an electron beam, in a resist layer directly overlaid on the metal layer by difference in solubility between exposed and unexposed portions of the resist. The desired component pattern is then transferred to the metal layer by (i) removing less soluble portions of the resist layer to expose first portions of the metal layer, (ii) applying over said exposed first portions and the remaining portions of resist layer an oxidation masking layer of a composition such as aluminum, being relatively oxidation resistant compared to the metal layer and being relatively etchable compared to the metal layer when oxidized, (iii) removing the remaining portions of the resist layer and overlying oxidation masking layer to expose second portions of the metal layer, (iv) selectively oxidizing the second portions of the metal layer to become relatively etchant resistant while said first portions of the metal layer are masked against oxidation by the masking layer, and (v) removing the remaining portions of the oxidation masking layer and underlying unoxidized first portions of the metal layer by etching.

    Abstract translation: 微型电子部件,特别是高分辨率的电子掩模是通过首先施加金属层,诸如钛的组合物,能够以较高的速率被蚀刻剂蚀刻并能够变得相对耐蚀性 氧化,在基底的主表面上。 然后,优选通过电子束的选择性曝光来限定通过抗蚀剂的曝光部分和未曝光部分之间的溶解度的差异直接覆盖在金属层上的抗蚀剂层。 然后,通过(i)除去抗蚀剂层的较少可溶部分以暴露金属层的第一部分,将所需的组分图案转移到金属层,(ii)在所述暴露的第一部分和抗蚀剂层的剩余部分上施加氧化 诸如铝的组合物的掩模层与金属层相比相对抗氧化,并且当被氧化时与金属层相比是相对可蚀刻的,(iii)去除抗蚀剂层的剩余部分并覆盖氧化掩模层以暴露第二部分 (iv)选择性地氧化金属层的第二部分以变得相对耐蚀性,同时金属层的第一部分被掩蔽层掩蔽以防止被掩蔽层氧化,和(v)去除剩余的氧化部分 掩模层和金属层的下层的未氧化的第一部分。

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