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公开(公告)号：US07696285B2
公开(公告)日：2010-04-13
申请号：US10866595
申请日：2004-06-11
CPC分类号： C09D201/025 , C08F8/00 , C08F2800/20 , C09D201/02 , C08F220/20
摘要： Disclosed is a carbamate functional reactive polymer composition, comprising an acrylic resin (a′) comprising a functional group (F3) that is at least one of a primary carbamate group, a primary hydroxyl group, a secondary hydroxyl group, and mixtures thereof, and a nonvolatile solvent (b′nv) that is not a crystalline solid at 75° C. but is a fluid solid at a temperature of free radical polymerization and comprises (i) four or more isomers, and (ii) at least two reactive functional groups (F2) that are selected from primary carbamate, primary hydroxyl, and secondary hydroxyl, wherein no more than 10% of the sum of functional groups (F2) and (F3) are primary hydroxyl groups and at least 60% of the sum of functional groups (F2) and (F3) are primary carbamate groups. In one exemplary embodiment, the reactive polymer composition is made by a disclosed method.
摘要翻译： 公开了一种氨基甲酸酯官能反应性聚合物组合物，其包含丙烯酸树脂（a'），其包含主要氨基甲酸酯基，伯羟基，仲羟基及其混合物中的至少一种的官能团（F3），以及 在75℃下不是结晶固体的非挥发性溶剂（b'nv），但是在自由基聚合温度下是流体固体，并且包含（i）四种或更多种异构体，和（ii）至少两种反应性官能团 选自伯氨基甲酸酯，伯羟基和仲羟基的基团（F2），其中不超过10％的官能团（F2）和（F3）的和为伯羟基，并且至少60％ 官能团（F2）和（F3）是伯氨基甲酸酯基团。 在一个示例性实施方案中，通过公开的方法制备反应性聚合物组合物。
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公开(公告)号：US07321013B2
公开(公告)日：2008-01-22
申请号：US10866596
申请日：2004-06-11
CPC分类号： C09D201/02 , C08F8/00 , C08F2800/20 , C08G18/4072 , C08G18/4233 , C08G18/6229 , C08G18/6254 , C08G18/672 , C08G18/8175 , C08G2190/00 , C09D5/02 , C09D133/14 , C09D167/00 , C09D175/04 , C09D201/00 , C09D201/025 , C08F220/20
摘要： Disclosed is a method of making reduced VOC polymers and coating compositions containing such polymers. Provided is a mixture (I) comprising a reactant mixture (a) of polymerizable components and a nonvolatile solvent (bnv) that (i) is not a crystalline solid at 25° C., (ii) is nonvolatile, (iii) comprises at least one functional group (F1) and (iv) is a fluid solid. Reactant mixture (a) is polymerized to provide a polymer (a′). The at least one functional group (F1) of nonvolatile solvent (bnv) is reacted with one or more reactants (e) to obtain a nonvolatile solvent (b′nv) comprising at least two functional groups (F2). Obtained is a mixture (II) comprising polymer (a′) in nonvolatile solvent (b′nv) comprising at least two functional groups (F2). The at least one functional group (F1) is substantially nonreactive: (1) with the components of reactive mixture (a), (2) under the polymerization conditions which polymerize reactant mixture (a), and (3) with polymer (a′).
摘要翻译： 公开了一种制备含有这种聚合物的VOC聚合物和涂料组合物的方法。 提供了包含可聚合组分的反应物混合物（a）和不挥发性溶剂（b）的混合物（I），（i）在25℃下不是结晶固体，（ii） 是非挥发性的，（iii）包含至少一个官能团（F 1 H 1）和（iv）是流体固体。 将反应物混合物（a）聚合以提供聚合物（a'）。 非挥发性溶剂（b）的至少一个官能团（F 1 N 1）与一种或多种反应物（e）反应，得到非挥发性溶剂（b' 包括至少两个官能团（F 2 N 2）。 获得的包含聚合物（a'）在包含至少两个官能团（F 2 N 2）的非挥发性溶剂（b'Nv））中的混合物（II）。 至少一个官能团（F 1 H 1）基本上是非反应性的：（1）在聚合反应混合物（a）的聚合条件下与反应混合物（a），（2）的组分反应，和 （3）与聚合物（a'）。
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公开(公告)号：US07368501B2
公开(公告)日：2008-05-06
申请号：US10866607
申请日：2004-06-11
CPC分类号： C08F4/28 , C08F2/06 , C08F2/52 , C08F2/56 , C08F4/04 , C09D175/04 , C09D201/02 , C09D201/025 , C08L2666/16
摘要： Disclosed is a method of making an environmentally durable material, the method requiring providing a material comprising at least one functional group Fc, and subjecting the material to a free radical source such that substantially all functional groups Fc are eliminated but the material is not polymerized. In one embodiment, the functional group Fc is at least one of a nonaromatic carbon-carbon double bond, a hydrogen atom alpha to an aromatic ring, a hydrogen atom alpha to a carbon-carbon double bond, or a hydrogen atom attached to a tertiary substituted carbon. In another embodiment, functional group Fc is present in the material as a contaminant. In one exemplary embodiment, the material comprises from 0.05 to less than 15% by weight of functional group Fc, based on the total weight of the material.
摘要翻译： 公开了一种制备环境耐久材料的方法，该方法需要提供包含至少一个官能团F 1的材料，并使材料经受自由基源，使得基本上所有官能团F < SUB> c 被消除，但材料未聚合。 在一个实施方案中，官能团F C是至少一种非芳族碳 - 碳双键，芳环的α，氢原子，碳 - 碳双键的氢原子， 或与叔取代的碳连接的氢原子。 在另一个实施方案中，作为污染物的材料中存在官能团F C c。 在一个示例性实施方案中，基于材料的总重量，该材料包含0.05至小于15重量％的官能团F C c C。
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公开(公告)号：US07691951B2
公开(公告)日：2010-04-06
申请号：US11868104
申请日：2007-10-05
CPC分类号： C09D201/02 , C08F8/00 , C08F2800/20 , C08G18/4072 , C08G18/4233 , C08G18/6229 , C08G18/6254 , C08G18/672 , C08G18/8175 , C08G2190/00 , C09D5/02 , C09D133/14 , C09D167/00 , C09D175/04 , C09D201/00 , C09D201/025 , C08F220/20
摘要： Disclosed is a method of making reduced VOC polymers and coating compositions containing such polymers. Provided is a mixture (I) comprising a reactant mixture (a) of polymerizable components and a nonvolatile solvent (bnv) that (i) is not a crystalline solid at 25° C., (ii) is nonvolatile, (iii) comprises at least one functional group (F1) and (iv) is a fluid solid. Reactant mixture (a) is polymerized to provide a polymer (a′). The at least one functional group (F1) of nonvolatile solvent (bnv) is reacted with one or more reactants (e) to obtain a nonvolatile solvent (b′nv) comprising at least two functional groups (F2). Obtained is a mixture (II) comprising polymer (a′) in nonvolatile solvent (b′nv) comprising at least two functional groups (F2). The at least one functional group (F1) is substantially nonreactive: (1) with the components of reactive mixture (a), (2) under the polymerization conditions which polymerize reactant mixture (a), and (3) with polymer (a′).
摘要翻译： 公开了一种制备含有这种聚合物的VOC聚合物和涂料组合物的方法。 提供了包含可聚合组分的反应物混合物（a）和不挥发性溶剂（bnv）的混合物（I），其中（i）在25℃下不是结晶固体，（ii）是非挥发性的，（iii）包含 至少一个官能团（F1）和（iv）是流体固体。 将反应物混合物（a）聚合以提供聚合物（a'）。 将不挥发性溶剂（bnv）的至少一种官能团（F1）与一种或多种反应物（e）反应，得到包含至少两个官能团（F2）的非挥发性溶剂（b'nv）。 获得的是包含至少两个官能团（F2）的非挥发性溶剂（b'nv）中的聚合物（a'）的混合物（II）。 至少一个官能团（F1）基本上是非反应性的：（1）在反应混合物（a）和（3）与聚合物（a'）聚合的聚合条件下，反应混合物（a），（2） ）。
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公开(公告)号：US07030263B2
公开(公告)日：2006-04-18
申请号：US10280619
申请日：2002-10-25
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G63/64
CPC分类号： C09D175/02 , C07C269/04 , C07C269/06 , C07C273/1809 , C07C273/1854 , C08G18/4615 , C09D175/06 , Y10T428/31551 , C08L2666/16
摘要： A method of preparing a carbamate or urea-functional compound is described comprising the step of reacting a lactone or hydroxy carboxylic acid with a compound (A) comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group capable of reacting with the hydroxy carboxylic acid or in a ring-opening reaction with a lactone. The compound thus prepared is useful in curable compositions.
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公开(公告)号：US5760127A
公开(公告)日：1998-06-02
申请号：US698526
申请日：1996-08-15
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G71/00 , C09D167/04 , C09D201/02 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C09D201/02 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.
摘要翻译： 描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物， 和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或 羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物 或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。
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公开(公告)号：US5744550A
公开(公告)日：1998-04-28
申请号：US333917
申请日：1994-11-03
IPC分类号： C09D133/06 , C08G18/80 , C09D133/04 , C09D161/20 , C09D161/28 , C09D201/02 , C08L29/02
CPC分类号： C09D201/025 , C08G18/8077
摘要： Curable coating compositions are described comprising (a) a polymer resin comprising active hydrogen-containing functional groups other than carbamate, (b) a curing agent having groups that are reactive with said functional groups on (a), and (c) a compound having a molecular weight of from 75 to 2000 comprising at least one group of the formula: ##STR1## wherein X is O or NH and either (a), (b), or both (a) and (b) comprise groups that are reactive with said group on (c).
摘要翻译： 描述了可固化涂料组合物，其包含（a）包含除氨基甲酸酯以外的含活性氢的官能团的聚合物树脂，（b）具有与（a）上的所述官能团反应的基团的固化剂，和（c）具有 包含至少一个下列基团的分子量为75至2000的式（b））或（a）和（b）都包含与（c）上的所述基团反应的基团。
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公开(公告)号：US5576063A
公开(公告)日：1996-11-19
申请号：US426340
申请日：1995-04-21
IPC分类号： C08G18/62 , C09D175/04 , C09D201/06 , B05D1/38
CPC分类号： C09D175/04 , C08G18/6229 , C08G18/6237 , C08G18/6283 , C09D201/06
摘要： A method of preparing a multilayer coating is described. The method comprises the steps of:(1) applying onto a substrate a first curable coating composition comprising two components that are reactive with one another to form urethane linkages and a third component that includes one or more epoxy groups,(2) curing the first curable coating composition to form a cured coating,(3) applying a second curable coating composition onto the surface of the coating from step (2), and(4) curing the second curable coating composition.
摘要翻译： 描述了制备多层涂层的方法。 该方法包括以下步骤：（1）将包含彼此反应形成氨基甲酸酯键的两个组分的第一可固化涂料组合物和包含一个或多个环氧基团的第三组分施加到基材上，（2）固化第一 固化涂料组合物以形成固化涂层，（3）将第二可固化涂料组合物施加到来自步骤（2）的涂层表面上，和（4）固化第二可固化涂料组合物。
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9.发明申请公开(公告)号：US20120100378A1
公开(公告)日：2012-04-26
申请号：US13380304
申请日：2010-06-24
申请人： Walter H. Ohrbom , Gregory G. Menovcik , Patrick J. Mormile , Donald H. Campbell , David Cranfill
发明人： Walter H. Ohrbom , Gregory G. Menovcik , Patrick J. Mormile , Donald H. Campbell , David Cranfill
CPC分类号： B05D1/36 , B05D7/52 , C09D4/00 , Y10T428/31507 , Y10T428/31515 , Y10T428/31536
摘要： A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.
摘要翻译： 涂料系统包括基材和设置在基材上的第一涂料层。 第一涂料层由包含第一解络剂或第一有机硼烷络合物的第一组合物形成。 涂料系统还包括设置在第一涂料层上的第二涂料层。 第二涂层由第二组合物形成，第二组合物包含第一解络剂和第一有机硼烷络合物中的另一种。 第一和第二组合物中的至少一种还包含自由基聚合性化合物。 制造多层涂料涂料的方法包括以下步骤：提供基材，在基材上施加第一涂料层，在第一涂料层上施加第二涂料层，并固化第一和第二涂料层中的至少一个。
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公开(公告)号：US20100183882A1
公开(公告)日：2010-07-22
申请号：US12516836
申请日：2008-02-13
申请人： Donald H. Campbell , Gregory G. Menovcik , David J. Santure , Walter H. Ohrbom , Donald St. Aubin , Paul J. Harris
发明人： Donald H. Campbell , Gregory G. Menovcik , David J. Santure , Walter H. Ohrbom , Donald St. Aubin , Paul J. Harris
CPC分类号： B05D7/576 , B05D2202/15 , C09D201/025 , Y10T428/31551 , C08L2666/16
摘要： A coating system includes a clear coat layer and a sealant. The clear coat layer is formed from a clear coat composition that comprises a crosslinkable carbamate-functional resin and an aminoplast. Optionally, the coating system further includes a sub-clear coat layer that is formed from a sub-clear coat composition. The sealant is bonded to the clear coat layer opposite the sub-clear coat layer. Optionally, the coating system further includes a tie coat layer that is formed from a tie coat composition and that is disposed between the sealant and the clear coat layer. An adhesion promoter is present in the clear coat composition in an amount of less than or equal to about 3% by weight based on the total weight of resin solids of the clear coat composition. Further, the adhesion promoter is present in at least one of the sub-clear coat composition and the tie coat composition in an amount sufficient to increase adhesion between the clear coat layer and the sealant.
摘要翻译： 涂层系统包括透明涂层和密封剂。 透明涂层由透明涂层组合物形成，该组合物包含可交联的氨基甲酸酯官能树脂和氨基塑料。 任选地，涂层系统还包括由亚透明涂层组合物形成的副透明涂层。 密封剂粘合到与透明涂层相对的透明涂层上。 任选地，涂层系统还包括由粘结涂层组合物形成并且设置在密封剂和透明涂层之间的粘结涂层。 基于透明涂料组合物的树脂固体的总重量，粘合促进剂以小于或等于约3重量％的量存在于透明涂料组合物中。 此外，粘合促进剂以足以增加透明涂层和密封剂之间的粘合力的量存在于至少一种亚透明涂料组合物和粘合涂层组合物中。
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