Adhesive compositions containing aqueous copolymer dispersions and acid
metal salts or free acids
    1.
    发明授权
    Adhesive compositions containing aqueous copolymer dispersions and acid metal salts or free acids 失效
    含有共聚物水分散体和酸金属盐或游离酸的粘合剂组合物

    公开(公告)号:US5296532A

    公开(公告)日:1994-03-22

    申请号:US837553

    申请日:1992-02-14

    CPC classification number: C09J151/003 C08F261/04

    Abstract: The invention relates to adhesive compositions for gluing wood containing aqueous vinyl ester graft copolymer dispersions and water-soluble acid metal salts or free acids, in which the adhesive compositions exhibit outstanding resistance to hot water and have high storage stability. The vinyl ester graft copolymer comprises from 2 to 12 percent by weight, based on the total weight of the graft copolymer, of one or more polyvinyl alcohols having a degree of hydrolysis of from 60 to 99 mol persent and 88 to 98 percent by weight, based on the total weight of the graft copolymer, of a grafting monomer mixture. The grafting monomer mixture contains from 5 to 50 percent by weight, based on the total weight of the monomer mixture, of vinyl esters of saturated, highly branched aliphatic monocarboxylic acids having 9 or 10 carbon atoms, vinyl pivalate, diisopropyl maleate, diisopropyl fumarate, vinyl chloride and mixtures thereof.

    Abstract translation: 本发明涉及用于胶合木材的粘合剂组合物,其含有乙烯基酯水溶液接枝共聚物分散体和水溶性酸性金属盐或游离酸,其中粘合剂组合物显示出优异的耐热水性并且具有高储存稳定性。 乙烯基酯接枝共聚物包含2至12重量%的基于接枝共聚物的总重量的一种或多种水解度为60至99摩尔%的聚乙烯醇和88至98重量% 基于接枝共聚物的总重量,接枝单体混合物。 接枝单体混合物含有5至50重量%,基于单体混合物的总重量,具有9或10个碳原子的饱和,高度支化的脂族一元羧酸的乙烯基酯,新戊酸乙烯酯,马来酸二异丙酯,富马酸二异丙酯, 氯乙烯及其混合物。

    Adhesive aqueous dispersions of polyvinyl alcohol graft polymers with
acidic hardeners and process of production
    2.
    发明授权
    Adhesive aqueous dispersions of polyvinyl alcohol graft polymers with acidic hardeners and process of production 失效
    具有酸性硬化剂的聚乙烯醇接枝聚合物的粘合剂水性分散体和生产方法

    公开(公告)号:US4118357A

    公开(公告)日:1978-10-03

    申请号:US792682

    申请日:1977-05-02

    CPC classification number: C09J151/003 C08F261/04

    Abstract: An aqueous copolymer adhesive dispersion having a long pot life and giving highly waterproof bonds, comprising an acid hardener of water-soluble acids having pKs of under 0 and an aqueous dispersion of a pre-crosslinked polyvinyl ester grafted onto polyvinyl alcohol, said polyvinyl ester being an ester of an acid of 1 to 12 carbon atoms and said pre-crosslinking caused by the presence of small amounts of poly-ethylenically-unsaturated compounds in the monomer mixture, as well as the aqueous dispersion and the method for its production.

    Abstract translation: 一种水性共聚物粘合剂分散体,其具有长的适用期并提供高度防水的粘合剂,其包含pKs低于0的水溶性酸的酸性固化剂和接枝到聚乙烯醇上的预交联聚乙烯酯的水分散体,所述聚乙烯酯是 1至12个碳原子的酸的酯和由单体混合物中少量聚烯键式不饱和化合物的存在引起的所述预交联,以及水分散体及其制备方法。

    Hydrostatically deforming a hollow body
    3.
    发明授权
    Hydrostatically deforming a hollow body 失效
    使空心体静电变形

    公开(公告)号:US5279142A

    公开(公告)日:1994-01-18

    申请号:US927397

    申请日:1992-09-23

    Applicant: Wilhelm Kaiser

    Inventor: Wilhelm Kaiser

    CPC classification number: B21D26/045

    Abstract: An apparatus for pressure deforming a hollow workpiece having a tubular end portion has a die formed with a cavity adapted to receive the workpiece with the end portion of the workpiece projecting out of the die and a fitting movable along an axis toward and away from the die and formed with a seat sealingly engageable in a feed position over the projecting end portion of the workpiece. An annular self-tightening gland in the seat circumferentially engages in the feed position around the projecting end portion of the workpiece. A passage opening in the seat into the hollow workpiece when the fitting is engaged over the projecting end portion serves for pressurizing an interior of the workpiece and thereby deforming it outward against an inner surface of the die and for pressing the gland radially tightly against the workpiece and against the fitting.

    Abstract translation: 用于在模具(12)的成形凹部(17)内的可冷加工金属的空心体(19)的静水压成型装置装配有用于将加压流体供应到中空体(19)中的系统。 供应系统包括供应套筒联接器(23),其输送加压流体,所述加压流体可相对于容纳在模具(12)中的中空体(19)移动和移出并锁定在供应位置。 供应套筒联接件(23)可以推动在位于模具(12)的成形凹部(17)外侧的中空本体(19)的圆柱形夹持区域(22)的前部。 在供应位置,供应套筒联接器(23)在供给位置接受夹紧区域(22),以便可轴向移动并通过套筒密封件(36)夹紧,该密封件由流体压力自动密封。

    Hydrostatically deforming a hollow body
    6.
    发明授权
    Hydrostatically deforming a hollow body 失效
    使空心体静电变形

    公开(公告)号:US5303570A

    公开(公告)日:1994-04-19

    申请号:US927398

    申请日:1992-09-23

    Applicant: Wilhelm Kaiser

    Inventor: Wilhelm Kaiser

    CPC classification number: B21D26/045 B21C37/283 B21D26/033 Y10T29/49805

    Abstract: A hollow workpiece having a tubular end portion is deformed by first fitting the workpiece into a die formed with a cavity adapted to receive the workpiece with the end portion of the workpiece projecting along an axis out of the die and then engaging over the projecting end portion of the workpiece a feed sleeve in a pressure-tight fit. The sleeve and workpiece are supported relative to each other such that the holding portion can slide in the sleeve and that the sleeve exerts substantially no axial force on the workpiece. Then an interior of the workpiece is pressurized through the sleeve and to deform the workpiece outward against an inner surface of the die.

    Abstract translation: PCT No.PCT / DE92 / 00060 Sec。 371日期:1992年9月23日 102(e)日期1992年9月23日PCT提交1992年1月31日PCT公布。 WO92 / 13653 PCT出版物 日期为1992年8月20日。具有管状端部的中空工件通过首先将工件装配到模具中而变形,所述模具形成有适于容纳工件的腔,其中工件的端部沿着轴线离开模具突出, 然后以压力配合的方式在工件的突出端部上接合进料套筒。 套筒和工件相对于彼此支撑,使得保持部分可以在套筒中滑动,并且套筒基本上不对工件施加轴向力。 然后,工件的内部通过套筒被加压,并使工件向外压靠在模具的内表面上。

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