公开(公告)号：US06187963B1

公开(公告)日：2001-02-13

申请号：US09169798

申请日：1998-10-09

申请人： William George Etzkorn ,  Richard A. Galley ,  Thomas E. Snead ,  Jonathan Lester Brockwell ,  Mark Anderson Young ,  John Michael Maher ,  Barbara Knight Warren

发明人： William George Etzkorn ,  Richard A. Galley ,  Thomas E. Snead ,  Jonathan Lester Brockwell ,  Mark Anderson Young ,  John Michael Maher ,  Barbara Knight Warren

IPC分类号： C07C2710

CPC分类号： C07C29/141 ,  C07C41/56 ,  C07C45/33 ,  C07C45/35 ,  C07C45/60 ,  C07C45/64 ,  C07C45/69 ,  C07C45/71 ,  C07C319/16 ,  C07C31/245 ,  C07C31/205 ,  C07C47/22 ,  C07C47/12 ,  C07C47/19 ,  C07C47/46 ,  C07C47/198 ,  C07C323/22 ,  C07C43/315

摘要： Processes are disclosed for the conversion of propylene to an acrolein derivative by converting propylene to acrolein and converting acrolein to the acrolein derivative. The processes utilize oxygen and recycle propane to the acrolein reactor. Process feeds can comprise, propane, propylene or mixtures thereof. The presence of propane in the propylene-to-acrolein reaction can enhance the efficiency of the processes.

摘要翻译： 公开了通过将丙烯转化成丙烯醛并将丙烯醛转化为丙烯醛衍生物将丙烯转化为丙烯醛衍生物的方法。 该方法利用氧气并将丙烷再循环到丙烯醛反应器中。 工艺进料可以包含丙烷，丙烯或其混合物。 在丙烯到丙烯醛反应中丙烷的存在可以提高工艺的效率。

公开(公告)号：US6166263A

公开(公告)日：2000-12-26

申请号：US169335

申请日：1998-10-09

申请人： William George Etzkorn ,  Jonathan Lester Brockwell ,  Mark Anderson Young ,  John Michael Maher ,  Barbara Knight Warren

发明人： William George Etzkorn ,  Jonathan Lester Brockwell ,  Mark Anderson Young ,  John Michael Maher ,  Barbara Knight Warren

IPC分类号： C07C45/33 ,  C07C45/35 ,  C07C45/60 ,  C07C45/64 ,  C07C45/69 ,  C07C45/71 ,  C07C45/32

CPC分类号： C07C45/69 ,  C07C45/33 ,  C07C45/35 ,  C07C45/60 ,  C07C45/64 ,  C07C45/71 ,  Y02P20/142 ,  C07C47/22 ,  C07C47/12 ,  C07C47/19 ,  C07C47/46 ,  C07C47/42 ,  C07C47/198

摘要： Processes are disclosed for the conversion of propylene to acrolein in the presence of propane. The processes utilize oxygen and recycle propane to the acrolein reactor. Process feeds can comprise, propane, propylene or mixtures thereof. The presence of propane in the propylene-to-acrolein reaction can enhance the efficiency of the processes.

摘要翻译： 公开了在丙烷存在下将丙烯转化为丙烯醛的方法。 该方法利用氧气并将丙烷再循环到丙烯醛反应器中。 工艺进料可以包含丙烷，丙烯或其混合物。 在丙烯到丙烯醛反应中丙烷的存在可以提高工艺的效率。

公开(公告)号：US5917095A

公开(公告)日：1999-06-29

申请号：US814854

申请日：1997-03-11

申请人： David Robert Bryant ,  James Clair Nicholson ,  John Robert Briggs ,  Diane Lee Packett ,  John Michael Maher

发明人： David Robert Bryant ,  James Clair Nicholson ,  John Robert Briggs ,  Diane Lee Packett ,  John Michael Maher

IPC分类号： C07C45/50

CPC分类号： C07C45/50 ,  Y02P20/582

摘要： This invention relates to a process for separating one or more phosphorus acidic compounds from a reaction product fluid containing said one or more phosphorus acidic compounds, a metal-organophosphorus ligand complex catalyst and optionally free organophosphorus ligand which process comprises (a) treating said reaction product fluid with water sufficient to remove at least some amount of said one or more phosphorus acidic compounds from said reaction product fluid and (b) treating the water which contains phosphorus acidic compounds removed from said reaction product fluid with an acid removal substance sufficient to remove at least some amount of said one or more phosphorus acidic compounds from said water.

摘要翻译： 本发明涉及从含有一种或多种磷酸性化合物，金属 - 有机磷配位体配合物催化剂和任选的游离有机磷配体的反应产物流体中分离一种或多种磷酸性化合物的方法，该方法包括（a）处理所述反应产物 具有足以从所述反应产物流体中除去至少一定量的所述一种或多种磷酸性化合物的流体，和（b）用足以从所述反应产物流体中除去的除酸物质处理从所述反应产物流体中除去的含磷酸性化合物的水 从所述水中至少一些量的所述一种或多种磷酸性化合物。

公开(公告)号：US06307065B1

公开(公告)日：2001-10-23

申请号：US09729408

申请日：2000-12-04

申请人： Erik Bruce Tjaden ,  John Robert Briggs ,  Anil Sakharam Guram ,  John Michael Maher

发明人： Erik Bruce Tjaden ,  John Robert Briggs ,  Anil Sakharam Guram ,  John Michael Maher

IPC分类号： C07D31304

CPC分类号： C07D315/00 ,  C07C67/38 ,  Y02P20/582 ,  C07C69/675

摘要： This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof which comprise subjecting one or more substituted or unsubstituted penten-1-ols to carbonylation in the presence of a carbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof. The substituted and unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactam. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof as principal product(s) of reaction.

公开(公告)号：US5883265A

公开(公告)日：1999-03-16

申请号：US834271

申请日：1997-04-15

申请人： Erik Bruce Tjaden ,  John Robert Briggs ,  Anil Sakharam Guram ,  John Michael Maher

发明人： Erik Bruce Tjaden ,  John Robert Briggs ,  Anil Sakharam Guram ,  John Michael Maher

IPC分类号： C07C67/38 ,  C07D313/04

CPC分类号： C07D313/04 ,  C07C67/38 ,  Y02P20/582

摘要： This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof which comprise subjecting one or more substituted or unsubstituted penten-1-ols to carbonylation in the presence of a carbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof. The substituted and unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactam. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof as principal product(s) of reaction.

摘要翻译： 本发明部分涉及制备一种或多种取代或未取代的ε-己内酯和/或其水合物和/或其酯的方法，其包括在羰基化催化剂存在下使一种或多种取代或未取代的戊烯-1-醇进行羰基化， 例如金属 - 有机磷配体络合物催化剂，以产生所述一种或多种取代或未取代的ε己内酯和/或其水合物和/或其酯。 通过本发明方法制备的取代和未取代的ε-己内酯和/或其水合物和/或酯可进一步反应以提供其所需的衍生物，例如ε己内酰胺。 本发明还部分涉及含有一种或多种取代或未取代的ε-己内酯和/或其水合物和/或其酯作为主要反应产物的反应混合物。

公开(公告)号：US5756855A

公开(公告)日：1998-05-26

申请号：US293028

申请日：1994-08-19

申请人： Anthony George Abatjoglou ,  David Robert Bryant ,  John Michael Maher

发明人： Anthony George Abatjoglou ,  David Robert Bryant ,  John Michael Maher

IPC分类号： B01J31/18 ,  C07C45/50

CPC分类号： C07C45/50 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/0288 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/824 ,  B01J2531/845

摘要： The present invention provides a hydroformylation process comprising: (1) forming a reaction mixture containing: (a) an olefinic compound, (b) hydrogen, (c) carbon monoxide, (d) a phosphite in which each phosphorus atom is bonded to three oxygen atoms and at least one such oxygen atom is bonded to a carbon atom of an aromatic ring that is adjacent to another carbon atom of said ring having a pendant monovalent group having a steric hindrance at least as great as the steric hindrance of the isopropyl group, (e) a catalytic amount of rhodium, and (f) a Group VIII metal (other than a rhodium) in an amount sufficient to reduce the rhodium-catalyzed decomposition of the phosphite during the hydroformylation process; and (2) maintaining the reaction mixture under conditions at which the olefinic compound reacts with the hydrogen and carbon monoxide to form an aldehyde.

公开(公告)号：US20090143544A1

公开(公告)日：2009-06-04

申请号：US12328868

申请日：2008-12-05

申请人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

发明人： Zenon Lysenko ,  Bob R. Maughon ,  Jozef Bicerano ,  Kenneth A. Burdett ,  Christopher P. Christenson ,  Clark H. Cummins ,  Marvin L. Dettloff ,  Alan K. Schrock ,  P. J. Thomas ,  Richard D. Varjian ,  Jerry E. White ,  John Michael Maher

IPC分类号： C08L63/08 ,  C07C51/43 ,  C07C59/42 ,  C07C31/18 ,  C07C215/00 ,  C08L79/02 ,  C08L67/04 ,  C07C229/00 ,  C07C69/732 ,  C07C1/00

CPC分类号： C07D303/42 ,  C07C67/31 ,  C07C67/333 ,  C07C67/347 ,  C07C67/56 ,  C07C69/533 ,  C07C227/08 ,  C07C227/18 ,  C07C229/08 ,  Y02P20/125 ,  C07C69/716 ,  C07C69/675

摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.

摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

公开(公告)号：US06184391B2

公开(公告)日：2001-02-06

申请号：US08839577

申请日：1997-04-15

申请人： Erik Bruce Tjaden ,  John Robert Briggs ,  Anil Sakharam Guram ,  John Michael Maher

发明人： Erik Bruce Tjaden ,  John Robert Briggs ,  Anil Sakharam Guram ,  John Michael Maher

IPC分类号： C07D31304

CPC分类号： C07D315/00 ,  C07C67/38 ,  Y02P20/582 ,  C07C69/675

摘要： This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof which comprise subjecting one or more substituted or unsubstituted penten-1-ols to carbonylation in the presence of a carbonylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce said one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof. The substituted and unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactam. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactones and/or hydrates and/or esters thereof as principal product(s) of reaction.

摘要翻译： 本发明部分涉及制备一种或多种取代或未取代的ε-己内酯和/或其水合物和/或其酯的方法，其包括在羰基化催化剂存在下使一种或多种取代或未取代的戊烯-1-醇进行羰基化， 例如金属 - 有机磷配体络合物催化剂，以产生所述一种或多种取代或未取代的ε己内酯和/或其水合物和/或其酯。 通过本发明方法制备的取代和未取代的ε-己内酯和/或其水合物和/或酯可进一步反应以提供其所需的衍生物，例如ε己内酰胺。 本发明还部分涉及含有一种或多种取代或未取代的ε-己内酯和/或其水合物和/或其酯作为主要反应产物的反应混合物。

公开(公告)号：US5925754A

公开(公告)日：1999-07-20

申请号：US956745

申请日：1997-10-23

申请人： John Michael Maher ,  David Robert Bryant ,  Johnathan Eugene Holladay ,  Thomas Carl Eisenschmid ,  John Robert Briggs ,  Kurt Damar Olson

发明人： John Michael Maher ,  David Robert Bryant ,  Johnathan Eugene Holladay ,  Thomas Carl Eisenschmid ,  John Robert Briggs ,  Kurt Damar Olson

IPC分类号： E02B5/08 ,  C02F1/00 ,  C07C29/16 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/02 ,  C07D201/08 ,  C07D213/16 ,  C07D213/30 ,  C07D213/55 ,  C07F9/6574 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36 ,  C07D223/10

CPC分类号： C07D201/02 ,  C07C45/49 ,  C07C45/50 ,  C07C45/68 ,  C07C47/19 ,  C07D201/08 ,  C07F9/65744 ,  C08G69/02 ,  C08G69/14 ,  C08G69/36 ,  Y02P20/582

摘要： This invention relates to a composition comprising (a) epsilon caprolactam and (b) one or more of 5-�4,5-di(3-carboxypropyl)-2-pyridyl!pentanoic acid or salt or amide, 4-�4,5-di(2-carboxypropyl)-2-pyridyl!-2-methylbutanoic acid or salt or amide, 2-�2-(2-carboxybutyl)-5-(1-carboxypropyl)-4-pyridyl!butanoic acid or salt or amide, 5-�3,5-di(3-carboxypropyl)-2-pyridyl!pentanoic acid or salt or amide, 4-�3,5-di(2-carboxypropyl)-2-pyridyl!-2-methylbutanoic acid or salt or amide, 2-�-2-(2-carboxybutyl)-5-(1-carboxypropyl)-3-pyridyl!butanoic acid or salt or amide, 5-amino-4-methylpentanamide, 4-amino-3-ethylbutanamide, 5-�4,5-di(4-hydroxybutyl)-2-pyridyl!pentanol, 4-�4,5-di(2-methoxypropyl)-2-pyridyl!-2-methylbutanol, 2-�2-(2-methoxybutyl)-5-(1-methoxypropyl)-4-pyridyl!butanol, 5-�3,5-di(4-hydroxybutyl)-2-pyridyl!pentanol, 4-�3,5-di(2-methoxypropyl)-2-pyridyl!-2-methylbutanol, 2-�2-(2-methoxybutyl)-5-(1-methoxypropyl)-3-pyridyl!butanol, 5-amino-4-methyl-1-pentanol, 5-imino-2-methyl-1-pentanamine, 5-amino-2-methyl-1-pentanol, 5-imino-4-methyl-1-pentanamine and 2-butyl-4,5-dipropylpyridine, wherein the weight ratio of component (a) to component (b) is at least about 99 to 1. The epsilon caprolactam compositions are useful in the preparation of nylon 6.

摘要翻译： 本发明涉及包含（a）ε-己内酰胺和（b）一种或多种5- [4,5-二（3-羧丙基）-2-吡啶基]戊酸或其盐或酰胺的组合物，4- [ 2-（2-羧基丙基）-2-吡啶基] -2-甲基丁酸或盐或酰胺，2- [2-（2-羧基丁基）-5-（1-羧基丙基）-4-吡啶基]丁酸或盐 或酰胺，5- [3,5-二（3-羧丙基）-2-吡啶基]戊酸或盐或酰胺，4- [3,5-二（2-羧丙基）-2-吡啶基] -2-甲基丁酸 酸或盐或酰胺，2- [ - 2-（2-羧丁基）-5-（1-羧基丙基）-3-吡啶基]丁酸或盐或酰胺，5-氨基-4-甲基戊酰胺，4-氨基-3 乙基丁酰胺，5- [4,5-二（4-羟丁基）-2-吡啶基]戊醇，4- [4,5-二（2-甲氧基丙基）-2-吡啶基] -2-甲基丁醇，2- [2 - （2-甲氧基丁基）-5-（1-甲氧基丙基）-4-吡啶基]丁醇，5- [3,5-二（4-羟基丁基）-2-吡啶基]戊醇，4- [3,5-二 2-甲氧基丙基）-2-吡啶基] -2-甲基丁醇，2- [2-（2-甲氧基丁基）-5-（1-甲氧基丙基）-3-吡啶基]丁醇，5-氨基-4-甲基-1-戊醇 ，5-亚氨基-2-甲基-1-戊酰胺 5-氨基-2-甲基-1-戊醇，5-亚氨基-4-甲基-1-戊胺和2-丁基-4,5-二丙基吡啶，其中组分（a）与组分（b）的重量比为 至少约99至1。ε-己内酰胺组合物可用于制备尼龙6。

公开(公告)号：US5886236A

公开(公告)日：1999-03-23

申请号：US834248

申请日：1997-04-15

申请人： Thomas Carl Eisenschmid ,  John Robert Briggs ,  Diane Lee Packett ,  Kurt Damar Olson ,  John Michael Maher

发明人： Thomas Carl Eisenschmid ,  John Robert Briggs ,  Diane Lee Packett ,  Kurt Damar Olson ,  John Michael Maher

IPC分类号： C07C51/373 ,  C07C45/50

CPC分类号： C07C51/373 ,  Y02P20/582

摘要： This invention relates in part to processes for producing one or more substituted or unsubstituted aldehyde acid salts, e.g., epsilon caprolactam, which comprises subjecting said one or more substituted or unsubstituted unsaturated acid salts, e.g., pentenoic acid salts, to hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted aldehyde acid salts and/or one or more substituted or unsubstituted epsilon caprolactam precursors. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted aldehyde acid salts as the principal product(s) of reaction.

摘要翻译： 本发明部分地涉及生产一种或多种取代或未取代的醛酸盐，例如ε-己内酰胺的方法，其包括将所述一种或多种取代或未取代的不饱和酸盐例如戊烯酸盐在存在下加成甲酰化反应 加氢甲酰化催化剂，例如金属 - 有机磷配体络合物催化剂，以产生一种或多种取代或未取代的醛酸盐和/或一种或多种取代或未取代的ε-己内酰胺前体。 本发明还部分涉及含有一种或多种取代或未取代的醛酸盐作为主要反应产物的反应混合物。