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    Modified silica based catalyst
    2.
    发明授权
    Modified silica based catalyst 失效
    改性二氧化硅基催化剂

    公开(公告)号：US4950631A

    公开(公告)日：1990-08-21

    申请号：US326708

    申请日：1989-03-21

    申请人： Charles K. Buehler ,  Richard W. Fries ,  Thomas J. Pullukat

    发明人： Charles K. Buehler ,  Richard W. Fries ,  Thomas J. Pullukat

    IPC分类号： C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： A catalyst comprising the product formed by(a) treating silica to remove surface hydroxyl groups;(b) contacting said treated silica with (1) a modifying compound selected from the group consisting of silicon halides, boron halides, aluminum halides, alkyl silicon halides and mixtures thereof; and (2) at least one hydrocarbon soluble magnesium-containing compound selected from the group consisting of hydrocarbyloxy magnesium, hydrocarbyloxymagnesium halides and mixtures thereof; said contacting steps (1) and (2) occurring in random order;(c) contacting the product of step (b) with at least one titanium-containing compound having the structural formula Ti(OR).sub.n X.sub.m, where R is aryl, alkyl or mixtures thereof; X is halogen; n is an integer of 1 to 4; m is 0 or an integer of 1 to 3; and the sum of m and n is 4; and(d) treating the product of step (c) with a titanium-containing compound having the structural formula TiX.sup.1.sub.p OR.sup.1).sub.q, where X.sup.1 is halogen; R.sup.1 is aryl or alkyl; p is an integer of 1 to 4; q is 0 or an integer of 1 to 3; and the sum of p and q is 4, with the proviso that the titanium-containing compound of this step is not the same as the titanium-containing compound of step (c).The catalyst is useful in polymerizing propylene. In this application propylene is polymerized under propylene polymerization conditions in the presence of a first co-catalyst, an aluminum-containing compound, and a second co-catalyst, a slane.

    摘要翻译： 一种催化剂，其包含通过（a）处理二氧化硅以除去表面羟基而形成的产物; （b）使所述经处理的二氧化硅与（1）选自卤化硅，卤化硼，卤化铝，烷基硅卤化物及其混合物的改性化合物接触; 和（2）至少一种选自烃氧基镁，烃氧基镁卤化物及其混合物的烃溶性含镁化合物; 所述接触步骤（1）和（2）以随机顺序出现; （c）使步骤（b）的产物与至少一种具有结构式Ti（OR）n X m的含钛化合物接触，其中R是芳基，烷基或其混合物; X是卤素; n为1〜4的整数， m为0或1〜3的整数， m和n的和为4; 和（d）用具有结构式TiX1pOR1（其中X1为卤素）的钛的化合物处理步骤（c）的产物; R1是芳基或烷基; p为1〜4的整数， q为0或1〜3的整数; p和q的和为4，条件是该步骤的含钛化合物与步骤（c）的含钛化合物不同。 该催化剂可用于聚合丙烯。 在该应用中，丙烯在丙烯聚合条件下在第一助催化剂，含铝化合物和第二助催化剂，硅烷的存在下聚合。

    Propylene polymerization using modified silica based catalyst
    4.
    发明授权
    Propylene polymerization using modified silica based catalyst 失效
    使用改性二氧化硅基催化剂进行丙烯聚合

    公开(公告)号：US5098969A

    公开(公告)日：1992-03-24

    申请号：US569688

    申请日：1990-08-20

    申请人： Charles K. Buehler ,  Richard W. Fries ,  Thomas J. Pullukat

    发明人： Charles K. Buehler ,  Richard W. Fries ,  Thomas J. Pullukat

    IPC分类号： C08F10/00

    CPC分类号： C08F10/00

    摘要： A process for making a propylene polymer which comprises polymerizing propylene under propylene polymerization conditions in the presence of a catalyst system which includes a catalyst component comprising (I) the product obtained by (a) treating silica to remove surface hydroxyl groups; (b) contacting said treated silica with (1) a modifying compound selected from the group consisting of silicon halides, boron halides, aluminum halides, alkyl silicon halides and mixtures thereof; and (2) at least one hydrocarbon soluble magnesium-containing compound; (c) contacting the product of step (b) with at least one titanium-containing compound having the structural formula Ti(OR).sub.n X.sub.m, where R is aryl, alkyl or mixtures thereof; X is halogen; n is an integer of 1 to 4; m is 0 or an integer of 1 to 3; and the sum of m and n is 4; and (d) treating the product of step (c) with a titanium-containing compound having the structural formula TiX.sup.1.sub.p (OR.sup.1).sub.q, where X.sup.1 is halogen; R.sup.1 is aryl or alkyl; p is an integer of 1 to 4; q is 0 or an integer of 1 to 3; and the sum of p and q is 4; a second catalyst component (II), an aluminum-containing compound selected from the group consisting of an alkyl aluminum, an alkyl aluminum halide and mixtures thereof; and a third catalyst component (III), a silane compound.

    摘要翻译： 一种制备丙烯聚合物的方法，其包括在丙烯聚合条件下在催化剂体系存在下聚合丙烯，所述催化剂体系包括催化剂组分，所述催化剂组分包含（I）通过（a）处理二氧化硅以除去表面羟基获得的产物; （b）使所述经处理的二氧化硅与（1）选自卤化硅，卤化硼，卤化铝，烷基硅卤化物及其混合物的改性化合物接触; 和（2）至少一种烃溶性含镁化合物; （c）使步骤（b）的产物与至少一种具有结构式Ti（OR）n X m的含钛化合物接触，其中R是芳基，烷基或其混合物; X是卤素; n为1〜4的整数， m为0或1〜3的整数， m和n的和为4; 和（d）用具有结构式TiX1p（OR1）q的含钛化合物处理步骤（c）的产物，其中X1是卤素; R1是芳基或烷基; p为1〜4的整数， q为0或1〜3的整数; p和q之和为4; 第二催化剂组分（II），选自烷基铝，烷基卤化铝及其混合物的含铝化合物; 和第三催化剂组分（III），硅烷化合物。

    Polymerization method
    5.
    发明授权
    Polymerization method 失效
    聚合方法

    公开(公告)号：US5122581A

    公开(公告)日：1992-06-16

    申请号：US506581

    申请日：1990-04-09

    申请人： Richard W. Fries

    发明人： Richard W. Fries

    IPC分类号： C08F10/00

    CPC分类号： C08F10/00

    摘要： A process for the preparation of linear olefins which comprises polymerizing ethylene in a hydrocarbon solvent at a temperature of 50.degree.-150.degree. C. in the presence of a catalyst comprising a zirconium metal compound, an organometallic compound wherein the metal is selected from the group consisting of zinc, magnesium and aluminum, and a basic salt of a carboxylic acid which forms a fine suspension or a homogeneous solution in the hydrocarbon solvent wherein the ratio of the salt equivalents to the moles of zirconium compound is from above 0 to about 4.0.

    摘要翻译： 一种制备线性烯烃的方法，其包括在包含锆金属化合物的有机金属化合物的存在下，在烃溶剂中在50-150℃的温度下聚合乙烯，其中金属选自 由锌，镁和铝组成的碱金属盐和在烃溶剂中形成细悬浮液或均匀溶液的羧酸碱盐，其中盐当量与锆化合物摩尔数之比为0至约4.0。

    Olefin polymerization catalyst activity by olefin washing
    7.
    发明授权
    Olefin polymerization catalyst activity by olefin washing 失效
    烯烃聚合催化剂活性通过烯烃洗涤

    公开(公告)号：US4471065A

    公开(公告)日：1984-09-11

    申请号：US530533

    申请日：1983-09-09

    申请人： Charles K. Buehler ,  Richard W. Fries

    发明人： Charles K. Buehler ,  Richard W. Fries

    IPC分类号： C08F4/00 ,  C08F4/14 ,  C08F4/16 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： A method is disclosed for increasing the productivity of an olefin polymerization catalyst. The catalyst contains an aluminum chloride co-crystallized titanium halide modified with an electron donor containing an ester group. The catalyst component is washed with an olefin, thereby greatly increasing its productivity without significantly adversely affecting the crystallinity of the polymer produced.

    摘要翻译： 公开了一种用于提高烯烃聚合催化剂的生产率的方法。 催化剂含有用含有酯基团的电子给体改性的氯化铝共结晶的卤化钛。 催化剂组分用烯烃洗涤，从而大大提高其生产率，而不会显着地不利地影响所生产的聚合物的结晶度。

    Method to reactor-fill polyolefins by employing a sticky prepolymer as a blending and compatibilizing agent
    8.
    发明授权
    Method to reactor-fill polyolefins by employing a sticky prepolymer as a blending and compatibilizing agent 失效
    通过使用粘性预聚物作为共混和相容剂来反应填充聚烯烃的方法

    公开(公告)号：US5412025A

    公开(公告)日：1995-05-02

    申请号：US114031

    申请日：1993-08-30

    申请人： Richard W. Fries

    发明人： Richard W. Fries

    IPC分类号： C08F2/44 ,  C08F10/00 ,  C08K5/05 ,  C08K3/04 ,  C08K3/22 ,  C08K3/34

    CPC分类号： C08F10/00 ,  C08F2/44

    摘要： The present invention relates to a process to in-situ reactor-fill polyolefins. More specifically, the instant invention provides a process to reactor-fill polyolefins comprising the steps of (a) adding a sufficient amount of alpha-olefin to a filler prior to using the filler for in-situ polymerization; (b) prepolymerizing the mixture of step (a) by contacting the treated filler in random order of no specific sequence with a high activity polymerization catalyst, a cocatalyst, and, if necessary a cocatalyst modifier; and (c) adding an alpha-olefin under olefin polymerization reaction conditions to the reaction product of step (b) to form a reactor-filled composite. The prepolymerization step results in the formation of a sticky prepolymer on the surface and in the pores of the filler.The present invention further relates to reactor-filled polyolefin composites obtained from the process of the present invention. The reactor-filled polyolefin composites produced by the instant invention are characterized as containing low levels of fines and having a relatively uniform distribution of filler material dispensed throughout the composite matrix.

    摘要翻译： 本发明涉及一种原位反应堆填充聚烯烃的方法。 更具体地，本发明提供了一种反应器填充聚烯烃的方法，包括以下步骤：（a）在使用填料进行原位聚合之前，向填料中加入足够量的α-烯烃; （b）通过使经处理的填料按照无特定顺序的顺序与高活性聚合催化​​剂，助催化剂和必要时的助催化剂改性剂接触来预聚合步骤（a）的混合物; 和（c）在烯烃聚合反应条件下将α-烯烃加入到步骤（b）的反应产物中以形成反应器填充的复合材料。 预聚合步骤导致在填料的表面和孔中形成粘性预聚物。 本发明还涉及从本发明方法获得的反应器填充的聚烯烃复合材料。 由本发明生产的反应器填充的聚烯烃复合材料的特征在于含有低水平的细粒并且具有分布在整个复合基质中的填料分布相对均匀的分布。

    Method to reactor-fill polyolefins by formation of a dual catalyst system causing compatibilization of the filler with the maxtrix polymer
    9.
    发明授权
    Method to reactor-fill polyolefins by formation of a dual catalyst system causing compatibilization of the filler with the maxtrix polymer 失效
    通过形成引起填料与maxtrix聚合物相容化的双重催化剂体系反应器填充聚烯烃的方法

    公开(公告)号：US5412001A

    公开(公告)日：1995-05-02

    申请号：US114034

    申请日：1993-08-30

    申请人： Richard W. Fries

    发明人： Richard W. Fries

    IPC分类号： C08F10/00 ,  C08L9/02 ,  C08L9/04

    CPC分类号： C08F10/00

    摘要： The present invention relates to a method to reactor-fill polyolefins and to reactor-filled composites obtained from the instant method. More specifically, the present invention relates to a method to reactor-fill polyolefins comprising the steps of (a) adding a catalytic amount of a low activity catalyst to a filler material either during or before polymerization to initiate the formation of atactic polyolefin on the surface and in the pores of the filler; (b) contacting the product of step (a) in no specific order with a high activity catalyst, a cocatalyst, and, if necessary a cocatalyst modifier; and (c) adding an alpha-olefin under olefin polymerization reaction conditions to the reaction product of step (b) to form a reactor-filled composite. The addition of the low activity catalyst to the filler material causes compatibilization of the filler with the matrix polymer, reduced fines, rounded aggregate particles and increased catalyst activity over an un-filled polymerization catalyst system or by that afforded by the elimination of the low activity catalyst obtained from the method of the present invention. The reactor-filled polyolefin composites produced by the instant invention are characterized as having a relatively uniform distribution of filler particles dispensed therein and having improved physical and rheological properties compared to prior art reactor-filled composites.

    摘要翻译： 本发明涉及从本方法获得的聚烯烃反应器填充方法和反应堆填充复合材料的方法。 更具体地说，本发明涉及一种反应器填充聚烯烃的方法，包括以下步骤：（a）在聚合期间或之前向填料添加催化量的低活性催化剂，以引发在表面上形成无规聚烯烃 并在填料的孔中; （b）使步骤（a）的产物以特定的顺序与高活性催化剂，助催化剂和必要时的助催化剂改性剂接触; 和（c）在烯烃聚合反应条件下将α-烯烃加入到步骤（b）的反应产物中以形成反应器填充的复合材料。 将低活性催化剂加入到填充材料中导致填料与基质聚合物的相容化，减少的细粉，圆形骨料颗粒和增加的催化剂活性超过未填充的聚合催化剂体系，或通过消除低活性而提供的催化剂活性 由本发明方法得到的催化剂。 由本发明生产的反应器填充的聚烯烃复合材料的特征在于与现有技术的反应器填充的复合材料相比，其中分配有填料颗粒的相对均匀的分布并具有改进的物理和流变性能。

    Modified silica based catalyst
    10.
    发明授权
    Modified silica based catalyst 失效
    改性二氧化硅基催化剂

    公开(公告)号：US5143883A

    公开(公告)日：1992-09-01

    申请号：US590992

    申请日：1990-10-01

    申请人： Charles K. Buehler ,  Richard W. Fries ,  Thomas J. Pullukat

    发明人： Charles K. Buehler ,  Richard W. Fries ,  Thomas J. Pullukat

    IPC分类号： C08F4/654 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： The present invention relates to a silica supported magnesium-containing catalytic precursor of reduced SiOH content for reaction with a titanium halide to form a catalyst for the production of a stereospecific alpha olefin polymer characterized in that prior to reacting with titanium halide the magnesium-containing silica is reacted with at least one titanium compound having the formula Ti(R).sub.n X.sub.m or Ti(OR).sub.n X.sub.m where R is aryl, alkyl, alkaryl, or mixtures thereof; X is halogen; n is an integer of 1 to 4, and m is 0 or an integer of 1 to 3 with the provision that the sum of n and m is 4. It also relates to preparing the catalyst from the precursor.

    摘要翻译： 本发明涉及一种二氧化硅负载的含镁催化剂前体，其具有降低的SiOH含量，用于与卤化钛反应以形成用于制备立体特异性α-烯烃聚合物的催化剂，其特征在于在与卤化钛反应之前，将含镁二氧化硅 与至少一种具有式Ti（R）n Xm或Ti（OR）n X m的钛化合物反应，其中R是芳基，烷基，烷芳基或其混合物; X是卤素; n为1〜4的整数，m为0或1〜3的整数，n和m的总和为4.也涉及从前体制备催化剂。