Apparatus and process for recovery of hydrocarbon from inorganic host
materials
    1.
    发明授权
    Apparatus and process for recovery of hydrocarbon from inorganic host materials 失效
    从无机主体材料回收烃的装置和方法

    公开(公告)号:US4285773A

    公开(公告)日:1981-08-25

    申请号:US88133

    申请日:1979-10-25

    Applicant: William Taciuk

    Inventor: William Taciuk

    CPC classification number: C10G1/02 C10B1/10 B01J2219/182

    Abstract: In the apparatus, concentric, radially spaced tubes are secured to each other and rotated about a common horizontal long axis. Selectively placed and configured lift elements repeatedly lift and drop feed material in the two tubes. Advance elements cause the feed material introduced into the feed end of the structure to advance through the inner tube where it is progressively heated, dehydrated and its hydrocarbon content is largely vaporized. The hydrocarbon vapors are removed from the opposite product end of the structure. The remaining solid material falls from the end of the inner tube into a combustion zone in the outer tube. Oxygen supplying means are provided for causing the carbon coatings on the particles in the combustion zone to burn to produce heat employed in the processing of the feed material. The solid particles in the outer tube are moved back toward the feed end by advancing elements. Recycle fixtures divert a portion of the hot, solid material which has had its carbon coating burned off back into the inner tube to be mixed with the incoming feed material. Means are described for processing the hydrocarbon vapors removed from the inner tube and for cleaning combustion gases and vapors removed from the feed end of both tubes.

    Abstract translation: 在该装置中,同心的,径向间隔的管彼此固定并围绕共同的水平长轴旋转。 选择性放置和配置的升降元件可以反复升降两根管中的进料。 推进元件使得引入到结构的进料端的进料被推进通过内管,其中它被逐渐加热,脱水,并且其烃含量被大部分蒸发。 从结构的相对的产品端去除碳氢化合物蒸汽。 剩余的固体材料从内管的端部落入外管中的燃烧区。 提供氧气供应装置,用于使燃烧区域上的颗粒上的碳涂层燃烧以产生用于进料的加工中所用的热量。 外管中的固体颗粒通过前进元件朝着进给端移回。 回收夹具将一部分已经将其碳涂层燃烧的热固体材料转回到内管中以与进料进料混合。 描述了用于处理从内管去除的烃蒸气并且用于清洁从两个管的进料端去除的燃烧气体和蒸气的装置。

    Thermal apparatus and process for removing contaminants from oil
    2.
    发明授权
    Thermal apparatus and process for removing contaminants from oil 失效
    用于从油中除去污染物的热设备和方法

    公开(公告)号:US06203765B1

    公开(公告)日:2001-03-20

    申请号:US08956441

    申请日:1997-10-23

    Abstract: Used oil is treated in a reactor to remove contaminants. The reactor comprises a rotating vessel forming an internal reaction chamber. The vessel is housed within a heating chamber. The inside of the vessel is indirectly heated by conduction through the vessel walls. The reaction chamber contains a permanently resident charge of non-ablating, granular coarse solids. Within the reaction chamber, the oil is vaporized and pyrolyzed, producing a hydrocarbon vapour. Coke is formed as a byproduct. Contaminants, such as metals and halides, become associated with the coke. The coarse solids scour and comminute the coke to form fine solids. The fine solids are separated within the reaction chamber from the coarse solids and are removed from the vessel through a pipe located at the axis of the vessel. The hydrocarbon vapours are also removed from the vessel through the axial pipe, as a separate stream. Residual fine solids are separated in a cyclone from the vapour stream. The cleaned vapour stream is then condensed to produce a substantially contaminant-free product oil. The contaminant-rich solids are collected for disposal.

    Abstract translation: 将二手油在反应器中处理以除去污染物。 反应器包括形成内部反应室的旋转容器。 容器容纳在加热室内。 容器的内部通过导管通过容器壁间接加热。 反应室含有非消融的颗粒状粗固体的永久性驻留装置。 在反应室内,油被汽化和热解,产生烃蒸气。 焦炭形成副产物。 污染物,例如金属和卤化物,与焦炭相关。 粗固体洗涤并粉碎焦炭以形成细固体。 细小固体在反应室内与粗固体分离,并通过位于容器轴线的管道从容器中取出。 烃蒸气也通过轴向管作为单独的流从容器中取出。 残留的细固体在旋风分离器中与蒸气流分离。 然后将经清洁的蒸汽流冷凝以产生基本上无污染的产物油。 收集富含污染物的固体以便处理。

    Process for thermal cracking a heavy hydrocarbon
    3.
    发明授权
    Process for thermal cracking a heavy hydrocarbon 失效
    重质烃热裂解工艺

    公开(公告)号:US4180455A

    公开(公告)日:1979-12-25

    申请号:US864087

    申请日:1977-12-23

    Applicant: William Taciuk

    Inventor: William Taciuk

    CPC classification number: C10G1/02 B01J8/10 C10C3/007 C10G9/28 B01J2219/182

    Abstract: There is provided an apparatus comprising rotating inner and outer concentric tubes. The inner tube provides a vapor zone and the annular space between the tubes provides a combustion zone. Hot particulate solids, such as sand, are advanced along an endless path through the vapor zone, back through the combustion zone and back into the vapor zone. In the vapor zone, oil is sprayed on the hot solids. The mixture is mixed and cascaded to obtain heat transfer from the solids to the oil, thereby generating hydrocarbon vapors and coke deposition on the solids. The vapors are removed by suction from the vapor zone. The coked solids are transferred into the combustion zone and cascaded and lifted and dropped therein to mix with added oxygen. Coke is burned to heat the solids which are then returned to the vapor zone. The vapors generated in the combustion zone are removed by suction. Segregation of the atmospheres in the two zones is achieved by a combination of maintaining equal pressures in the zones and using the solids, being transferred from one zone to the other, to block gas flow.

    Abstract translation: 提供了一种包括旋转内部和外部同心管的装置。 内管提供蒸气区,管之间的环形空间提供燃烧区。 热的颗粒固体,例如砂,沿着环形路径前进通过蒸汽区,通过燃烧区返回到蒸汽区。 在蒸气区,油被喷在热固体上。 将混合物混合并级联以获得从固体到油的热传递​​,从而在固体上产生烃蒸气和焦炭沉积。 通过蒸气区抽吸除去蒸汽。 将焦炭固体转移到燃烧区中并级联并提升并滴入其中以与添加的氧混合。 将焦炭燃烧以加热固体,然后将其返回到蒸气区。 在燃烧区产生的蒸气通过抽吸除去。 通过在区域中保持相等的压力并使用固体从一个区域转移到另一个区域来阻止气体流动的组合来实现两个区域中的气氛的分离。

    Thermal apparatus and process for removing contaminants from oil
    4.
    发明授权
    Thermal apparatus and process for removing contaminants from oil 有权
    用于从油中除去污染物的热设备和方法

    公开(公告)号:US06589417B2

    公开(公告)日:2003-07-08

    申请号:US09861673

    申请日:2001-05-22

    Abstract: Used oil is treated in a reactor to remove contaminants. The reactor comprises a rotating vessel housed within a heating chamber. The inside of the vessel is indirectly heated by conduction through the vessel walls. The vessel contains a permanently resident charge of non-ablating, coarse granular solids. Within the vessel, the oil is vaporized and pyrolyzed, producing a hydrocarbon vapor. Coke is formed as a byproduct. Contaminants, such as metals and halides become associated with the coke. The coarse granular solids scour and comminute the coke to form fine solids. The fine solids are separated from the coarse solids and are removed from the vessel. The hydrocarbon vapors are separated from any fine solids and are routed to a vapor condensation system for producing a substantially contaminant-free product oil. The contaminant-rich solids are collected for disposal.

    Abstract translation: 将二手油在反应器中处理以除去污染物。 反应器包括容纳在加热室内的旋转容器。 容器的内部通过导管通过容器壁间接加热。 该容器含有非消融性粗颗粒固体的永久性驻留费用。 在容器内,油被蒸发和热解,产生烃蒸气。 焦炭形成副产物。 诸如金属和卤化物的污染物与焦炭相关。 粗颗粒状固体洗涤并粉碎焦炭以形成细小的固体。 细固体与粗固体分离,并从容器中取出。 碳氢化合物蒸气与任何细小的固体分离,并被送至蒸气冷凝系统,以产生基本上无污染的产品油。 收集富含污染物的固体以便处理。

    Prevention of sulfur gas emissions from a rotary processor using lime
addition
    5.
    发明授权
    Prevention of sulfur gas emissions from a rotary processor using lime addition 失效
    防止使用石灰添加剂的旋转处理器中的硫化氢排放

    公开(公告)号:US5607577A

    公开(公告)日:1997-03-04

    申请号:US264094

    申请日:1994-06-21

    CPC classification number: C10G1/02

    Abstract: Oil sand is treated to prevent the production of sulfur dioxide ("SO.sub.2 ") from a known rotating kiln-type processor. Lime or calcium oxide ("CaO") is added with the oil sand feed to the kiln. In the kiln, the CaO is mixed with the sulfur-containing bitumen of the oil sand and preheated. The preheated mixture is then pyrolysed, forming coke which is modified by the added CaO to reduce its tendency to produce SO.sub.2 when combusted. The modified coke is then combusted with air, producing substantially no SO.sub.2.

    Abstract translation: 处理油砂以防止已知的旋转窑式处理器产生二氧化硫(“SO2”)。 将石灰或氧化钙(“CaO”)加入到窑内的油砂进料。 在窑炉中,将CaO与油砂的含硫沥青混合并预热。 然后将预热的混合物热解,形成焦炭,其通过加入的CaO进行改性,以降低其在燃烧时产生SO 2的倾向。 然后将改性焦炭与空气一起燃烧,基本上不产生SO 2。

    Dry thermal processor
    6.
    发明授权
    Dry thermal processor 失效
    干热处理器

    公开(公告)号:US5217578A

    公开(公告)日:1993-06-08

    申请号:US511904

    申请日:1990-04-23

    CPC classification number: B01J8/10 B22C5/08 C10B1/10 B01J2219/182

    Abstract: The processor is of the type incorporating horizontal, concentric, co-extensive inner and outer tubular members which rotate together. The processor is modified in the following respects:The front end of the inner tubular member is circumferentially corrugated and may be provided in the form of a plurality of parallel tubes arranged in a ring array, to thereby increase the shell area to promote heat transfer through the tube walls;Means are provided for interconnecting the tubular members, which means can accommodate differing rates of thermal expansion and;a rock recycle tube assembly is provided to recover oversize material leaving the corrugated portion of the inner tubular member and reject it from the processor.

    Abstract translation: 处理器是包括横向,同心,共同的内部和外部管状构件的类型的处理器,其一起旋转。 处理器在以下方面进行了改进:内管状构件的前端是周向波纹状的,并且可以以多个平行管的形式设置成环形阵列,从而增加壳体区域以促进热传递 管壁; 提供了用于互连管状构件的装置,这意味着可以适应不同的热膨胀率; 岩石循环管组件被提供以回收离开内管状构件的波纹部分的大尺寸材料并将其从处理器中排除。

    Dry thermal processor
    7.
    发明授权
    Dry thermal processor 失效
    干热处理器

    公开(公告)号:US5366596A

    公开(公告)日:1994-11-22

    申请号:US73438

    申请日:1993-06-09

    CPC classification number: C10B1/10

    Abstract: The processor is of the type incorporating horizontal, concentric, co-extensive inner and outer tubular members which rotate together. The processor is modified in the following respects:The front end of the inner tubular member is circumferentially corrugated and may be provided in the form of a plurality of parallel tubes arranged in a ring array, to thereby increase the shell area to promote heat transfer through the tube walls;Means are provided for interconnecting the tubular members, which means can accommodate differing rates of thermal expansion; anda rock recycle tube assembly is provided to recover oversize material leaving the corrugated portion of the inner tubular member and reject it from the processor.

    Abstract translation: 处理器是包括横向,同心,共同的内部和外部管状构件的类型的处理器,其一起旋转。 处理器在以下方面进行了改进:内管状构件的前端是周向波纹状的,并且可以以多个平行管的形式设置成环形阵列,从而增加壳体区域以促进热传递 管壁; 提供了用于互连管状构件的装置,这意味着可以适应不同的热膨胀率; 并且提供岩石再循环管组件以回收离开内管状构件的波纹部分的大尺寸材料并将其从处理器中排除。

    Process for recovery of hydrocarbons from inorganic host materials
    8.
    发明授权
    Process for recovery of hydrocarbons from inorganic host materials 失效
    从无机主体材料回收烃的方法

    公开(公告)号:US4306961A

    公开(公告)日:1981-12-22

    申请号:US158068

    申请日:1980-06-09

    Applicant: William Taciuk

    Inventor: William Taciuk

    Abstract: A dry thermal processor is provided for recovering hydrocarbons from oil sand solids. The processor comprises concentric, radially spaced, horizontal inner and outer tubular members connected for rotation together. The inner member provides a substantially open preheat zone and vaporization zone while the outer member provides, in the annular space between the tubular members, a substantially open combustion zone and heat transfer zone. The ends of the outer member are sealed by stationary feed end and product end structures. Advance means move the oil sand solids from the feed end structure through the preheat and vaporization zones to the product end structure and back through the combustion and heat transfer zones. In the preheat zone the oil sands are progressively heated and dehydrated by heat transferred through walls of the inner member from hot solids being dropped thereon in the heat transfer zone. Rotation of the inner member causes size reduction of the oil sand feed in the preheat zone, and oversize is discharged directly into the annular space at the second end of the preheat zone. In the vaporization zone, the preheated oil sands are mixed with hot sand solids recycled from the combustion zone to thereby vaporize the hydrocarbon content of the oil sands and produce a coke residue on the sands. These coked sands are transferred into the combustion zone where they are struck by air to support combustion of the coke. This combustion together with supplemental heat provide the heat requirements of the processor.

    Abstract translation: 提供干热处理器用于从油砂固体回收烃。 处理器包括同心的,径向间隔开的水平的内部和外部管状构件,其连接用于一起旋转。 内部构件提供基本上开放的预热区域和蒸发区域,而外部构件在管状构件之间的环形空间中提供基本上敞开的燃烧区域和传热区域。 外部构件的端部由固定的进给端和产品端部结构密封。 推进意味着将油砂固体从进料端结构移动通过预热和蒸发区域到产品端部结构并且通过燃烧和传热区域返回。 在预热区域,油砂通过内部构件的壁传递的热量逐渐加热和脱水,热传递区域中的热固体落在其上。 内部构件的旋转导致预热区域中的油砂进料的尺寸减小,并且超大尺寸直接排放到预热区域的第二端处的环形空间中。 在蒸发区中,将预热的油砂与从燃烧区再循环的热砂固体混合,从而汽化油砂的烃含量并在砂上产生焦炭残渣。 这些焦化砂被转移到燃烧区,在那里被空气冲击以支持焦炭的燃烧。 这种燃烧与补充热量一起提供了处理器的热量要求。

    Apparatus and process for recovery of hydrocarbons from inorganic host
materials
    9.
    发明授权
    Apparatus and process for recovery of hydrocarbons from inorganic host materials 失效
    从无机主体材料回收碳氢化合物的装置和方法

    公开(公告)号:US4280879A

    公开(公告)日:1981-07-28

    申请号:US91910

    申请日:1979-11-06

    Applicant: William Taciuk

    Inventor: William Taciuk

    CPC classification number: C10G1/02 B09C1/06 C10B1/10

    Abstract: A dry thermal processor for recovering hydrocarbons from oil sand solids comprises concentric, radially spaced, horizontal inner and outer tubular members connected for rotation together. The inner member provides a substantially open preheat zone and vaporization zone while the outer member provides, in the annular space between the tubular members, a substantially open combustion zone and heat transfer zone. The ends of the outer member are sealed by stationary feed end and product end structures. Advance means move the oil sand solids from the feed end structure through the preheat and vaporization zones to the product end structure and back through the combustion and heat transfer zones. Rotation of the inner member causes size reduction of the oil sand feed in the preheat zone, and oversize is discharged directly into the annular space at the second end of the preheat zone. Separate means are provided for removing the gases produced in the zones, said means maintaining the gaseous atmospheres in the preheat zone, vaporization zone and annular space substantially segregated from each other.

    Abstract translation: 用于从油砂固体回收碳氢化合物的干热处理器包括连接以一起旋转的同心的,径向间隔开的水平的内部和外部管状构件。 内部构件提供基本上开放的预热区域和蒸发区域,而外部构件在管状构件之间的环形空间中提供基本上敞开的燃烧区域和传热区域。 外部构件的端部由固定的进给端和产品端部结构密封。 推进意味着将油砂固体从进料端结构移动通过预热和蒸发区域到产品端部结构并且通过燃烧和传热区域返回。 内部构件的旋转导致预热区域中的油砂进料的尺寸减小,并且超大尺寸直接排放到预热区域的第二端处的环形空间中。 提供分离的装置用于去除区域中产生的气体,所述装置将气氛气氛保持在预热区域,蒸发区域和环形空间基本上彼此分离。

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