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公开(公告)号：US4093668A
公开(公告)日：1978-06-06
申请号：US452565
申请日：1974-03-19
申请人： Wolfgang Reiss , Hans-Ingo Joschek , Rudolf Schnur , Siegfried Winderl , Juergen Dehler , Herwig Hoffmann
发明人： Wolfgang Reiss , Hans-Ingo Joschek , Rudolf Schnur , Siegfried Winderl , Juergen Dehler , Herwig Hoffmann
CPC分类号： C07C33/046 , C08K3/36
摘要： Butynediol is prepared by reacting acetylene and formaldehyde in contact with a heavy metal acetylide as catalyst, in the liquid phase by the Reppe method. Acetylene is fed upwardly through a suspension of the catalyst in formaldehyde at such a rate that it is virtually completely consumed and a liquid zone containing no catalyst is formed above the suspension.
摘要翻译： 丁炔二醇通过使乙炔和甲醛与重金属乙炔化物作为催化剂接触，通过Reppe法在液相中反应制备。 将乙炔向上通过催化剂在甲醛中的悬浮液，其速率实质上完全消耗，并且在悬浮液上形成不含催化剂的液体区域。
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公开(公告)号：US3957888A
公开(公告)日：1976-05-18
申请号：US569216
申请日：1975-04-18
IPC分类号： C07C29/42 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/38 , C07C33/046 , C07C67/00 , C07C29/00
CPC分类号： C07C29/38 , C07C33/046
摘要： Process for the manufacture of butynediol-1,4 from acetylene and formaldehyde in aqueous solution in contact with a copper acetylide catalyst in the absence of a gas phase.
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公开(公告)号：US4067914A
公开(公告)日：1978-01-10
申请号：US671384
申请日：1976-03-29
CPC分类号： C07C33/046
摘要： In a process for the manufacture of butynediol by the reaction of formaldehyde and acetylene in aqueous solution, in which a catalyst is used which is produced by the action of acetylene and formaldehyde on copper (II) compounds, the catalyst becomes inactive when it is treated for a relatively long period with formaldehyde at elevated temperature in the absence of acetylene so that it must constantly remain in contact with acetylene-containing solution if its temperature is above 70.degree. C.
摘要翻译： 在通过甲醛和乙炔在水溶液中反应制造丁炔二醇的方法中，其中使用通过乙炔和甲醛作用于铜（II）化合物而产生的催化剂，当处理时催化剂变得不活动 在不存在乙炔的情况下，甲醛在高温下持续相当长的时间，如果其温度高于70℃，则必须与乙炔溶液一直保持接触。
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公开(公告)号：US3954669A
公开(公告)日：1976-05-04
申请号：US525317
申请日：1974-11-19
申请人： Franz Josef Broecker , Wolfgang Reiss , Karl Baer , Siegfried Winderl , Wolfgang Schroeder , Herwig Hoffmann
发明人： Franz Josef Broecker , Wolfgang Reiss , Karl Baer , Siegfried Winderl , Wolfgang Schroeder , Herwig Hoffmann
IPC分类号： B01J23/72 , B01J23/745 , B01J23/86 , B01J27/232 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/42 , C07C33/04 , C07C67/00 , B01J31/12 , B01J31/14
CPC分类号： C07C29/42 , B01J23/72 , B01J23/745 , B01J23/868
摘要： A new catalyst for the manufacture of butynediol from formaldehyde and acetylene, based on a carbonate which contains copper, has the structure of the natural mineral manasseite, also contains magnesium or aluminum or -- in place of aluminum -- iron or chromium and is converted into the catalyst by reaction of the copper ions with acetylene.
摘要翻译： 用于从甲醛和乙炔制造丁炔二醇的新型催化剂，基于含有铜的碳酸盐，具有天然矿物人造石的结构，还含有镁或铝或代替铝 - 铁或铬，并转化为 催化剂通过铜离子与乙炔的反应。
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公开(公告)号：US4048116A
公开(公告)日：1977-09-13
申请号：US706471
申请日：1976-07-19
申请人： Dieter Voges , Karl Baer , Juergen Boudier , Siegfried Winderl , Herwig Hoffmann
发明人： Dieter Voges , Karl Baer , Juergen Boudier , Siegfried Winderl , Herwig Hoffmann
IPC分类号： B01J23/88 , C07B61/00 , C07C27/00 , C07C29/17 , C07C31/02 , C07C67/00 , C07C209/00 , C07C209/70 , C07C213/00 , C07C213/08 , C07C215/08 , B01J23/72 , B01J23/84
CPC分类号： B01J23/8898 , C07C29/172
摘要： An improved catalyst for the complete hydrogenation of acetylenically unsaturated alcohols and based on nickel, copper and manganese. The catalyst is used without a support and molybdenum is additionally included in an amount approximately equal to the content of manganese.
摘要翻译： 用于炔属不饱和醇的完全氢化并基于镍，铜和锰的改进的催化剂。 催化剂不需要载体就可以使用，钼的含量大约等于锰的含量。
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公开(公告)号：US4072714A
公开(公告)日：1978-02-07
申请号：US765762
申请日：1977-02-04
申请人： Dieter Voges , Karl Baer , Juergen Boudier , Siegfried Winderl , Herwig Hoffmann
发明人： Dieter Voges , Karl Baer , Juergen Boudier , Siegfried Winderl , Herwig Hoffmann
CPC分类号： B01J23/8898
摘要： An improved catalyst for the complete hydrogenation of acetylenically unsaturated alcohols and based on nickel, copper and manganese. The catalyst is used without a support and molybdenum is additionally included in an amount approximately equal to the content of manganese.
摘要翻译： 用于炔属不饱和醇的完全氢化并基于镍，铜和锰的改进的催化剂。 催化剂不需要载体就可以使用，钼的含量大约等于锰的含量。
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公开(公告)号：US3972938A
公开(公告)日：1976-08-03
申请号：US450145
申请日：1974-03-11
IPC分类号： C07B61/00 , B01J23/00 , B01J27/00 , C07C67/00 , C07C209/00 , C07C209/48 , C07C211/09 , C07C211/12 , C07C87/14
CPC分类号： C07C209/48
摘要： A process for the catalytic hydrogenation of adiponitrile in the presence of ammonia, in which a portion of the reaction mixture is recycled and specific molar ratios of adiponitrile and ammonia are maintained.
摘要翻译： 在氨的存在下己二腈催化氢化的方法，其中一部分反应混合物被再循环，并且维持特定的己二腈和氨的摩尔比。
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公开(公告)号：US4197258A
公开(公告)日：1980-04-08
申请号：US969663
申请日：1978-12-15
IPC分类号： C07D295/084 , C07D207/04
CPC分类号： C07D295/084
摘要： The manufacture of N-disubstituted 1-aminoalk-2-yn-4-ols by reacting a secondary amine, e.g. a dialkylamine, formaldehyde and an acetylene-alcohol by a Mannich reaction, using a copper catalyst, takes place with better yield and at a higher rate if carried out in the presence of iodine or of a bromide or iodide.
摘要翻译： N-二取代的1-氨基
碳-2-炔-4-醇的制备通过使仲胺例如 通过Mannich反应使用铜催化剂，以更好的产率发生二烷基胺，甲醛和乙炔醇，并且如果在碘或溴或碘的存在下进行，则以更高的速率进行。-
公开(公告)号：US4014933A
公开(公告)日：1977-03-29
申请号：US391828
申请日：1973-08-27
IPC分类号： B01J23/72 , B01J23/755 , B01J23/76 , B01J23/89 , B01J23/90 , B01J27/185 , B01J27/188 , B01J27/198 , C07C85/02
CPC分类号： B01J27/198 , B01J23/72 , B01J23/755 , B01J23/76 , B01J23/8933 , B01J27/1853 , B01J27/188 , B01J23/90
摘要： An improved method of preparing amines by reaction of alcohols with ammonia or primary or secondary amines at elevated temperature and superatmospheric pressure in the presence of hydrogen and a hydrogenation catalyst containing cobalt, nickel and copper, the improvement comprising using a catalyst which contains (calculated on the metal content of the catalyst) from 70 to 95% by weight of a mixture of cobalt and nickel and from 5 to 30% by weight of copper, the ratio by weight of cobalt to nickel being from 4:1 to 1:4. The amines prepared in this way are suitable for the production of emulsifying agents, plant protection agents and vulcanization accelerators.
摘要翻译： 在氢气和含钴，镍和铜的氢化催化剂的存在下，在高温和超大气压下，通过醇与氨或伯或仲胺的反应来制备胺的改进方法，其改进包括使用含有（按 催化剂的金属含量）70至95重量％的钴和镍的混合物和5至30重量％的铜，钴与镍的重量比为4:1至1:4。 以这种方式制备的胺适用于生产乳化剂，植物保护剂和硫化促进剂。
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公开(公告)号：US3991127A
公开(公告)日：1976-11-09
申请号：US657926
申请日：1976-02-13
申请人： Hubert Corr , Erich Haarer , Herwig Hoffmann , Siegfried Winderl
发明人： Hubert Corr , Erich Haarer , Herwig Hoffmann , Siegfried Winderl
CPC分类号： C07C29/175
摘要： Production of saturated aliphatic alcohols by continuously contacting olefinically unsaturated aliphatic aldehydes with hydrogen in a single stage at elevated temperature in the presence of catalysts containing metallic nickel, supported catalysts being used which contain 60 to 100% by weight of metallic nickel with reference to the metal content of the catalysts.
摘要翻译： 通过在含有金属镍的催化剂存在下，在高温下将烯属不饱和脂族醛与氢气连续接触来制备饱和脂族醇，使用的载体催化剂含有相对于金属的60至100重量％的金属镍 催化剂含量。
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