摘要:
A method is provided for evaporating cyclohexanone oxime in which cyclohexanone oxime is evaporated using a falling-film evaporator with wetting the evaporation surface of the evaporator well with the cyclohexanone oxime at a pressure of less than about 1060 Torr with a falling rate of the cyclohexanone oxime of about 170 kg/hour or more per one meter around the circumference of evaporation surface at the lowest part of the evaporator. In this method, the cyclohexanone oxime is evaporated efficiently with little decomposition thereof, while preventing the plugging of the pipes of the evaporator and continuously carrying out the operation of the evaporator for a long period of time.
摘要:
An apparatus for the production of &egr;-caprolactam is provided which comprises (i) a fluidized bed reactor having a solid catalyst therein for subjecting cyclohexanone oxime to a rearrangement reaction to obtain a reaction product containing unreacted cyclohexanone oxime and (ii) a fixed bed reactor packed with a solid catalyst for subjecting the unreacted cyclohexanone oxime to a rearrangement reaction to obtain &egr;-caprolactam. Using the apparatus, &egr;-caprolactam is obtained with a high yield.
摘要:
A process for producing &egr;-caprolactam is provided which comprises the steps of subjecting cyclohexanone oxime to a gaseous phase Beckmann rearrangement reaction in a fluidized bed system using a solid catalyst and re-generating the catalyst, wherein said process comprises a step of treating the catalyst with an oxygen-containing gas at an elevated temperature in a re-generation step so that the nitrogen content of the catalyst falls within a range of 10 ppm to 2,500 ppm on its way to the reaction step from the re-generating step. According to the present invention, &egr;-caprolactam is produced with a high conversion or a high selectivity without interrupting the rearrangement reaction or the re-generation step.
摘要:
In the production of .epsilon.-caprolactam from cyclohexanon oxime in gaseous phase in the presence of solid catalysts, the catalysts, no matter whether they may have worked, are brought into contact with either aqueous solution of ammonium salts and at least one basic material or ammonia water.
摘要:
This invention relates to a bottle and a method of mixing with the bottle capable of readily mixing solute or dispersoid and liquid contained in different bottles as required.This invention employs as one bottle a glass or hard plastic bottle like a Vial and as the other bottle a flexible plastic bottle, both bottles are engaged and fluctuated to mix the solute or dispersoid in the liquid.
摘要:
.epsilon.-caprolactam is produced by gas phase catalytic synthesis with high selectivity of lactam wherein cyclohexanone oxime is brought into contact with a crystalline metallo-silicate catalyst having Si/metal atomic ratio is more than 500. The metal moiety in the catalyst is Ga, Fe, B, Zr, Bi, Nb, Zn, Be, Cr, La, Ti, Hf, V and/or Cu.
摘要:
The angle of each collimator plate with respect to an X ray focal point is determined by fitting the collimator plate in grooves formed in upper and lower supports each having an integral structure. In addition, the warpage of each collimator plate is corrected and its flatness is maintained by fitting the periphery of the collimator plate which is on the X ray detector side in a corresponding groove of an abutment plate provided on the X ray detection surface side of the upper and lower supports. Furthermore, each collimator plate is supported by the corresponding grooves of the upper and lower supports and the corresponding groove of the abutment plate on at least three sides.
摘要:
A projection type image display apparatus for projecting an image onto a screen includes a light source, a beam shape converter, a beam divider, a beam superimposer, a processing unit, and a projection lens. In operation, the light source emits a light beam. The beam shape converter converts a sectional shape of the light beam into a different shape. For example, the beam shape converter can convert a circular cross section into a rectangular cross section. The beam divider then spatially divides the converted light beam into plural light beams. The beam divider can include, for example, a first prism array that divides the converted light beam horizontally and vertically into four beams. The beam superimposer superimposes the plural light beams onto a target surface, such as a liquid crystal panel. The beam superimposer can include, for example, a second prism array and a beam collimator that superimpose the plural light beams on the target surface. The processing unit supplies a signal so as to display an image on the target surface. The projection lens projects the image onto the screen by the superimposed beam. This apparatus can improve the uniformity of illuminance distribution and the light utilization efficiency, while maintaining high directivity of light.
摘要:
A flexible joint comprises: first cylindrical bodies comprising a pair of spherical ring members; a second cylindrical body comprising a sleeve relatively movably inserted in the first cylindrical bodies from an axial direction X of the second cylindrical body; third cylindrical bodies comprising a pair of casing tubes which are fitted around outer peripheral surfaces of the first cylindrical bodies and are provided with mutually slidable spherical inner peripheral surfaces, the casings being formed at their opposite ends with connecting portions, and being provided at their outer peripheral surfaces of large diameter portions with projections having through holes; and rods capable of being inserted into the through holes formed in the outer peripheral surfaces of the large diameter portions, each of the rods being provided and fixed between the projections of the pair of third cylindrical bodies for restricting the telescopic movement of the tube joint, wherein the rods comprise a pair of rods connected to each other in the vicinity of a substantially central portion between the opposed projections, the pair of rods being threadedly connected to at least one of bottomed holes opened and formed on opposite ends of a long nut which is provided at its substantially central portion with a notched portion so that when excessive external force is applied, the notched portion is preferentially broken to restore telescopic flexible effect of the tube joint.
摘要:
.epsilon.-Caprolactam is prepared by subjecting cyclohexanone oxime in a gas phase to a catalytic reaction using zeolite catalysts in the presence of water and at least one compound selected from alcohols and ether compounds.