摘要:
A method of operating a fuel cell capable of suppressing degradation of a fuel cell caused by starting and stopping of the fuel cell, including carrying out a restoring operation by decreasing a voltage of the cathode following termination of the fuel cell.
摘要:
A polymer electrolyte fuel cell is provided comprising: a hydrogen ion conductive polymer electrolyte membrane; an anode and a cathode sandwiching the hydrogen ion conductive polymer electrolyte membrane; an anode side electroconductive separator having a gas channel for supplying a fuel gas to the anode; a cathode side electroconductive separator having a gas channel for supplying an oxidant gas to the cathode; characterized in that the anode and the cathode comprise a gas diffusion layer and a catalyst layer formed on the gas diffusion layer at the side in contact with the hydrogen ion conductive polymer electrolyte membrane, the catalyst layer has catalyst particles and a hydrogen ion conductive polymer electrolyte, and at least either of hydrogen ion conductivity and gas permeability of at least either of the anode and the cathode varies in a thickness direction of the anode or the cathode.
摘要:
The present specification discloses a polymer electrolyte fuel cell characterized in that each of the cathode and the anode comprises catalyst particles, a hydrogen ion-conductive polymer electrode, a conductive porous base material and a water repellent agent, and water repellency of at least one of the cathode and the anode varies in a direction of thickness or in a plane direction. As such, by varying the degree of the water repellency of the cathode and the anode on the basis of a position, an excellent polymer electrolyte fuel cell having a high discharge characteristic or more specifically a high current-voltage characteristic in a high current density range.
摘要:
A polymer electrolyte fuel cell is provided comprising: a hydrogen ion conductive polymer electrolyte membrane; an anode and a cathode sandwiching the hydrogen ion conductive polymer electrolyte membrane; an anode side electroconductive separator having a gas channel for supplying a fuel gas to the anode; a cathode side electroconductive separator having a gas channel for supplying an oxidant gas to the cathode; characterized in that the anode and the cathode comprise a gas diffusion layer and a catalyst layer formed on the gas diffusion layer at the side in contact with the hydrogen ion conductive polymer electrolyte membrane, the catalyst layer has catalyst particles and a hydrogen ion conductive polymer electrolyte, and at least either of hydrogen ion conductivity and gas permeability of at least either of the anode and the cathode varies in a thickness direction of the anode or the cathode.
摘要:
The durability of a polymer electrolyte fuel cell is very significantly improved by using a tightening pressure of about 2 to 4 kgf/cm2 of area of electrode; or a tightening pressure of about 4 to 8 kgf/cm2 of contact area between electrode and separator plate; or by selecting a value not exceeding about 1.5 mS/cm2 for the short-circuit conductivity attributed to the DC resistance component in each unit cell; or by selecting a value not exceeding about 3 mA/cm2 for the hydrogen leak current per area of electrode of each MEA. Further, in a method of manufacturing or an inspection method for a polymer electrolyte fuel cell stack, fuel cells having high durability can be efficiently manufactured by removing such MEAs or unit cells using such MEAs or such cell stacks having short-circuit conductivity values and/or hydrogen leak current values exceeding predetermined values, respectively.
摘要翻译:通过使用约2至4kgf / cm 2的电极面积的紧固压力,可以显着改善聚合物电解质燃料电池的耐久性; 或约4〜8kgf / cm 2的电极与隔离板之间的接触面积的紧固压力; 或通过选择不超过约1.5mS / cm 2的值,对于每个晶胞中的直流电阻分量导致的短路导电率; 或者通过为每个MEA的电极面积的氢泄漏电流选择不超过约3mA / cm 2的值。 此外,在聚合物电解质燃料电池堆的制造方法或检查方法中,通过使用这样的MEA或这种具有短路导电性值的电池组除去这样的MEA或单元电池,能够有效地制造具有高耐久性的燃料电池,和/ 或氢泄漏电流值分别超过预定值。
摘要:
The durability of a polymer electrolyte fuel cell is very significantly improved by using a tightening pressure of about 2 to 4 kgf/cm2 of area of electrode; or a tightening pressure of about 4 to 8 kgf/cm2 of contact area between electrode and separator plate; or by selecting a value not exceeding about 1.5 mS/cm2 for the short-circuit conductivity attributed to the DC resistance component in each unit cell; or by selecting a value not exceeding about 3 mA/cm2 for the hydrogen leak current per area of electrode of each MEA. Further, in a method of manufacturing or an inspection method for a polymer electrolyte fuel cell stack, fuel cells having high durability can be efficiently manufactured by removing such MEAs or unit cells using such MEAs or such cell stacks having short-circuit conductivity values and/or hydrogen leak current values exceeding predetermined values, respectively.
摘要翻译:通过使用约2至4kgf / cm 2的电极面积的紧固压力,聚合物电解质燃料电池的耐久性得到非常显着的改善; 或电极和隔板之间的接触面积约4至8kgf / cm 2的紧固压力; 或者通过为每个单位电池中的直流电阻分量的短路导电率选择不超过约1.5mS / cm 2的值; 或者通过选择每个MEA的电极面积的氢泄漏电流不超过约3mA / cm 2的值。 此外,在聚合物电解质燃料电池堆的制造方法或检查方法中,通过使用这样的MEA或这种具有短路导电性值的电池组除去这样的MEA或单元电池,能够有效地制造具有高耐久性的燃料电池,和/ 或氢泄漏电流值分别超过预定值。
摘要:
A method of preserving a PEFC stack of the present invention is a method of preserving a PEFC stack that is provided with an oxidizing agent passage having an inlet and an outlet and extending through a cathode and a reducing agent passage having an inlet and an outlet and extending through an anode. The method comprises preserving the polymer electrolyte fuel cell stack in an uninstalled state under a condition in which an oxygen concentration within the oxidizing agent passage and within the reducing agent passage is lower than an oxygen concentration in atmospheric air.
摘要:
A method for easily, quickly and accurately detecting a cross leak or a micro short-circuit in a unit cell or group of cells of a fuel cell stack is provided by determining an electric output of the unit cell or group of cells after stoppage of fuel and/or oxidant and preferably during the introduction of a non-fuel and non-oxidant gas to the cell.
摘要:
A preservation assembly of a polymer electrolyte fuel cell stack is provided. The assembly includes an uninstalled polymer electrolyte fuel cell stack and sealing units. The uninstalled polymer electrolyte fuel cell stack is provided with an oxidizing agent passage having an inlet and an outlet and extending through a cathode and a reducing agent passage having an inlet and an outlet and extending through an anode. The sealing units include sealing plugs or containers and are configured to seal the inlet and the outlet of the oxidizing agent passage within which an oxygen concentration has been decreased and to seal the inlet and the outlet of the reducing agent passage within which the oxygen concentration has been decreased. The uninstalled polymer electrolyte fuel cell stack is in a state before an assembled polymer electrolyte fuel cell stack is incorporated into a fuel cell system.
摘要:
A method of preserving a PEFC stack of the present invention is a method of preserving a PEFC stack that is provided with an oxidizing agent passage having an inlet and an outlet and extending through a cathode and a reducing agent passage having an inlet and an outlet and extending through an anode. The method comprises preserving the polymer electrolyte fuel cell stack in an uninstalled state under a condition in which an oxygen concentration within the oxidizing agent passage and within the reducing agent passage is lower than an oxygen concentration in atmospheric air.