摘要:
A novel olefin polymerization catalyst is provided which comprises (A) a transition metal compound or lanthanoid compound containing two or more atoms selected from the group consisting of boron, nitrogen, oxygen, phosphorus, sulfur, and selenium; and (B) a Lewis acid. A process for producing an olefin polymer is also provided. The catalyst has a high olefin polymerization activity without a combined use of an expensive organoaluminum oxy-compound or organoboron compound, and can maintain the high activity for a long polymerization time.
摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
Olefin polymer with narrow molecular weight distribution and specific molecular weight, olefin polymer having functional group introduced at terminal, tapered polymer containing segment wherein monomer composition continuously changes in the polymer chain, olefin polymer having different segments bonded to each other, and process for preparing these polymers. The olefin polymers are polymers of C2-20 carbon atom olefins and have a number-average molecular weight of ≧500 and Mw/Mn of ≦1.5. In syntheses, an olefin of 2-20 carbon atoms is polymerized in the presence of a catalyst comprising a transition metal compound represented by the formula LmMXn wherein M is a transition metal atom of Group 3-11, m is 1-5, n is a number satisfying a valence of M, L is a ligand—coordinated to the central metal M—which contains a heteroatom having no direct bond to the central metal, and X is e.g. halogen or a hydrocarbon.
摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
The present invention relates to a polymer having a melt tension (MT (g)) substantially the same as or lower than that of a conventional polymer which is substantially the same as the polymer in the recurring unit of the main skeleton, the molecular weight, the molecular weight distribution and the crystallinity, and having a flow activation energy (Ea (KJ/mol)) larger than a value obtained by adding 5 KJ/mol to the Ea value of the conventional polymer. A preferred example of the polymer is a branched polyolefin comprising 50 to 100% by mol of recurring units derived from ethylene and 0 to 50% by mol of recurring units derived from an α-olefin of 3 to 20 carbon atoms and having the following properties: the flow activation energy (Ea (KJ/mol)) and the α-olefin content (C (% by weight)) satisfy a specific relation, and the melt tension (MT (g)) and the melt flow rate (MFR (g/10 min)) satisfy a specific relation. This branched polyolefin is excellent in moldability and mechanical strength.
摘要:
Ethylene-based copolymer microparticles and functional group-containing ethylene-based copolymer microparticles that have particle diameter smaller than that of conventional polyethylene fine-particles, no inter-particle agglomeration, very narrow particle size distribution, and high sphericity are provided, in which requirements (A) to (E): (A) The intrinsic viscosity [η] measured in decalin at 135° C. is in the range of 0.1 to 50 dl/g, (B) at least 95 wt % or more of particles pass through a mesh screen with an opening of 37 μm, (C) the median diameter (d50) measured by laser diffraction scattering is 3 μm≦d50≦25 μm, (D) the circularity coefficient is 0.85 or more, and (E) the variation coefficient of particle diameter (Cv) is 20% or less. Non-agglomerated spherical magnesium-containing microparticles used as magnesium-containing carrier component for olefin-polymerization catalysts that can manufacture the above microparticles are also provided.
摘要:
Ethylene-based copolymer microparticles and functional group-containing ethylene-based copolymer microparticles that have particle diameter smaller than that of conventional polyethylene fine-particles, no inter-particle agglomeration, very narrow particle size distribution, and high sphericity are provided, in which requirements (A) to (E): (A) The intrinsic viscosity [η] measured in decalin at 135° C. is in the range of 0.1 to 50 dl/g, (B) at least 95 wt % or more of particles pass through a mesh screen with an opening of 37 μm, (C) the median diameter (d50) measured by laser diffraction scattering is 3 μm≦d50≦25 μm, (D) the circularity coefficient is 0.85 or more, and (E) the variation coefficient of particle diameter (Cv) is 20% or less. Non-agglomerated spherical magnesium-containing microparticles used as magnesium-containing carrier component for olefin-polymerization catalysts that can manufacture the above microparticles are also provided.
摘要:
The invention provides a process using olefin polymerization catalysts exhibiting excellent polymerization activities. The olefin polymerization catalysts of the invention contain a transition metal compound typified by formula (I) and at least one of an organometallic compound, an organoaluminum oxy-compound or a compound which reacts with said transition metal compound to form an ion pair. The process using the inventive catalysts is useful in producing α-olefin/conjugated diene copolymers having specific properties
摘要:
The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal compound useful for the catalyst, and an &agr;-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc.
摘要翻译:本发明提供了表现出优异聚合活性的烯烃聚合催化剂,使用该催化剂的烯烃聚合方法,用于催化剂的新型过渡金属化合物和具有特定性能的α-烯烃/共轭二烯共聚物。 本发明的烯烃聚合催化剂包含(A)式(I)或(II)的过渡金属化合物和(B)有机金属化合物,或者是含有氧化铝的氧化合物或离子化离子化合物。 本发明的新型过渡金属化合物是式(I)的化合物,其中M是周期表第3或4族的过渡膳食原子; m为1〜3的整数。 R 1是烃基等; R 2〜R 5各自为H,卤素,烃基等; R 6是卤素,烃基等; n是满足M价的数; X为卤素,烃基等