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    PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND
    1.
    发明申请
    PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND 失效
    生产含氧有机化合物的方法

    公开(公告)号：US20100331569A1

    公开(公告)日：2010-12-30

    申请号：US12919494

    申请日：2009-02-27

    申请人： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    发明人： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    IPC分类号： C07C51/50

    CPC分类号： C07C45/33 ,  B01J27/053 ,  B01J37/0201 ,  C07C29/50 ,  C07C45/36 ,  C07C51/00 ,  C07C51/265 ,  C07C2603/74 ,  Y02P20/55 ,  C07C35/37 ,  C07C47/542 ,  C07C49/417 ,  C07C63/04

    摘要： Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.

    摘要翻译： 本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法， 其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基 。 该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

    Process for production of oxygen-containing organic compound
    2.
    发明授权
    Process for production of oxygen-containing organic compound 失效
    含氧有机化合物的制备方法

    公开(公告)号：US08410308B2

    公开(公告)日：2013-04-02

    申请号：US12919494

    申请日：2009-02-27

    申请人： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    发明人： Minoru Takano ,  Naruhisa Hirai ,  Yasutaka Ishii

    IPC分类号： C07C51/50

    CPC分类号： C07C45/33 ,  B01J27/053 ,  B01J37/0201 ,  C07C29/50 ,  C07C45/36 ,  C07C51/00 ,  C07C51/265 ,  C07C2603/74 ,  Y02P20/55 ,  C07C35/37 ,  C07C47/542 ,  C07C49/417 ,  C07C63/04

    摘要： Disclosed is a process for the production of an oxygen-containing organic compound by oxidizing an organic compound with molecular oxygen in a liquid phase in the presence both of a catalytic nitrogen-containing cyclic compound and a catalyst including a solid superacid and, supported thereon, a transition metal compound, in which the nitrogen-containing cyclic compound contains, as a ring constituent, a skeleton represented by following Formula (1), wherein X represents an —OR group, and wherein R represents hydrogen atom or a hydroxyl-protecting group. The process gives the oxygen-containing organic compound in a high yield and enables easy recovery and reuse of the catalyst.

    摘要翻译： 本发明公开了一种在含有催化含氮环状化合物和含有固体超强酸的催化剂存在的条件下，通过在液相中用分子氧氧化有机化合物来制备含氧有机化合物的方法， 其中含氮环状化合物含有作为环成分的由下式（1）表示的骨架的过渡金属化合物，其中X表示-OR基，其中R表示氢原子或羟基保护基 。 该方法以高产率提供含氧有机化合物，并且能够容易地回收和再利用催化剂。

    IMMOBILIZED CYCLIC IMIDE CATALYST AND PROCESS FOR OXIDATION OF ORGANIC COMPOUNDS WITH THE SAME
    3.
    发明申请
    IMMOBILIZED CYCLIC IMIDE CATALYST AND PROCESS FOR OXIDATION OF ORGANIC COMPOUNDS WITH THE SAME 审中-公开
    固定化的环化催化剂及其有机化合物氧化方法

    公开(公告)号：US20100317869A1

    公开(公告)日：2010-12-16

    申请号：US12526010

    申请日：2008-02-28

    申请人： Yasutaka Ishii ,  Minoru Takano ,  Naruhisa Hirai

    发明人： Yasutaka Ishii ,  Minoru Takano ,  Naruhisa Hirai

    IPC分类号： C07F7/10 ,  C07C45/38 ,  C07C51/235

    CPC分类号： B01J31/0247 ,  B01J21/08 ,  B01J31/0254 ,  B01J31/04 ,  B01J2531/72 ,  B01J2531/845 ,  C07B41/06 ,  C07B41/08 ,  C07C45/36 ,  C07C51/265 ,  C07D209/48 ,  Y02P20/55 ,  C07C47/542 ,  C07C63/04 ,  C07C63/26

    摘要： To provide a solid catalyst containing a cyclic imide skeleton which is easily available and easily separable from reaction products and which is easily recovered and regenerated, and free from reaction inhibitory factors; and a process for oxidation of organic compounds with the solid catalyst.An immobilized cyclic imide catalyst having a structure represented by following Formula (1), wherein X is oxygen or an —OR group (wherein R is hydrogen atom or a hydroxyl-protecting group); n is 0 or 1; Z1 is a five- or six-membered cyclic imide skeleton to which an aromatic or nonaromatic ring Z2 may be adjacent; elliptically shaped moiety S is an inorganic support; A1 is a group linking silicon atom with the cyclic imide skeleton Z1 or with the ring Z2 and is either a divalent hydrocarbon group or a group composed of a divalent hydrocarbon group and an amide bond (—NHCO—); and the cyclic imide skeleton Z1 and the ring Z2 may each be substituted.

    摘要翻译： 提供含有环状酰亚胺骨架的固体催化剂，其易于获得并且易于与反应产物分离并易于回收和再生，并且没有反应抑制因子; 以及用固体催化剂氧化有机化合物的方法。 具有下式（1）表示的结构的固定化的环状酰亚胺催化剂，其中X为氧或-OR基（其中R为氢原子或羟基保护基）; n为0或1; Z1是芳族或非芳族环Z2可以相邻的五元或六元环酰亚胺骨架; 椭圆形部分S是无机载体; A1是将硅原子与环状酰亚胺骨架Z1或环Z2连接的基团，为二价烃基或由二价烃基和酰胺键（-NHCO-）构成的基团。 并且环状酰亚胺骨架Z1和环Z2可各自被取代。

    Polymerizable adamantane derivatives and process for producing the same
    6.
    发明授权
    Polymerizable adamantane derivatives and process for producing the same 失效
    可聚合的金刚烷衍生物及其制备方法

    公开(公告)号：US06235851B1

    公开(公告)日：2001-05-22

    申请号：US09214724

    申请日：1999-01-11

    申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Naruhisa Hirai

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Naruhisa Hirai

    IPC分类号： C08F2000

    CPC分类号： C07C67/03 ,  C07C2603/74 ,  C07C69/54

    摘要： A compound shown by the following formula: wherein each of R1a, R2a, R3a and R4a represents a substituent selected from a non-reactive atom, a non-reactive group, a hydroxyl group and an amino group, and at least two members selected from R1a, R2a, R3a and R4a are a hydroxyl group, a carboxyl group or an amino group; is subjected to an esterification reaction or an amidation reaction with a polymerizable unsaturated compound (e.g., an alcohol, a carboxylic acid, an amine) in the presence of a catalyst comprising an element selected from the Group 3 elements, such as a samarium compound, to obtain a polymerizable adamantane derivative having at least one polymerizable unsaturated group in high yield.

    摘要翻译： 下式表示的化合物：其中R1a，R2a，R3a和R4a各自表示选自非反应性原子，非反应性基团，羟基和氨基的取代基，以及选自以下的至少两种： R1a，R2a，R3a和R4a是羟基，羧基或氨基; 在包含选自第3族元素的元素如钐化合物的催化剂存在下，与可聚合不饱和化合物（例如醇，羧酸，胺）进行酯化反应或酰胺化反应， 以高收率得到具有至少一个聚合性不饱和基团的聚合性金刚烷衍生物。