摘要:
A process for crosslinking a thermoplastic ethylene silane copolymer which comprises forming the ethylene silane copolymer in a thermoforming operation into a shaped article and thereafter subjecting the thermoplastic ethylene silane copolymer shaped article to a solution of benzoic acid in an mount and for a time sufficient to crosslink the thermoplastic ethylene silane copolymer.
摘要:
A process for crosslinking comprising the following steps:(a) admixing, in a processing zone, a copolymer containing at least one hydrolyzable silane moiety; a dihydrocarbyltin oxide; and(i) a carboxylic acid;(ii) a compound bearing at least one carboxylate moiety, which is capable of forming a carboxylic acid when subjected to heat and/or moisture; or(iii) mixtures thereof, with the proviso that:(A) in the event that component (ii) is present, the conditions in the processing zone are such that the carboxylate moiety forms a carboxylic acid;(B) the residence time of the mixture in the processing zone is sufficient to at least partially complete the processing of the copolymer, but of sufficient brevity to substantially avoid a reaction of the carboxylic acid with the dihydrocarbyltin oxide; and(b) passing the mixture from step (a) into a crosslinking zone under such reaction conditions that the carboxylic acid reacts with the dihydrocarbyltin oxide to form dihydrocarbyltin carboxylate, said crosslinking zone having a moisture content sufficient to crosslink the hydrolyzable copolymer in the presence of the dihydrocarbyltin carboxylate.
摘要:
Relatively water-stable compositions comprising a thermoplastic polymer having hydrolyzable, pendant silane moieties, a primary or secondary monohydric alcohol and an organo titanate esterification catalyst, which can be activated and extruded about wires and cables and water-cured to crosslinked products.
摘要:
Water-curable silane modified alkylene-alkyl acrylate copolymers, produced by reacting an alkylene-alkyl acrylate copolymer with a polysiloxane in the presence of an organo titanate, which are useful as extrudates about wires and cables.
摘要:
The disclosure of this application is directed to flame retardant compositions comprising an alkylene-alkyl acrylate copolymer, a halogenated flame retardant additive, an oxide, hydroxide, carbonate or sulfate of calcium or magnesium and antimony oxide as a second flame retardant additive. The compositions, as described, can be extruded about electrical conductors to provide insulation thereon and also extruded as jacketing about telephone wires and cables.
摘要:
The disclosure of this application is directed to a polysiloxane, having combined therein an organo titanate, which can be used in the production of silane modified alkylene-alkyl acrylate copolymers. The silane modified copolymers can be extruded about electrical conductors to provide insulation thereon characterized by improved surface characteristics.
摘要:
The disclosure of this application is directed to compositions having improved flame retardant properties containing an alkylene-alkyl acrylate copolymer, a halogenated flame retardant additive and an oxide, carbonate, hydroxide or sulfate of magnesium or calcium in an amount more than 20 and up to about 30 percent by weight. The compositions disclosed are useful as jacketing material and as insulation about wire and cable.
摘要:
An article of manufacture comprising (i) a plurality of electrical conductors having interstices therebetween, each conductor being surrounded by one or more layers of a composition comprising (a) one or more polyolefins and, blended therewith, (b) a mixture containing one or more alkylhydroxyphenylalkanoyl hydrazines and a defined functionalized hindered amine; and (ii) hydrocarbon cable filler grease within the interstices.
摘要:
A flame retardant composition comprising:(i) a linear polyethylene having a density equal to or less than 0.915 gram per cubic centimeter;(ii) a linear polyethylene having a density in the range of 0.916 to 0.925 gram per cubic centimeter, grafted with an unsaturated aliphatic diacid anhydride, said polyethylene being present in an amount of about 40 to about 400 parts by weight based on 100 parts by weight of component (i); and(iii) magnesium hydroxide, surface treated with an organic phosphate ester or a salt thereof in an amount of about 0.1 to about 4 parts by weight of ester per 100 parts by weight of magnesium hydroxide, said magnesium hydroxide being present in an amount of about 90 to about 400 parts by weight based on 100 parts by weight of component (i).
摘要:
A composition comprising:(a) polyethylene having a density equal to or less than 0.915 gram per cubic centimeter grafted with an unsaturated aliphatic diacid anhydride; and(b) magnesium hydroxide, the surface of which is untreated.