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1.发明授权Laminate or thermoplastic polymer composition having low air permeability and pneumatic tire using same as inner liner 有权使用与内衬相同的透气性低的充气轮胎或热塑性聚合物组合物公开(公告)号：US08691373B2
公开(公告)日：2014-04-08
申请号：US12160386
申请日：2006-01-10
CPC分类号： B60C1/0008 , B29C47/0023 , B29C47/065 , B29C47/26 , B32B7/10 , B32B25/08 , B32B25/14 , B32B27/08 , B32B27/302 , B32B27/306 , B32B27/32 , B32B27/34 , B32B2270/00 , B32B2274/00 , B32B2307/54 , B32B2307/7242 , B32B2605/00 , Y10T428/24975 , Y10T428/249981 , Y10T428/249982 , Y10T428/31725 , Y10T428/31855 , Y10T428/31931
摘要： A laminate (C) of a thermoplastic polymer composition comprising: a thermoplastic resin composition (A) having an permeation coefficient of 10×10−12 cc·cm/cm2·sec·cmHg or less, laminated with a thermoplastic polymer composition (B) having a melt viscosity of 500-2000 Pa·s and a Young's modulus at a room temperature of 1-400 MPa, wherein the thickness of a layer of the thermoplastic resin composition (A) is 0.05-10 μm and the air permeation coefficient of the laminate (C) of 20×10−12 cc·cm/cm2·sec·cmHg or less, and a pneumatic tire using the above laminate (C) as an inner liner.
摘要翻译： 1.一种热塑性聚合物组合物的层压体（C），其包含：热塑性树脂组合物（A），其透过系数为10×10〜12cc·cm·cm 2·sec·cmHg以下，与热塑性聚合物组合物（B） 熔体粘度为500-2000Pa·s，室温下的杨氏模量为1-400MPa，其中热塑性树脂组合物（A）的层的厚度为0.05-10μm，透气系数为 层压体（C）为20×10〜12cc·cm·cm 2·sec·cmHg以下，以及使用上述层叠体（C）作为内衬的充气轮胎。
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2.发明申请POLYAMIDE RESIN COMPOSITION HAVING SUPERIOR EXTENSIBILITY AND FLEXING FATIGUE AND PNEUMATIC TIRE AND HOSE USING THE SAME 有权具有超强扩展性和柔韧性疲劳的聚酰胺树脂组合物及使用其的气动轮胎和软管公开(公告)号：US20100099821A1
公开(公告)日：2010-04-22
申请号：US12523477
申请日：2007-01-18
IPC分类号： C08G59/16
CPC分类号： C08L77/00 , C08L51/04 , C08L51/06 , C08L77/02 , C08L77/06 , C08L2666/14 , C08L2666/02 , C08L2666/06 , C08L2666/24
摘要： A polyamide resin composition, having an excellent extensibility and flexing fatigue, composed of a polyamide resin (A), as a matrix, and a modifying polymer (C), dispersed therein, having a functional group (B) reactive with the polyamide resin (A), wherein a tensile stress at break of the modifying polymer (C) is 30 to 70% of the tensile stress at break of the polyamide resin (A), and a tensile elongation at break of the modifying polymer (C) is 100 to 500% of the tensile elongation at break of the polyamide resin (A) as well as a pneumatic tire and hose using the same.
摘要翻译： 具有聚酰胺树脂（A），作为基质的聚酰胺树脂（A）和分散有聚酰胺树脂（B）的官能团（B））的改性聚合物（C）具有优异的伸长性和挠曲疲劳性的聚酰胺树脂组合物 A），其中，改性聚合物（C）的断裂拉伸应力为聚酰胺树脂（A）的断裂拉伸应力的30〜70％，改性聚合物（C）的拉伸断裂伸长率为100 至聚酰胺树脂（A）的断裂拉伸伸长率的500％，以及使用其的充气轮胎和软管。
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3.发明授权Polyamide resin composition having superior extensibility and flexing fatigue and pneumatic tire and hose using the same 有权具有优异的伸缩性和挠曲疲劳的聚酰胺树脂组合物和使用其的充气轮胎和软管公开(公告)号：US08021728B2
公开(公告)日：2011-09-20
申请号：US12523477
申请日：2007-01-18
CPC分类号： C08L77/00 , C08L51/04 , C08L51/06 , C08L77/02 , C08L77/06 , C08L2666/14 , C08L2666/02 , C08L2666/06 , C08L2666/24
摘要： A polyamide resin composition, having an excellent extensibility and flexing fatigue, composed of a polyamide resin (A), as a matrix, and a modifying polymer (C), dispersed therein, having a functional group (B) reactive with the polyamide resin (A), wherein a tensile stress at break of the modifying polymer (C) is 30 to 70% of the tensile stress at break of the polyamide resin (A), and a tensile elongation at break of the modifying polymer (C) is 100 to 500% of the tensile elongation at break of the polyamide resin (A) as well as a pneumatic tire and hose using the same.
摘要翻译： 具有聚酰胺树脂（A），作为基质的聚酰胺树脂（A）和分散有聚酰胺树脂（B）的官能团（B））的改性聚合物（C）具有优异的伸长性和挠曲疲劳性的聚酰胺树脂组合物 A），其中，改性聚合物（C）的断裂拉伸应力为聚酰胺树脂（A）的断裂拉伸应力的30〜70％，改性聚合物（C）的拉伸断裂伸长率为100 至聚酰胺树脂（A）的断裂拉伸伸长率的500％，以及使用其的充气轮胎和软管。
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4.发明申请LAMINATE OR THERMOPLASTIC POLYMER COMPOSITION HAVING LOW AIR PERMEABILITY AND PNEUMATIC TIRE USING SAME AS INNER LINER 有权具有低空气渗透性和气动轮胎的层压或热塑性聚合物组合物使用同一内衬公开(公告)号：US20090038729A1
公开(公告)日：2009-02-12
申请号：US12160386
申请日：2006-01-10
CPC分类号： B60C1/0008 , B29C47/0023 , B29C47/065 , B29C47/26 , B32B7/10 , B32B25/08 , B32B25/14 , B32B27/08 , B32B27/302 , B32B27/306 , B32B27/32 , B32B27/34 , B32B2270/00 , B32B2274/00 , B32B2307/54 , B32B2307/7242 , B32B2605/00 , Y10T428/24975 , Y10T428/249981 , Y10T428/249982 , Y10T428/31725 , Y10T428/31855 , Y10T428/31931
摘要： A laminate (C) of a thermoplastic polymer composition comprising: a thermoplastic resin composition (A) having an permeation coefficient of 10×10−12 cc·cm/cm2·sec·cmHg or less, laminated with a thermoplastic polymer composition (B) having a melt viscosity of 500-2000 Pa·s and a Young's modulus at a room temperature of 1-400 MPa, wherein the thickness of a layer of the thermoplastic resin composition (A) is 0.05-10 μm and the air permeation coefficient of the laminate (C) of 20×10−12 cc·cm/cm2·sec·cmHg or less, and a pneumatic tire using the above laminate (C) as an inner liner.
摘要翻译： 1.一种热塑性聚合物组合物的层压体（C），其包含：具有10×10-12cc.cm / cm2.sec.cmHg以下的渗透系数的热塑性树脂组合物（A），与具有 500-2000Pa.s的熔体粘度和室温下的杨氏模量为1-400MPa，其中热塑性树脂组合物（A）的层的厚度为0.05-10μm，层压体的透气系数 （C）为20×10-12cc.cm / cm2.sec.cmHg以下，以及使用上述层叠体（C）作为内衬的充气轮胎。
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公开(公告)号：US20120136100A1
公开(公告)日：2012-05-31
申请号：US13368539
申请日：2012-02-08
申请人： Yuichi Hara , Naoyuki Morooka
发明人： Yuichi Hara , Naoyuki Morooka
CPC分类号： B60C1/0008 , C08K5/0016 , C08K5/435 , C08L23/28 , C08L23/283 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2207/04 , C08L2312/00 , C08L2666/20
摘要： Provided is a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The composition can be used as an inner liner of a pneumatic tire.
摘要翻译： 提供一种热塑性弹性体组合物，其包含分散在聚酰胺树脂中的卤化异烯烃/对烷基苯乙烯共聚物橡胶，以提高聚酰胺树脂的疲劳耐久性，同时保持聚酰胺的高流动性。 提供了包含由改性聚酰胺树脂（A）构成的连续相和由卤代异烯烃/对烷基苯乙烯共聚物橡胶（B）组成的分散相的热塑性弹性体组合物。 改性聚酰胺树脂（A）是通过将100重量份的聚酰胺树脂（C）以0.05重量份以上且小于3重量份的化合物（D），如 能够在不低于聚酰胺树脂（C）的熔点的温度下与聚酰胺树脂的末端氨基结合的单官能环氧化合物。 组合物可以用作充气轮胎的内衬。
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公开(公告)号：US08288461B2
公开(公告)日：2012-10-16
申请号：US13368539
申请日：2012-02-08
申请人： Yuichi Hara , Naoyuki Morooka
发明人： Yuichi Hara , Naoyuki Morooka
IPC分类号： C08K5/1515 , C08L77/00
CPC分类号： B60C1/0008 , C08K5/0016 , C08K5/435 , C08L23/28 , C08L23/283 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2207/04 , C08L2312/00 , C08L2666/20
摘要： Provided is a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The composition can be used as an inner liner of a pneumatic tire.
摘要翻译： 提供一种热塑性弹性体组合物，其包含分散在聚酰胺树脂中的卤化异烯烃/对烷基苯乙烯共聚物橡胶，以提高聚酰胺树脂的疲劳耐久性，同时保持聚酰胺的高流动性。 提供了包含由改性聚酰胺树脂（A）构成的连续相和由卤代异烯烃/对烷基苯乙烯共聚物橡胶（B）组成的分散相的热塑性弹性体组合物。 改性聚酰胺树脂（A）是通过将100重量份的聚酰胺树脂（C）以0.05重量份以上且小于3重量份的化合物（D），如 能够在不低于聚酰胺树脂（C）的熔点的温度下与聚酰胺树脂的末端氨基结合的单官能环氧化合物。 组合物可以用作充气轮胎的内衬。
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公开(公告)号：US08129453B2
公开(公告)日：2012-03-06
申请号：US13107268
申请日：2011-05-13
申请人： Yuichi Hara , Naoyuki Morooka
发明人： Yuichi Hara , Naoyuki Morooka
IPC分类号： C08K5/1515 , C08L77/00
CPC分类号： B60C1/0008 , C08K5/0016 , C08K5/435 , C08L23/28 , C08L23/283 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2207/04 , C08L2312/00 , C08L2666/20
摘要： Provided is a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The composition can be used as an inner liner of a pneumatic tire.
摘要翻译： 提供一种热塑性弹性体组合物，其包含分散在聚酰胺树脂中的卤化异烯烃/对烷基苯乙烯共聚物橡胶，以提高聚酰胺树脂的疲劳耐久性，同时保持聚酰胺的高流动性。 提供了包含由改性聚酰胺树脂（A）构成的连续相和由卤代异烯烃/对烷基苯乙烯共聚物橡胶（B）组成的分散相的热塑性弹性体组合物。 改性聚酰胺树脂（A）是通过将100重量份的聚酰胺树脂（C）以0.05重量份以上且小于3重量份的化合物（D），如 能够在不低于聚酰胺树脂（C）的熔点的温度下与聚酰胺树脂的末端氨基结合的单官能环氧化合物。 组合物可以用作充气轮胎的内衬。
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公开(公告)号：US20110218281A1
公开(公告)日：2011-09-08
申请号：US13107268
申请日：2011-05-13
申请人： Yuichi Hara , Naoyuki Morooka
发明人： Yuichi Hara , Naoyuki Morooka
CPC分类号： B60C1/0008 , C08K5/0016 , C08K5/435 , C08L23/28 , C08L23/283 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2207/04 , C08L2312/00 , C08L2666/20
摘要： Provided is a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The composition can be used as an inner liner of a pneumatic tire.
摘要翻译： 提供一种热塑性弹性体组合物，其包含分散在聚酰胺树脂中的卤化异烯烃/对烷基苯乙烯共聚物橡胶，以提高聚酰胺树脂的疲劳耐久性，同时保持聚酰胺的高流动性。 提供了包含由改性聚酰胺树脂（A）构成的连续相和由卤代异烯烃/对烷基苯乙烯共聚物橡胶（B）组成的分散相的热塑性弹性体组合物。 改性聚酰胺树脂（A）是通过将100重量份的聚酰胺树脂（C）以0.05重量份以上且小于3重量份的化合物（D），如 单官能环氧化合物，能够在不低于聚酰胺树脂（C）的熔点的温度下与聚酰胺树脂的末端氨基结合。 组合物可以用作充气轮胎的内衬。
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公开(公告)号：US20100234500A1
公开(公告)日：2010-09-16
申请号：US12721955
申请日：2010-03-11
申请人： Yuichi Hara , Naoyuki Morooka
发明人： Yuichi Hara , Naoyuki Morooka
CPC分类号： B60C1/0008 , C08K5/0016 , C08K5/435 , C08L23/28 , C08L23/283 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2207/04 , C08L2312/00 , C08L2666/20
摘要： An object of the invention is to provide a thermoplastic elastomer composition, which includes a halogenated isoolefin/para-alkylstyrene copolymer rubber dispersed in a polyamide resin in order to improve the fatigue durability of a polyamide resin, while maintaining high flowability of the polyamide resin, even if a halogenated isoolefin/para-alkylstyrene copolymer rubber is finely dispersed and loaded to a high content. A thermoplastic elastomer composition comprising a continuous phase composed of a modified polyamide resin (A) and a dispersed phase composed of a halogenated isoolefin/para-alkylstyrene copolymer rubber (B) is provided. The modified polyamide resin (A) is a resin obtained by melt-kneading 100 parts by weight of a polyamide resin (C) with not less than 0.05 part by weight and less than 3 parts by weight a compound (D), such as a monofunctional epoxy compound, capable of binding to a terminal amino group of the polyamide resin at a temperature not lower than the melting point of the polyamide resin (C). The thermoplastic elastomer composition can be favorably used as an inner liner of a pneumatic tire.
摘要翻译： 本发明的目的是提供一种热塑性弹性体组合物，其包含分散在聚酰胺树脂中的卤化异烯烃/对烷基苯乙烯共聚物橡胶，以提高聚酰胺树脂的疲劳寿命，同时保持聚酰胺树脂的高流动性， 即使卤化异烯烃/对烷基苯乙烯共聚物橡胶被细分散并加载到高含量。 提供了包含由改性聚酰胺树脂（A）构成的连续相和由卤代异烯烃/对烷基苯乙烯共聚物橡胶（B）组成的分散相的热塑性弹性体组合物。 改性聚酰胺树脂（A）是通过将100重量份的聚酰胺树脂（C）以0.05重量份以上且小于3重量份的化合物（D），如 能够在不低于聚酰胺树脂（C）的熔点的温度下与聚酰胺树脂的末端氨基结合的单官能环氧化合物。 热塑性弹性体组合物可以有利地用作充气轮胎的内衬。
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公开(公告)号：US20130056121A1
公开(公告)日：2013-03-07
申请号：US13660597
申请日：2012-10-25
CPC分类号： B32B27/34 , B29D30/0005 , B29D30/0685 , B32B25/08 , B32B25/12 , B32B25/18 , B32B27/22 , B32B27/306 , B32B2264/102 , B32B2264/108 , B32B2307/306 , B32B2307/7242 , B60C1/0008 , B60C5/14 , B60C2005/145 , C08K5/435 , C08L21/00 , C08L29/04 , C08L77/02 , Y10T152/10495 , Y10T428/2495 , C08L2666/20 , C08L2666/04
摘要： A low permeability laminate obtained by laminating (A) a thermoplastic resin composition layer containing (i) 50 to 90% by weight of an ethylene vinyl alcohol copolymer having an ethylene content of 20 to 50 mol % and a saponification degree of 90% or more, (ii) 50 to 10% by weight of an aliphatic polyamide resin having 90 mol % or more of an ε-caprolactam-derived component and (iii) 3 to 50 parts by weight of a sulfonamide-based plasticizer, based upon 100 parts by weight of the total amount of the components (i) and (ii) and (B) at least one rubber composition layer, a layer of a thickness εB of layer (B)/a thickness εA of layer (A) (εB/εA) being 10 or more, followed by being heat treated within a range of 130° C. to 210° C. capable of molding and processing for a long time and a pneumatic tire using the same.
摘要翻译： 将（A）含有（i）50〜90重量％的乙烯含量为20〜50摩尔％，皂化度为90％以上的乙烯乙烯醇共聚物的热塑性树脂组合物层 ，（ii）50〜10重量％的具有90摩尔％以上的ε-己内酰胺衍生成分的脂肪族聚酰胺树脂，（iii）3〜50重量份的磺酰胺类增塑剂，基于100 组分（i）和（ii）和（B）的总量的重量份，至少一种橡胶组合物层，层（B）的厚度等级B，层的厚度（A） A）（A等）为10以上，然后在能够长时间成型加工的130℃〜210℃的范围内进行热处理，使用其的充气轮胎 。
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