摘要:
The silicone rubber composition of the present invention comprises (A) an organopolysiloxane obtained by mixing and heating an organopolysiloxane having a silanol group at both ends of the molecular chain and a silane or a siloxane having two hydrolyzable groups in the molecule, (B) a finely divided silica, and (C) a curing agent. The composition, wherein the content of low-molecule siloxanes is remarkably constrained, is quite useful in the application wherein low-molecular siloxanes are obnoxious, for example, in the application of electrical contacts and parts used adjacent thereto, roll materials of copying machines, gaskets for construction, etc.
摘要:
A method of producing a silicone rubber composition, comprising heating a mixture of an organopolysiloxane having a silanol group at both the ends of the molecular chain, a end blocking agent, such as a triorganosilanol, a silane or a siloxane having two dialkylaminosilyl groups in the molecule, and a reinforcing filler thereby carrying out chain lengthening and end blocking of said organopolysiloxane. According to this method, a silicone rubber composition whose low-molecular siloxane content is held down remarkably can be produced without consuming a large amount of energy for the mixing.
摘要:
Organopolysiloxanes having a silanol group at both terminal ends of molecular chain thereof are brought into condensation reaction with each other in the presence of a silane or siloxane having at least two dialkylaminosilyl groups per molecule as a condensation catalyst and a triorganosilanol or other endblocking agent, to lengthen the chain of the organopolysiloxane under reaction, whereby a triorganosilyl-endblocked organopolysiloxane with a high polymerization degree is obtained. The process yields a triorganosilyl-endblocked high-polymerization-degree organopolysiloxane while effectively suppressing or preventing the formation of low-molecular-weight siloxanes.
摘要:
A siloxane gum is prepared by adding a silane or siloxane having two hydrolyzable groups in a molecule to a silanol-terminated organopolysiloxane in such an amount to give a molar ratio of silanol group/hydrolyzable group of from 0.5 to 3 and effecting condensation polymerization. The resulting organopoly-siloxane has a degree of polymerization of higher than 1,000 and a minimized content of low-molecular weight cyclic siloxanes of less than 5,000 ppm.
摘要:
A conductive silicone rubber composition is prepared by mixing an organopolysiloxane having an aminoalkyl radical, an organopolysiloxane having a (meth)acryloxyalkyl or glycidoxyalkyl radical, and conductive carbon black to form silicone rubber composition (A) in which the carbon black is fixed, and then mixing it with a silicone rubber composition (B) comprising a dimethylpolysiloxane. The composition has stable resistivity in the semiconductive region independent of molding conditions.
摘要:
A cement mold-making silicone rubber composition is provided comprising (A) 100 parts by weight of a polyorganosiloxane having at least two silicon-bonded monovalent aliphatic unsaturated hydrocarbon groups in a molecule, (B) a polyorganohydrogensiloxane having at least three silicon-bonded hydrogen atoms in a molecule, in such an amount as to provide 0.1-5 silicon-bonded hydrogen atoms per monovalent aliphatic unsaturated hydrocarbon group in component (A), (C) a platinum base compound in such an amount as to provide 1-100 ppm of platinum atoms based on the weight of component (A), (D) 5-60 parts by weight of finely divided silica having a specific surface area of at least 50 m2/g, and (E) 0.1-100 parts by weight of coal ash and/or pozzolan powder.
摘要:
A fluorosilicone rubber composition is provided comprising (A) a first organopolysiloxane having the formula: R1aR2bR3cSiO(4-a-b-c)/2 wherein R1 is trifluoropropyl, R2 is an aliphatic unsaturated hydrocarbon group, R3 is an aliphatic saturated hydrocarbon or aromatic hydrocarbon group, (B) a silica filler, (C) a second organopolysiloxane having formula (2) wherein R4 is an aliphatic unsaturated hydrocarbon group or the like, and (D) a cure catalyst. The fluorosilicone rubber composition affords satisfactory adhesion at the interface with dimethylsilicone rubber even when the molding pressure is low.
摘要:
A silicone rubber composition contains (A) 100 parts by weight of an organopolysiloxane composition of the organic peroxide or addition reaction curing type, (B) 20-400 parts by weight of aluminum hydroxide, and (C) 1-20 parts by weight of an organopolysiloxane of formula (I): R.sup.1.sub.a (OX).sub.b SiO.sub.(4-a-b)/2 wherein R.sup.1 is a monovalent hydrocarbon group, at least 10 mol % of the R.sup.1 groups being phenyl, X is hydrogen or a monovalent hydrocarbon group, a and b are positive numbers satisfying the range: 1.0.ltoreq.a
摘要翻译:硅橡胶组合物含有(A)100重量份的有机过氧化物或加成反应固化型的有机基聚硅氧烷组合物,(B)20-400重量份的氢氧化铝,和(C)1-20重量份的 式(I)的有机聚硅氧烷:R1a(OX)bSiO(4-ab)/ 2其中R1是一价烃基,R 1基团的至少10摩尔%为苯基,X为氢或一价烃基, 和b是满足以下范围的正数:1.0 aa <2.0,1
摘要:
A silicone rubber composition comprising (A) 100 parts by weight of an organopolysiloxane composition of the organic peroxide or addition curing type, (B) 1-100 parts by weight of finely divided silica, and (C) 30-500 parts by weight of aluminum hydroxide is suitable for use as a high-voltage electrical insulator. The aluminum hydroxide (C) has a water-soluble sodium ion content of up to 0.01% by weight and exhibits pH 6.5-8.0 and an electrical conductivity of up to 50 .mu.s/cm when measured as a 30 wt % water slurry and preferably has been treated to be hydrophobic. The composition cures into a silicone rubber having improved high-voltage electrical insulating properties even under rigorous conditions.
摘要翻译:一种硅橡胶组合物,其包含(A)100重量份的有机过氧化物或加成固化型的有机聚硅氧烷组合物,(B)1-100重量份的细分二氧化硅,和(C)30-500重量份的 氢氧化铝适合用作高压电绝缘体。 氢氧化铝(C)的水溶性钠离子含量高达0.01重量%,当以30重量%的水浆测定时,其pH值为6.5-8.0,电导率高达50μs/ cm 2,优选 已被处理为疏水性。 组合物即使在严格条件下也固化成具有改进的高电压电绝缘性能的硅橡胶。
摘要:
A fiber-containing resin substrate for collectively sealing a semiconductor devices mounting surface of a substrate having the semiconductor devices mounted thereon or a semiconductor devices forming surface of a wafer having semiconductor devices formed thereon, includes: a resin-impregnated fiber base material obtained by impregnating a fiber base material with a thermosetting resin and semi-curing or curing the thermosetting resin; and an uncured resin layer containing an uncured thermosetting resin and formed on one side of the resin-impregnated fiber base material. There can be a fiber-containing resin substrate that enables suppressing warp of a wafer and delamination of semiconductor devices even though a large-diameter wafer or a large-diameter substrate made of a metal and the like is sealed, enables collectively sealing a semiconductor devices mounting surface of the substrate or a semiconductor devices forming surface of the wafer, and has excellent heat resistance or moisture resistance after sealing.