摘要:
A process for producing sulfur tetrafluoride comprises reacting in the absence or presence of a solvent an amine/hydrogen fluoride complex having the formula:Am . (HF).sub.nwherein Am represents an amine selected from the group consisting of nitrogen-containing heterocyclic aromatic amines and derivatives thereof, and n represents 2-4, with sulfur dichloride, sulfur monochloride or a combination of chlorine and sulfur at a temperature of 0.degree. to 60.degree. C., the molar ratio of said amine/hydrogen fluoride complex to said sulfur dichloride, sulfur monochloride or sulfur being represented by the formula: ##EQU1## wherein n is as defined above, A represents moles of sulfur in said sulfur dichloride, sulfur monochloride or sulfur, and B represents moles of said amine/hydrogen complex.
摘要:
SF.sub.6 is produced by a pyrolysis of SF.sub.5 Cl obtained by a reaction of sulfur or sulfur chloride with chlorine and an amine/hydrogen fluoride complex or a reaction of sulfur tetrafluoride with chlorine and an amine/hydrogen fluoride complex.
摘要:
A process for a separation of hexafluoropropylene oxide from hexafluoropropylene by an extractive distillation in the presence of a normally liquid inert compound such as 1,2-dichloroethane, monochlorobenzene, di-isopropyl ether and 1,1,2-trichloroethane.
摘要:
An unsaturated aldehyde having three to four carbon atoms is prepared by reacting the corresponding olefin with molecular oxygen in the vapor phase at a temperature of from 350.degree. to 520.degree. C in the presence of a metal oxide catalyst comprising the metallic components: (a) molybdenum; (b) at least one metal selected from the group consisting of niobium and tantalum; and (c) at least one metal selected from the group consisting of tellurium, bismuth, cobalt, tungsten, indium, and titanium.
摘要:
Methacrylic acid is prepared by reacting methacrolein with molecular oxygen in the presence of a catalyst comprising (a) molybdenum, (b) phosphorus, (c) at least one element selected from the group consisting of thallium and cesium, (d) at least one element selected from the group consisting of vanadium, zirconium, tin, niobium, nickel, tantalum and iron, and (e) oxygen.
摘要:
Methacrylic acid is prepared by reacting methacrolein with molecular oxygen in the vapor phase at a temperature of from 230.degree. C. to 450.degree. C. in the presence of a catalyst having the formula Mo.sub.12 P.sub..alpha.' X.sub..beta.' Y.sub..gamma.' O.sub..delta.' wherein X is at least one member of the group consisting of Cs and Tl:Y is at least one member of the group consisting of Cs and Tl; Y is at least one member of the group consisting of V, Zr, Nb, Ni, Ta and Fe; .alpha.'=0.1-3; .beta.'=0.2-9; .gamma.'=0.1-7; .delta.'=36-100.
摘要:
An unsaturated aldehyde having three to four carbon atoms is prepared by reacting the corresponding olefin with molecular oxygen in the vapor phase at a temperature of from 350.degree. to 520.degree. C in the presence of a metal oxide catalyst comprising the metallic components: (a) molybdenum; (b) at least one metal selected from the group consisting of niobium and tantalum; (c) tellurium; and (d) at least one metal selected from the group consisting of alkali metals, copper, arsenic, antimony, iron and nickel.
摘要:
Unsaturated carboxylic acids are prepared by reacting the corresponding unsaturated aldehyde with molecular oxygen in the presence of a catalyst of (a) molybdenum, (b) phosphorus, (c) antimony, (d) at least one element selected from the group consisting of tungsten, barium, chromium, lead, niobium, tantalum, tin, nickel, iron and zirconium, and (e) oxygen, and optionally (f) at least one element selected from the group consisting of strontium, titanium, germanium, cerium, and silver.
摘要:
Disclosed is a positive photosensitive resin composition which contains a polisiloxane, a naphthoquinone diazide compound, and a solvent. The positive photosensitive resin composition is characterized in that the polysiloxane has: an organosilane-derived structure represented by the general formula (1): at a content ration of 20-80% inclusive of Si relative to the overall number of moles of Si atoms in the polysiloxane; and an organosilane-derived structure represented by general formula (2): The positive photosensitive resin composition exhibits high heat resistance, high transparency, and enables high sensitivity, high resolution patterning. The positive photosensitive resin composition can be used to form cured films such as planarization films used in TFT substrates, interlayer insulating films, core materials and cladding materials, and can be used in elements having cured films such as display elements, semiconductor elements, solid-state imaging elements, and optical waveguide elements.