公开(公告)号：US20080038544A1

公开(公告)日：2008-02-14

申请号：US11577548

申请日：2005-10-21

申请人： Yukio Kitaike ,  Yoshinori Abe

发明人： Yukio Kitaike ,  Yoshinori Abe

IPC分类号： B32B27/28 ,  B32B27/30

CPC分类号： B29C45/14811 ,  B05D7/04 ,  B29K2995/0087 ,  B32B15/08 ,  B32B21/08 ,  B32B27/08 ,  B32B27/30 ,  B32B27/308 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2307/306 ,  B32B2307/4023 ,  B32B2307/408 ,  B32B2307/584 ,  B32B2307/738 ,  B32B2605/003 ,  Y10T428/265 ,  Y10T428/31855

摘要： The present invention provides a matte acrylic resin film which can realize unprecedented design characteristics and is excellent in handleability, the matte layer of which does not generate cracks even in the case of deep drawing of insert molding or in-mold decorating and which has anti-scratch property, surface hardness, heat resistance and flatting, a method for producing the same, and a laminated product in which the matte acrylic resin film is laminated on a substrate. More specifically the matte acrylic resin film comprises an acrylic resin film base and a matte layer which is formed, with the thickness of 0.1 to 5 μm, on one surface of the acrylic resin film base and has a matting agent and a binder resin. The matte acrylic resin film is produced by coating a paint containing the matting agent and the binder resin as the essential components on one surface of the acrylic resin film base by a printing method or a coating method in such a way that the amount of the paint to be coated has to be the amount equivalent to the thickness of the resultant coated layer of 0.1 to 5 μm when dried.

摘要翻译： 本发明提供一种无光泽的丙烯酸树脂膜，其可以实现前所未有的设计特性，并且处理性优异，即使在嵌入成型或模内装饰深拉的情况下，其无光泽层也不会产生裂纹， 刮擦性，表面硬度，耐热性和平整度，其制造方法和层压产品，其中无光泽丙烯酸树脂膜层压在基材上。 更具体地，无光丙烯酸树脂膜包括在丙烯酸树脂膜基材的一个表面上形成厚度为0.1至5μm的丙烯酸树脂膜基材和无光泽层，并具有消光剂和粘合剂树脂。 无机丙烯酸树脂膜通过印刷法或涂布法在丙烯酸树脂膜基材的一个表面上涂布含有消光剂和粘合剂树脂作为主要成分的涂料来制造，使得涂料的量 待干燥时的涂布量必须等于所得涂层厚度为0.1〜5μm的量。

公开(公告)号：US20060110617A1

公开(公告)日：2006-05-25

申请号：US10541729

申请日：2003-12-26

申请人： Yukio Kitaike ,  Yoshinori Abe ,  Junichi Abe ,  Koichiro Kitashima ,  Shogo Okazaki ,  Hideyuki Fujii

发明人： Yukio Kitaike ,  Yoshinori Abe ,  Junichi Abe ,  Koichiro Kitashima ,  Shogo Okazaki ,  Hideyuki Fujii

IPC分类号： B29C45/16 ,  B32B27/30

CPC分类号： B32B27/30 ,  B29C45/14811 ,  B29K2633/08 ,  B29L2031/3005 ,  B29L2031/3044 ,  B29L2031/3047 ,  B32B27/08 ,  B32B27/18 ,  B32B27/308 ,  B32B2605/003 ,  C08F265/06 ,  C08F285/00 ,  C08J5/18 ,  C08J2333/06 ,  Y10T428/254 ,  Y10T428/2998 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31928 ,  Y10T428/31935

摘要： An acrylic resin film material comprising at least a multilayer structure polymer with a particular structure prevent a molded item from being whitened during insert- or in-mold molding and meet the requirement for surface hardness, heat resistance, and transparency or matting performance for vehicle applications. It is also possible to use an acrylic resin film material exhibiting a difference of 30% or less between haze values as determined in accordance with the testing method of JIS K7136 (haze measurement method) after and before a tensile test where a test piece with a width of 20 mm is pulled under the conditions of an initial inter-chuck distance of 25 mm, a rate of 50 mm/min and a temperature of 23° C. until an end-point inter-chuck distance becomes 33 mm as well as having a pencil hardness of 2 B or higher as determined in accordance with JIS K5400.

摘要翻译： 包括至少具有特定结构的多层结构聚合物的丙烯酸树脂膜材料防止在嵌入或模内成型期间模塑物品变白，并满足车辆应用的表面硬度，耐热性和透明度或消光性能的要求 。 还可以使用丙烯酸树脂薄膜材料，其在根据JIS K7136的测试方法（雾度测量方法）测定的雾度值之间差异为30％以下，在拉伸试验之后和之后，将具有 在初始夹头距离为25mm，速率为50mm / min，温度为23℃的条件下拉出20mm的宽度，直到端点夹头间距为33mm， 具有根据JIS K5400确定的2B B或更高的铅笔硬度。

公开(公告)号：US08137803B2

公开(公告)日：2012-03-20

申请号：US12831436

申请日：2010-07-07

申请人： Yukio Kitaike ,  Yoshinori Abe ,  Junichi Abe ,  Koichiro Kitashima ,  Shogo Okazaki ,  Hideyuki Fujii

发明人： Yukio Kitaike ,  Yoshinori Abe ,  Junichi Abe ,  Koichiro Kitashima ,  Shogo Okazaki ,  Hideyuki Fujii

IPC分类号： B32B27/30

CPC分类号： B32B27/30 ,  B29C45/14811 ,  B29K2633/08 ,  B29L2031/3005 ,  B29L2031/3044 ,  B29L2031/3047 ,  B32B27/08 ,  B32B27/18 ,  B32B27/308 ,  B32B2605/003 ,  C08F265/06 ,  C08F285/00 ,  C08J5/18 ,  C08J2333/06 ,  Y10T428/254 ,  Y10T428/2998 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31928 ,  Y10T428/31935

摘要： An acrylic resin film material comprising at least a multilayer structure polymer with a particular structure prevent a molded item from being whitened during insert- or in-mold molding and meet the requirement for surface hardness, heat resistance, and transparency or matting performance for vehicle applications. It is also possible to use an acrylic resin film material exhibiting a difference of 30% or less between haze values as determined in accordance with the testing method of JIS K7136 (haze measurement method) after and before a tensile test where a test piece with a width of 20 mm is pulled under the conditions of an initial inter-chuck distance of 25 mm, a rate of 50 mm/min and a temperature of 23° C. until an end-point inter-chuck distance becomes 33 mm as well as having a pencil hardness of 2 B or higher as determined in accordance with JIS K5400.

摘要翻译： 包括至少具有特定结构的多层结构聚合物的丙烯酸树脂膜材料防止在嵌入或模内成型期间模塑物品变白，并满足车辆应用的表面硬度，耐热性和透明度或消光性能的要求 。 还可以使用丙烯酸树脂薄膜材料，其在根据JIS K7136的测试方法（雾度测量方法）测定的雾度值之间差异为30％以下，在拉伸试验之后和之后，将具有 在初始夹头距离为25mm，速率为50mm / min，温度为23℃的条件下拉出20mm的宽度，直到端点夹头间距为33mm， 具有根据JIS K5400确定的2B B或更高的铅笔硬度。

公开(公告)号：US07781062B2

公开(公告)日：2010-08-24

申请号：US10541729

申请日：2003-12-26

申请人： Yukio Kitaike ,  Yoshinori Abe ,  Junichi Abe ,  Koichiro Kitashima ,  Shogo Okazaki ,  Hideyuki Fujii

发明人： Yukio Kitaike ,  Yoshinori Abe ,  Junichi Abe ,  Koichiro Kitashima ,  Shogo Okazaki ,  Hideyuki Fujii

IPC分类号： B32B27/30 ,  B32B5/16

CPC分类号： B32B27/30 ,  B29C45/14811 ,  B29K2633/08 ,  B29L2031/3005 ,  B29L2031/3044 ,  B29L2031/3047 ,  B32B27/08 ,  B32B27/18 ,  B32B27/308 ,  B32B2605/003 ,  C08F265/06 ,  C08F285/00 ,  C08J5/18 ,  C08J2333/06 ,  Y10T428/254 ,  Y10T428/2998 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31928 ,  Y10T428/31935

摘要： An acrylic resin film material comprising at least a multilayer structure polymer with a particular structure prevent a molded item from being whitened during insert- or in-mold molding and meet the requirement for surface hardness, heat resistance, and transparency or matting performance for vehicle applications. It is also possible to use an acrylic resin film material exhibiting a difference of 30% or less between haze values as determined in accordance with the testing method of JIS K7136 (haze measurement method) after and before a tensile test where a test piece with a width of 20 mm is pulled under the conditions of an initial inter-chuck distance of 25 mm, a rate of 50 mm/min and a temperature of 23° C. until an end-point inter-chuck distance becomes 33 mm as well as having a pencil hardness of 2 B or higher as determined in accordance with JIS K5400.

摘要翻译： 包括至少具有特定结构的多层结构聚合物的丙烯酸树脂膜材料防止在嵌入或模内成型期间模塑物品变白，并满足车辆应用的表面硬度，耐热性和透明度或消光性能的要求 。 还可以使用丙烯酸树脂薄膜材料，其在根据JIS K7136的测试方法（雾度测量方法）测定的雾度值之间差异为30％以下，在拉伸试验之后和之后，将具有 在初始夹头距离为25mm，速率为50mm / min，温度为23℃的条件下拉出20mm的宽度，直到端点夹头间距为33mm， 具有根据JIS K5400确定的2B B或更高的铅笔硬度。

公开(公告)号：US5543463A

公开(公告)日：1996-08-06

申请号：US250614

申请日：1994-05-27

申请人： Yukio Kitaike ,  Hiroki Hatakeyama ,  Suehiro Tayama ,  Kazuhiko Nakagawa

发明人： Yukio Kitaike ,  Hiroki Hatakeyama ,  Suehiro Tayama ,  Kazuhiko Nakagawa

IPC分类号： B32B27/30 ,  C08L27/06 ,  C08L33/06 ,  C08L33/14 ,  C08L51/06 ,  C08L55/02 ,  C08L101/00 ,  C08L33/12 ,  C08L29/02 ,  C08L51/04

CPC分类号： C08L51/06 ,  B32B27/30 ,  C08L101/00 ,  C08L27/06 ,  C08L33/06 ,  C08L55/02 ,  C08L33/066 ,  C08L33/14 ,  Y10T428/31507 ,  Y10T428/31917 ,  Y10T428/3192 ,  Y10T428/31928 ,  Y10T428/31935

摘要： Disclosed is a technology for providing a thermoplastic resin composition or resin laminate having an excellent mat property by using, as matting agent, a copolymer (B) prepared by polymerizing 0.5 to 80% by weight of a hydroxyalkyl (meth)acrylate having a C.sub.1-8 alkyl group and 10 to 99% by weight of an alkyl methacrylate having a C.sub.1-13 alkyl group, with a C.sub.1-8 alkyl acrylate, vinyl aromatic monomer, another vinyl monomer, and a cross-linking monomer being optional.

公开(公告)号：US06509097B1

公开(公告)日：2003-01-21

申请号：US09508093

申请日：2000-03-16

申请人： Hiroki Hatakeyama ,  Kazuaki Hayashida ,  Yukio Kitaike

发明人： Hiroki Hatakeyama ,  Kazuaki Hayashida ,  Yukio Kitaike

IPC分类号： C08L5100

CPC分类号： B32B27/08 ,  B32B27/18 ,  B32B27/308 ,  B32B27/36 ,  B32B2367/00 ,  C08J5/18 ,  C08J2351/04 ,  C08L51/003 ,  C08L51/04 ,  C09D151/003 ,  C09D151/04 ,  Y10T428/31507 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31917 ,  Y10T428/31938 ,  C08L2666/04 ,  C08L2666/02

摘要： An acrylic film with excellent flexibility is easy to process and has 70 to 95 parts by weight of an acrylic rubber-containing polymer (A) and to 30 parts by weight of an acrylic-based thermoplastic polymer (B) and having a total amount of (A) and (B) of 100 parts by weight; a gel content of 50 to 70% by weight; and elongation at break in one direction of 180% or more. The acrylic rubber-containing polymer (A) has an elastic copolymer having a monomer unit whose polymer has a glass transition temperature of more than 65° C. The acrylic-based thermoplastic polymer (B) has a glass transition temperature of 65° C. or less and a weight average molecular weight of 100,000 to 300,000.

摘要翻译： 具有优异柔软性的丙烯酸薄膜易于加工，并且具有70至95重量份的含丙烯酸橡胶的聚合物（A）和30重量份的丙烯酸类热塑性聚合物（B），并且具有 （A）和（B）为100重量份; 凝胶含量为50〜70重量％ 一个方向的断裂伸长率在180％以上。 含丙烯酸类橡胶的聚合物（A）具有弹性共聚​​物，其具有聚合物的玻璃化转变温度高于65℃的单体单元。丙烯酸类热塑性聚合物（B）的玻璃化转变温度为65℃。 或更小，重均分子量为100,000至300,000。

公开(公告)号：US06764766B2

公开(公告)日：2004-07-20

申请号：US10096664

申请日：2002-03-14

申请人： Yukio Kitaike ,  Hideyuki Fujii ,  Kazuhiko Nakagawa

发明人： Yukio Kitaike ,  Hideyuki Fujii ,  Kazuhiko Nakagawa

IPC分类号： B32B2730

CPC分类号： B32B27/08 ,  B32B27/30 ,  B32B2327/06 ,  B32B2367/00 ,  B32B2369/00 ,  C08F285/00 ,  C08J5/18 ,  C08J2333/08 ,  Y10T428/2486 ,  Y10T428/24942 ,  Y10T428/2987 ,  Y10T428/31928 ,  Y10T428/31935

摘要： There is provided an acrylic resin film having good matted appearances and good printing characteristics, e.g., little suffering missing prints when printed. There is provided an acrylic resin film having a differential 60° surface gloss of 5% or more between the front and back sides, and thickness of 300 &mgr;m or less; a method of producing the above-described acrylic resin film, where a molten acrylic resin composition is extruded, and then rolled between a mirror-ground roll and rubber or embossed roll into the film; and a laminate (formed article coated with the acrylic resin film) with a side having a higher 60° surface gloss coming into contact with a base.

摘要翻译： 提供了一种丙烯酸树脂薄膜，其具有良好的表面光洁度和良好的印刷特性，例如在印刷时缺少少量印刷痕迹。提供了一种丙烯酸树脂薄膜，其前后两面具有5％或更大的差异60°表面光泽度 ，厚度300μm以下; 制造上述丙烯酸树脂膜的方法，其中挤出熔融丙烯酸树脂组合物，然后在反射镜研磨辊和橡胶或压花辊之间滚动到膜中; 和具有较高60°表面光泽的一侧与基底接触的层压体（被丙烯酸树脂膜涂覆的成型物）。

公开(公告)号：US5563227A

公开(公告)日：1996-10-08

申请号：US471412

申请日：1995-06-06

申请人： Yukio Kitaike ,  Hiroki Hatakeyama ,  Suehiro Tayama ,  Kazuhiko Nakagawa

发明人： Yukio Kitaike ,  Hiroki Hatakeyama ,  Suehiro Tayama ,  Kazuhiko Nakagawa

IPC分类号： B32B27/30 ,  C08L27/06 ,  C08L33/06 ,  C08L33/14 ,  C08L51/06 ,  C08L55/02 ,  C08L101/00 ,  C08F220/18 ,  C08F216/04 ,  C08F220/28

CPC分类号： C08L51/06 ,  B32B27/30 ,  C08L101/00 ,  C08L27/06 ,  C08L33/06 ,  C08L55/02 ,  C08L33/066 ,  C08L33/14 ,  Y10T428/2982

摘要： Disclosed is a technology for providing a thermoplastic resin composition or resin laminate having an excellent mat property by using, as matting agent, a copolymer (B) prepared by polymerizing 0.5 to 80% by weight of a hydroxyalkyl (meth)acrylate having a C.sub.1-8 alkyl group and 10 to 99% by weight of an alkyl methacrylate having a C.sub.1-13 alkyl group, with a C.sub.1-8 alkyl acrylate, vinyl aromatic monomer, another vinyl monomer, and a cross-linking monomer being optional.

摘要翻译： 公开了一种通过使用通过使0.5〜80重量％的具有C1-6烷基的（甲基）丙烯酸羟烷基酯的聚合而制备的共聚物（B）作为消光剂，提供具有优异垫层性质的热塑性树脂组合物或树脂层压体的技术， 8个烷基和10至99重量％的具有C1-13烷基的甲基丙烯酸烷基酯，其中C1-8烷基丙烯酸酯，乙烯基芳族单体，另一个乙烯基单体和交联单体是任选的。

公开(公告)号：US5560994A

公开(公告)日：1996-10-01

申请号：US466768

申请日：1995-06-06

申请人： Yukio Kitaike ,  Hiroki Hatakeyama ,  Suehiro Tayama ,  Kazuhiko Nakagawa

发明人： Yukio Kitaike ,  Hiroki Hatakeyama ,  Suehiro Tayama ,  Kazuhiko Nakagawa

IPC分类号： B32B27/30 ,  C08L27/06 ,  C08L33/06 ,  C08L33/14 ,  C08L51/06 ,  C08L55/02 ,  C08L101/00 ,  B32B27/08

CPC分类号： C08L51/06 ,  B32B27/30 ,  C08L101/00 ,  C08L27/06 ,  C08L33/06 ,  C08L55/02 ,  C08L33/066 ,  C08L33/14 ,  Y10T428/31507 ,  Y10T428/31917 ,  Y10T428/3192 ,  Y10T428/31928 ,  Y10T428/31935

摘要： Disclosed is a technology for providing a thermoplastic resin composition or resin laminate having an excellent mat property by using, as matting agent, a copolymer (B) prepared by polymerizing 0.5 to 80% by weight of a hydroxyalkyl (meth)acrylate having a C.sub.1-8 alkyl group and 10 to 99% by weight of an alkyl methacrylate having a C.sub.1-13 alkyl group, with a C.sub.1-8 alkyl acrylate, vinyl aromatic monomer, another vinyl monomer, and a cross-linking monomer being optional.

摘要翻译： 公开了一种通过使用通过使0.5〜80重量％的具有C1-6烷基的（甲基）丙烯酸羟烷基酯的聚合而制备的共聚物（B）作为消光剂，提供具有优异垫层性质的热塑性树脂组合物或树脂层压体的技术， 8个烷基和10至99重量％的具有C1-13烷基的甲基丙烯酸烷基酯，其中C1-8烷基丙烯酸酯，乙烯基芳族单体，另一个乙烯基单体和交联单体是任选的。