公开(公告)号：US20100016200A1

公开(公告)日：2010-01-21

申请号：US12440614

申请日：2007-09-11

申请人： Yuko Nagare ,  Kei Watanabe ,  Kazutami Sakamoto ,  Shun Takahashi ,  Teruhiko Hineno

发明人： Yuko Nagare ,  Kei Watanabe ,  Kazutami Sakamoto ,  Shun Takahashi ,  Teruhiko Hineno

IPC分类号： A61K8/06

CPC分类号： A61Q19/10 ,  A61K8/0291 ,  A61K8/0295 ,  A61K8/042 ,  A61K8/11 ,  A61K8/25 ,  A61K8/585 ,  A61K2800/262 ,  A61K2800/412 ,  A61Q1/02

摘要： The present invention provides new silica composite capsules that can be easily prepared, a composition containing the silica composite capsules, and a transparent gel-form composition excellent in appearance transparency and texture in use, and in particular, a transparent gel-form composition with improved cleansing properties when used as a cleanser. Micelle/silica composite capsules can easily be obtained, in an aqueous system, by mixing a material capable of forming micelles in water and a water-soluble silane derivative having a specific structure in aqueous solution. In addition, emulsion/silica composite capsules wherein the periphery of emulsion particles in the inner phase is coated with silica, can easily be obtained by mixing a surfactant, water, an oil, and a water-soluble silane derivative having a specific structure. Moreover, a transparent gel-form composition showing excellent appearance transparency, the texture in use and cleansing properties, can be obtained by blending a water-soluble silane derivative having a specific structure into the formulation that contains a surfactant, an oil and water, and capable of taking a surfactant association structure with aqueous continuous phase or both of aqueous continuous phase and oil continuous phase in the formulation.

摘要翻译： 本发明提供了可以容易地制备的新的二氧化硅复合胶囊，含有二氧化硅复合胶囊的组合物，以及外观透明性和使用质地优异的透明凝胶状组合物，特别是具有改进的透明凝胶状组合物 用作清洁剂时的清洁性能。 通过将能够在水中形成胶束的材料和在水溶液中具有特定结构的水溶性硅烷衍生物混合，可以在水性体系中容易地获得胶束/二氧化硅复合胶囊。 此外，通过混合表面活性剂，水，油和具有特定结构的水溶性硅烷衍生物，可以容易地得到内层的乳液粒子的周围用二氧化硅涂布的乳液/二氧化硅复合胶囊。 此外，通过将具有特定结构的水溶性硅烷衍生物掺入含有表面活性剂，油和水的配方中，可以获得表现出优异的外观透明度，使用质地和清洁性能的透明凝胶状组合物，以及 能够在制剂中具有含水连续相或水相连续相和油连续相的表面活性剂缔合结构。

公开(公告)号：US08030267B2

公开(公告)日：2011-10-04

申请号：US12440614

申请日：2007-09-11

申请人： Yuko Nagare ,  Kei Watanabe ,  Kazutami Sakamoto ,  Shun Takahashi ,  Teruhiko Hineno

发明人： Yuko Nagare ,  Kei Watanabe ,  Kazutami Sakamoto ,  Shun Takahashi ,  Teruhiko Hineno

IPC分类号： C11D9/36 ,  C11D3/44

CPC分类号： A61Q19/10 ,  A61K8/0291 ,  A61K8/0295 ,  A61K8/042 ,  A61K8/11 ,  A61K8/25 ,  A61K8/585 ,  A61K2800/262 ,  A61K2800/412 ,  A61Q1/02

摘要： The present invention provides new silica composite capsules that can be easily prepared, a composition containing the silica composite capsules, and a transparent gel-form composition excellent in appearance transparency and texture in use, and in particular, a transparent gel-form composition with improved cleansing properties when used as a cleanser. Micelle/silica composite capsules can easily be obtained, in an aqueous system, by mixing a material capable of forming micelles in water and a water-soluble silane derivative having a specific structure in aqueous solution. In addition, emulsion/silica composite capsules wherein the periphery of emulsion particles in the inner phase is coated with silica, can easily be obtained by mixing a surfactant, water, an oil, and a water-soluble silane derivative having a specific structure. Moreover, a transparent gel-form composition showing excellent appearance transparency, the texture in use and cleansing properties, can be obtained by blending a water-soluble silane derivative having a specific structure into the formulation that contains a surfactant, an oil and water, and capable of taking a surfactant association structure with aqueous continuous phase or both of aqueous continuous phase and oil continuous phase in the formulation.

摘要翻译： 本发明提供了可以容易地制备的新的二氧化硅复合胶囊，含有二氧化硅复合胶囊的组合物，以及外观透明性和使用质地优异的透明凝胶状组合物，特别是具有改进的透明凝胶状组合物 用作清洁剂时的清洁性能。 通过将能够在水中形成胶束的材料和在水溶液中具有特定结构的水溶性硅烷衍生物混合，可以在水性体系中容易地获得胶束/二氧化硅复合胶囊。 此外，通过混合表面活性剂，水，油和具有特定结构的水溶性硅烷衍生物，可以容易地得到内层的乳液粒子的周围用二氧化硅涂布的乳液/二氧化硅复合胶囊。 此外，通过将具有特定结构的水溶性硅烷衍生物掺入含有表面活性剂，油和水的配方中，可以获得表现出优异的外观透明度，使用质地和清洁性能的透明凝胶状组合物，以及 能够在制剂中具有含水连续相或水相连续相和油连续相的表面活性剂缔合结构。

公开(公告)号：US20090142565A1

公开(公告)日：2009-06-04

申请号：US12063502

申请日：2006-08-11

申请人： Shun Takahashi ,  Kazutami Sakamoto ,  Kouzou Hiwatari

发明人： Shun Takahashi ,  Kazutami Sakamoto ,  Kouzou Hiwatari

IPC分类号： B32B7/00 ,  C01B33/12

CPC分类号： C01B37/02 ,  B01J20/103 ,  B01J20/28083 ,  C01B33/1435 ,  C01B33/158

摘要： The object of the present invention is to provide a production method of mesoporous silica under electrolyte-free conditions by using a surfactant aggregate structure as a template and to provide mesoporous silica with a new shape, which could not be obtained in the past. It is possible to prepare mesoporous silica under electrolyte-free conditions by reacting a nonionic surfactant and a water-soluble silicate monomer with a specific structure under neutral conditions. In addition, a sheet-like mesoporous silica can be prepared in the use of a nonionic surfactant that can form a ribbon phase or a nematic phase in suitable temperature and concentration ranges in a water solution.

摘要翻译： 本发明的目的是通过使用表面活性剂聚集体结构作为模板，在无电解质条件下提供介孔二氧化硅的制造方法，并提供过去无法获得的新型的介孔二氧化硅。 通过在中性条件下使非离子表面活性剂和具有特定结构的水溶性硅酸盐单体反应，可以在无电解质条件下制备介孔二氧化硅。 此外，可以使用可以在适当的温度和浓度范围内在水溶液中形成带状或向列相的非离子表面活性剂制备片状介孔二氧化硅。

公开(公告)号：US20090149554A1

公开(公告)日：2009-06-11

申请号：US12063275

申请日：2006-08-11

申请人： Yuko Ishikawa ,  Katzutami Sakamoto ,  Toshikhiko Seki ,  Isao Yajima ,  Shun Takahashi ,  Kei Watanabe

发明人： Yuko Ishikawa ,  Katzutami Sakamoto ,  Toshikhiko Seki ,  Isao Yajima ,  Shun Takahashi ,  Kei Watanabe

IPC分类号： A61K47/24 ,  C07F7/28 ,  C07F7/02

CPC分类号： C07F7/045 ,  A61K9/0014 ,  A61K47/10 ,  C07C31/20

摘要： The object of the present invention is to provide a production method of water-soluble silane derivatives, the separation and purification of which are easy, and the reaction for which can be conducted under an industrially practicable temperature condition (under the temperature condition of 90° C. or lower) and to provide compounds with which solid gelatinous external preparations, with excellent stability against a temperature change and against an effect of additives and with excellent usability, can be prepared. The water-soluble silane derivative could be formed by the substitution reaction of a metal alkoxide with a polyhydric alcohol under the presence of a solid catalyst. According to this production method, the separation of the catalyst from the product is very easy, and the reaction can be carried out under the temperature condition of 90° C. or lower. The obtained water-soluble metal alcoholate derivative can satisfactory solidify an aqueous formulation of an external preparation by its blending thereinto. The obtained solid gelatinous external preparation has excellent stability against a temperature change and against the effect of additives. In addition, the external preparation is easily disintegrated during use; thus the usability such as easiness to be scooped up with fingers and spreadability during application is excellent.

摘要翻译： 本发明的目的是提供一种水溶性硅烷衍生物的制造方法，其分离纯化容易，其反应可以在工业上可行的温度条件下（在90℃的温度条件下进行） C.或更低），并且可以制备具有优异的耐温度变化稳定性和抗添加剂效果以及优异可用性的固体胶状外用制剂的化合物。 水溶性硅烷衍生物可以通过金属醇盐与多元醇在固体催化剂存在下的取代反应形成。 根据该制造方法，催化剂与产物的分离非常容易，反应可以在90℃以下的温度条件下进行。 所得到的水溶性金属醇化物衍生物可以通过其混合来使外用制剂的水性制剂充分固化。 所得固体凝胶状外用制剂对温度变化和添加剂的效果具有优异的稳定性。 此外，外用制剂在使用过程中容易分解; 因此在使用时易于用手指舀起的可用性和铺展性优异。

公开(公告)号：US07973102B2

公开(公告)日：2011-07-05

申请号：US10580336

申请日：2004-11-19

申请人： Shun Takahashi ,  Motoki Takata

发明人： Shun Takahashi ,  Motoki Takata

IPC分类号： C08K5/56 ,  C08K3/34

CPC分类号： C08K9/04 ,  B82Y30/00 ,  C08J5/005 ,  C08J2300/16 ,  C08J2367/04 ,  C08K9/06

摘要： A resin composition which reduces hydrolysis thereof and reduces the color change thereof at the time of heating and a resin molded object which reduces hydrolysis thereof and reduces quality change of content therein are provided. The resin composition includes a resin and an organically modified layered silicate in which a substituted silyl group having a substituted or non-substituted alkyl group bonds to a layered silicate. The resin molded object is obtained by molding a resin composition including a resin and an organically modified layered silicate in which a substituted silyl group having a substituted or non-substituted alkyl group bonds to a layered silicate.

摘要翻译： 提供一种降低其水解并降低其加热时的颜色变化的树脂组合物和降低其水解并降低其中的质量变化的树脂模制品。 树脂组合物包括树脂和有机改性的层状硅酸盐，其中具有取代或未取代的烷基的取代甲硅烷基与层状硅酸盐结合。 树脂成型体通过将含有取代或未取代的烷基的取代甲硅烷基与树脂和有机改性层状硅酸盐的树脂组合物成型为层状硅酸盐而得到。

公开(公告)号：US20060219651A1

公开(公告)日：2006-10-05

申请号：US10555388

申请日：2004-04-27

申请人： Shun Takahashi

发明人： Shun Takahashi

IPC分类号： B65D41/04 ,  B65D55/02

CPC分类号： B65D50/041

摘要： A safety container includes a container main body, an internal cap configured to be fit to an opening part of the container main body, and an external cap configured to be fit to the internal cap rotatably and moveably in upper and lower directions. The external cap is not rotated with the internal cap in a case where only the external cap is rotated in an opening direction. The external cap is rotated in a state where the external cap is pressed toward an internal cap side so that the external cap and the internal cap are engaged and the internal cap is opened and separated from the container main body. The safety container further comprises an inner ring having an end part where an engaging part engaged at a top part of the opening part of the container main body is provided and another end part where a slide contact part is provided. The internal cap is rotated with the external cap while the internal cap slides and contacts the slide contact part, by rotating the external cap in the opening direction in a state where the external cap is pressed toward the internal cap side until a rotation angle reaches a designated angle.

摘要翻译： 安全容器包括容器主体，构造成与容器主体的开口部配合的内盖，以及外壳，其被构造成可以上下方向可旋转地并且可移动地嵌合在内盖上。 在只有外盖在打开方向旋转的情况下，外盖不会与内盖一起旋转。 外盖在外盖被向内侧盖侧挤压的状态下旋转，使得外盖和内盖接合，内盖与容器主体分离。 安全容器还包括内环，其具有端部，其中设置有与容器主体的开口部的顶部接合的接合部，以及设置有滑动接触部的另一端部。 内盖在外罩被旋转的同时，内盖滑动并与滑动接触部接触，通过在将外盖向内盖侧按压的状态下使打开方向旋转，直到旋转角达到 指定角度

公开(公告)号：US07571825B2

公开(公告)日：2009-08-11

申请号：US10555388

申请日：2004-04-27

申请人： Shun Takahashi

发明人： Shun Takahashi

IPC分类号： B65D55/02

CPC分类号： B65D50/041

摘要： A safety container includes a container main body, an internal cap, and an external cap. The external cap is not rotated with the internal cap in a case where only the external cap is rotated in an opening direction. The external cap is rotated in a state where the external cap is pressed toward an internal cap side. The safety container includes an inner ring having an end part where an engaging part engaged at a top part of the opening part of the container main body is provided and another end part where a slide contact part is provided. The internal cap is rotated with the external cap while the internal cap slides and contacts the slide contact part, by rotating the external cap in a state where the external cap is pressed toward the internal cap side until a rotation angle reaches a designated angle.

摘要翻译： 安全容器包括容器主体，内盖和外盖。 在只有外盖在打开方向旋转的情况下，外盖不会与内盖一起旋转。 外盖在外盖被向内侧盖侧压的状态下旋转。 所述安全容器包括内圈，所述内圈具有端部，所述端部设有与所述容器主体的开口部的顶部接合的卡合部，以及设置有滑动接触部的另一端部。 通过在外盖被压向内盖侧的状态下旋转外盖，直到旋转角度达到指定角度，内盖在外部盖旋转的同时，内盖滑动并接触滑动接触部。

公开(公告)号：US20070093588A1

公开(公告)日：2007-04-26

申请号：US10580336

申请日：2004-11-19

申请人： Shun Takahashi ,  Motoki Takata

发明人： Shun Takahashi ,  Motoki Takata

IPC分类号： C08K9/04

CPC分类号： C08K9/04 ,  B82Y30/00 ,  C08J5/005 ,  C08J2300/16 ,  C08J2367/04 ,  C08K9/06

摘要： A resin composition which reduces hydrolysis thereof and reduces the color change thereof at the time of heating and a resin molded object which reduces hydrolysis thereof and reduces quality change of content therein are provided. The resin composition includes a resin and an organically modified layered silicate in which a substituted silyl group having a substituted or non-substituted alkyl group bonds to a layered silicate. The resin molded object is obtained by molding a resin composition including a resin and an organically modified layered silicate in which a substituted silyl group having a substituted or non-substituted alkyl group bonds to a layered silicate.

摘要翻译： 提供一种降低其水解并降低其加热时的颜色变化的树脂组合物和降低其水解并降低其中的质量变化的树脂模制品。 树脂组合物包括树脂和有机改性的层状硅酸盐，其中具有取代或未取代的烷基的取代甲硅烷基与层状硅酸盐结合。 树脂成型体通过将含有取代或未取代的烷基的取代甲硅烷基与树脂和有机改性层状硅酸盐的树脂组合物成型为层状硅酸盐而得到。

公开(公告)号：US5900127A

公开(公告)日：1999-05-04

申请号：US825866

申请日：1997-04-02

申请人： Masamori Iida ,  Yoshinori Nishiki ,  Takayuki Shimamune ,  Setsuro Ogata ,  Masashi Tanaka ,  Shuhei Wakita ,  Shun Takahashi

发明人： Masamori Iida ,  Yoshinori Nishiki ,  Takayuki Shimamune ,  Setsuro Ogata ,  Masashi Tanaka ,  Shuhei Wakita ,  Shun Takahashi

IPC分类号： C02F1/461 ,  C02F1/72 ,  C02F1/78 ,  C25B11/04 ,  C25B11/00

CPC分类号： C25B11/0478 ,  C02F1/46109 ,  C02F1/4618 ,  C02F1/722 ,  C02F1/78 ,  C02F2001/46138 ,  C02F2001/46161 ,  C02F2201/4611 ,  C02F2201/46115 ,  C02F2201/46195

摘要： An electrode for electrolysis comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. The electrode substance having an electrically conductive diamond structure may be a diamond containing an impurity selected from boron, phosphorus and graphite. Alternatively, the electrode substance having an electrically conductive diamond structure may comprise a composite of a diamond and an electrically conductive material. In a preferred embodiment, the electrode further comprises an interlayer comprising at least one of the carbide of a valve metal and silicon carbide disposed between the electrode base material and the electrode substance having an electrically conductive diamond structure. Also disclosed is an electrolytic cell having two chambers including an anode chamber and a cathode chamber partitioned by an ion-exchange membrane. At least one of the anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material. An electrolytic cell having three chambers is also disclosed, including an anode chamber, an intermediate chamber and a cathode chamber partitioned by ion-exchange membranes. At least one of an anode placed in the anode chamber and a cathode placed in the cathode chamber is an electrode comprising an electrode base material and an electrode substance having an electrically conductive diamond structure covering the surface of the electrode base material.

摘要翻译： 一种电解用电极，其特征在于，具有电极基材和覆盖所述电极基材表面的导电性金刚石结构的电极物质。 具有导电金刚石结构的电极物质可以是含有选自硼，磷和石墨的杂质的金刚石。 或者，具有导电金刚石结构的电极物质可以包括金刚石和导电材料的复合物。 在优选实施例中，电极还包括中间层，其包括设置在电极基材和具有导电金刚石结构的电极物质之间的阀金属和碳化硅的碳化物中的至少一种。 还公开了一种具有两个腔室的电解池，该腔室包括由离子交换膜隔开的阳极室和阴极室。 放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材和覆盖电极基材表面的导电金刚石结构的电极物质的电极。 还公开了一种具有三个室的电解池，包括由离子交换膜分隔的阳极室，中间室和阴极室。 放置在阳极室中的阳极中的至少一个和放置在阴极室中的阴极是包括电极基材的电极和具有覆盖电极母材表面的导电金刚石结构的电极物质。

公开(公告)号：US07981957B2

公开(公告)日：2011-07-19

申请号：US11628625

申请日：2005-06-08

申请人： Mitsuhiro Kawahara ,  Miho Nakai ,  Kazue Ueda ,  Akinobu Ogami ,  Shun Takahashi ,  Takahiro Kusumoto ,  Motoki Takata

发明人： Mitsuhiro Kawahara ,  Miho Nakai ,  Kazue Ueda ,  Akinobu Ogami ,  Shun Takahashi ,  Takahiro Kusumoto ,  Motoki Takata

IPC分类号： C08K3/34

CPC分类号： B65D65/466 ,  Y02W90/12 ,  Y02W90/13 ,  Y10T428/1379

摘要： A biodegradable gas barrier vessel comprising 100 parts of mass of a biodegradable polyester resin having a polylactic acid content of not less than 50% by mass and 0.1 to 10 parts by mass of a phyllosilicate. The degree of crystallization as measured by X-ray diffractometry is not less than 15%, and the coefficient of oxygen permeation as measured under conditions of 20° C. and relative humidity 90% is not more than 50 ml·mm/m2·day·MPa. Since the biodegradable polyester resin reinforced with the phyllosilicate has excellent heat resistance, the molded product can be heat treated at an elevated temperature. Such enhanced heat treatment conditions can further enhance the degree of crystallization of the polyester resin and thus can contribute to significantly improved gas barrier properties.

摘要翻译： 一种生物降解性气体阻隔容器，其包含100质量份的聚乳酸含量为50质量％以上的生物降解性聚酯树脂和0.1〜10质量份的页硅酸盐。 通过X射线衍射测定的结晶度为15％以上，在20℃，相对湿度90％的条件下测定的透氧系数为50毫升/毫米2·m 2·天以下 ·MPa。 由于用页硅酸盐增强的可生物降解的聚酯树脂具有优异的耐热性，所以可以在升高的温度下对成型体进行热处理。 这种增强的热处理条件可以进一步提高聚酯树脂的结晶度，因此有助于显着提高阻气性。