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公开(公告)号：US5830581A
公开(公告)日：1998-11-03
申请号：US843595
申请日：1997-04-16
CPC分类号： B05D5/068 , Y10T428/31692 , Y10T428/31699 , Y10T428/31855 , Y10T428/31935
摘要： The present invention provides a method for forming a multi-layer coating film by applying a colored clear coating (B) containing a color pigment and/or a glittering material, on the film of a leafing type aluminum flake-containing metallic coating (A), wherein the colored clear coating (B) also contains a polymer formed from an unsaturated monomer having a phosphoric acid group represented by --O--PO(OH)(R.sub.1) (wherein R.sub.1 is a hydroxyl group, a phenyl group or a C.sub.1-20 alkyl group) and a hydroxyl group-containing unsaturated monomer. The method can form a multi-layer coating film improved in interlayer adhesivity between the metallic coating film and the colored clear coating film, without reducing the excellent effects and metallic feeling provided by a metallic coating film containing leafing type aluminum flake.
摘要翻译： 本发明提供一种通过将含有着色颜料和/或闪光材料的着色透明涂层（B）涂覆在含叶片状铝箔金属涂层（A）的膜上形成多层涂膜的方法， ，其中着色透明涂层（B）还含有由具有由-O-PO（OH）（R1）表示的磷酸基的不饱和单体形成的聚合物（其中R1是羟基，苯基或C1- 20烷基）和含羟基的不饱和单体。 该方法可以形成改善金属涂膜和着色透明涂膜之间的层间粘合性的多层涂膜，而不会降低由含叶片型铝片的金属涂膜提供的优异的效果和金属感。
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公开(公告)号：US5780113A
公开(公告)日：1998-07-14
申请号：US833118
申请日：1997-04-04
摘要： The present invention provides a method for forming a multi-layer coating film by applying a clear coating (B) on the film of a leafing type aluminum flake-containing metallic coating (A), which method comprises forming a film of the metallic coating (A), curing the film, applying thereon a composition (C) containing a polymer formed from an unsaturated monomer having a phosphoric acid group represented by --O--PO(OH)(R.sub.1) (wherein R.sub.1 is a hydroxyl group, a phenyl group or a C.sub.1-20 alkyl group) and a hydroxyl group-containing unsaturated monomer, and then applying the clear coating (B) on the film of the composition (C). The method can form a multi-layer coating film improved in interlayer adhesivity between the metallic coating film and the clear coating film, without reducing the excellent effects and metallic feeling provided by a metallic coating film containing leafing type aluminum flake.
摘要翻译： 本发明提供了一种通过在含叶片状的含铝薄片的金属涂层（A）的薄膜上涂布透明涂层（B）来形成多层涂膜的方法，该方法包括形成金属涂层的膜 A），固化该膜，在其上涂覆含有由具有由-O-PO（OH）（R1）表示的磷酸基的不饱和单体形成的聚合物的组合物（C）（其中R1是羟基，苯基 或C 1-20烷基）和含羟基的不饱和单体，然后将透明涂层（B）涂布在组合物（C）的膜上。 该方法可以形成改善金属涂膜和透明涂膜之间层间粘合性的多层涂膜，而不会降低由含叶片型铝片的金属涂膜提供的优异的效果和金属感。
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公开(公告)号：US5587426A
公开(公告)日：1996-12-24
申请号：US024774
申请日：1993-03-02
CPC分类号： C08G18/8061 , C08G18/10 , C08G18/6229 , C08G18/6254 , C08G18/728
摘要： The present invention provides:(1) a self-crosslinking resin (I) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and an acrylic resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and(2) a self-crosslinking resin (II) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the acrylic resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).
摘要翻译： 本发明提供：（1）分子中具有封端异氰酸酯基和羟基的自交联树脂（I），其特征在于，所述树脂由具有至少两个游离异氰酸酯基的乙烯基聚合物（A） 在分子中具有至少两个羟基的丙烯酸树脂（B），其中树脂（B）的一些羟基与聚合物（A）的一些游离异氰酸酯基团反应，然后使 具有所有剩余的游离异氰酸酯基团的封端剂，和（2）分子中具有封端的异氰酸酯基和羟基的自交联树脂（II），其特征在于，树脂由具有 通过使树脂（B）的一些羟基与聚合物中的所有游离异氰酸酯基团反应，分子中的游离异氰酸酯基和封端的异氰酸酯基和分子中具有至少两个羟基的丙烯酸树脂（B） （C）。
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公开(公告)号：US5346958A
公开(公告)日：1994-09-13
申请号：US46987
申请日：1993-04-16
申请人： Yoshiyuki Yukawa , Motoshi Yabuta , Akimasa Nakahata , Yuzo Miyamoto , Masaaki Kobayashi , Naruhito Ueno
发明人： Yoshiyuki Yukawa , Motoshi Yabuta , Akimasa Nakahata , Yuzo Miyamoto , Masaaki Kobayashi , Naruhito Ueno
IPC分类号： B05D1/36 , C08L25/14 , C08L61/20 , C09D125/00 , C09D125/08 , C09D133/04 , C09D133/06 , C09D161/20 , C09D175/04 , C08F8/30 , C08F8/32 , C08L75/04
CPC分类号： C09D125/08 , C08L2205/18 , C08L25/14 , C08L61/20 , Y10T428/29 , Y10T428/31855 , Y10T428/31862
摘要： A curable top coating composition essentially including(A) a hydroxyl-containing vinyl type resin containing 45 to 55% by weight of styrene monomer as a copolymerized unit of the resin,(B) at least one member selected from among amino resins and (blocked) polyisocyanate compounds, and(C) a microparticulate polymer having an average particle diameter within the range of 0.01 to 1 .mu.m and containing 40 to 60% by weight of styrene monomer as a copolymerized component of each particle,wherein the cured film from the coating composition contains the styrene-derived benzene ring in a proportion of 13 to 40% by weight of the total resin solids;a coating method using the above coating composition, anda coated article obtainable by using the above coating composition.
摘要翻译： 一种可固化顶涂层组合物，其基本上包括（A）含有45至55重量％的作为树脂的共聚单元的苯乙烯单体的含羟基的乙烯基型树脂，（B）选自氨基树脂和（封端的）中的至少一种 ）多异氰酸酯化合物，（C）平均粒径为0.01〜1μm的微粒聚合物，含有40〜60重量％的作为各粒子的共聚成分的苯乙烯单体，其中，来自 涂料组合物含有苯乙烯衍生的苯环的比例为总树脂固体重量的13-40％ 使用上述涂料组合物的涂布方法和使用上述涂料组合物可获得的涂布制品。
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公开(公告)号：US5296529A
公开(公告)日：1994-03-22
申请号：US100994
申请日：1993-08-03
CPC分类号： C09D175/06 , C08G18/0823 , C08G18/10 , C08G18/4263 , C08G18/728 , C08G18/8061
摘要： The present invention provides (1) a self-crosslinking resin (I) having a carboxyl group, a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and a polyester resin (B) having at least two hydroxyl groups and at least one carboxyl group in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and (2) a self-crosslinking resin (II) having a carboxyl group, a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the polyester resin (B) having at least two hydroxyl groups and at least one carboxyl group in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).
摘要翻译： 本发明提供（1）在分子中具有羧基，封端异氰酸酯基和羟基的自交联树脂（I），其特征在于，所述树脂由具有至少两个 分子中的游离异氰酸酯基和分子中具有至少两个羟基和至少一个羧基的聚酯树脂（B），其中树脂（B）的一些羟基与一部分游离异氰酸酯基团 聚合物（A），然后使阻挡剂与剩余的游离异氰酸酯基团反应，和（2）分子中具有羧基，封端异氰酸酯基和羟基的自交联树脂（II），其特征在于 树脂由分子中具有游离异氰酸酯基和封端异氰酸酯基的乙烯基聚合物（C）制备，聚酯树脂（B）在分子中具有至少两个羟基和至少一个羧基 用聚合物（C）的全部游离异氰酸酯基团将树脂（B）的一些羟基封闭。
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公开(公告)号：US5296551A
公开(公告)日：1994-03-22
申请号：US97236
申请日：1993-07-27
IPC分类号： C08G18/10 , C08G18/42 , C08G18/72 , C08G18/80 , C08G18/81 , C09D175/00 , C09D175/06 , C08G81/02
CPC分类号： C08G18/728 , C08G18/10 , C08G18/42
摘要： The present invention provides(1) a self-crosslinking resin (I) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and a polyester resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and(2) a self-crosslinking resin (II) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the polyester resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).
摘要翻译： 本发明提供（1）在分子中具有封端异氰酸酯基和羟基的自交联树脂（I），其特征在于，所述树脂由具有至少两个游离异氰酸酯基的乙烯基聚合物（A） 所述分子和通过使所述树脂（B）的一些羟基与所述聚合物（A）的一些游离异氰酸酯基团反应而在所述分子中具有至少两个羟基的聚酯树脂（B）反应， 具有所有剩余的游离异氰酸酯基团的试剂，和（2）在分子中具有封端的异氰酸酯基和羟基的自交联树脂（II），其特征在于，树脂由乙烯基聚合物（C）制备， 游离异氰酸酯基和分子内的封端异氰酸酯基和分子中具有至少两个羟基的聚酯树脂（B），其中树脂（B）的一些羟基与聚合物的所有游离异氰酸酯基反应 r（C）。
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公开(公告)号：US5449717A
公开(公告)日：1995-09-12
申请号：US42517
申请日：1993-04-05
IPC分类号： C08F214/18 , C08F14/18 , C08F290/00 , C08F299/08 , C08L61/20 , C09D127/12 , C09D137/00 , C09D143/04 , C09D155/00 , C09D157/00 , C09D161/20 , C08L43/04 , C08L61/00
CPC分类号： C09D143/04 , C08L61/20
摘要： A coating composition which consists essentially of:(A) a copolymer comprising 5 to 40 wt. % of an alkoxysilane-containing vinyl monomer which is a compound represented by the formula ##STR1## wherein A is ##STR2## R.sub.1 is a hydrogen atom or methyl group, R.sub.2 is a bivalent aliphatic saturated hydrocarbon group having 1 to 6 carbon atoms, R.sub.3 and R.sub.4 are the same or different and are each a phenyl group, alkyl group having 1 to 6 carbon atoms or alkoxy group having 1 to 10 carbon atoms, R.sub.5 is an alkyl group having 1 to 10 carbon atoms, m is 0 or 1, and n is an integer of 1 to 100, 5 to 50 wt. % of a hydroxyl-containing vinyl monomer and 30 to 70 wt. % of a fluorine-containing vinyl monomer, and (B) an amino resin in an amount of 5 to 50 wt. % based on the total amount of solids in the copolymer (A) and the amino resin (B).
摘要翻译： 一种涂料组合物，其基本上由以下组成：（A）包含5至40wt。 ％为由式（I）表示的化合物的烷氧基硅烷的乙烯基单体，其中A为氢原子或甲基，R 2为具有1至6个碳原子的二价脂族饱和烃基 原子，R 3和R 4相同或不同，分别为苯基，碳原子数1〜6的烷基或碳原子数1〜10的烷氧基，R 5为碳原子数1〜10的烷基，m为0 或1，n为1〜100的整数，5〜50重量％ ％的含羟基的乙烯基单体和30至70wt。 ％的含氟乙烯基单体，和（B）5〜50重量％的氨基树脂。 基于共聚物（A）和氨基树脂（B）中的固体总量的％。
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公开(公告)号：US5274045A
公开(公告)日：1993-12-28
申请号：US842565
申请日：1992-02-27
申请人： Yoshiyuki Yukawa , Motoshi Yabuta , Yasushi Nakao
发明人： Yoshiyuki Yukawa , Motoshi Yabuta , Yasushi Nakao
IPC分类号： C08G18/67 , C08F290/06 , C08F290/14 , C08G18/72 , C08G18/80 , C09D175/04 , C09D175/14 , C09J175/00 , C09J175/04
CPC分类号： C08F290/147 , C08G18/728
摘要： A self-crosslinkable resin useful as, for example, adhesive compositions and coating compositions. The resin contains complementary reactive groups, that is, a blocked isocyanate group and a hydroxyl group, in the same molecule. The resin is prepared by reacting a hydroxy-containing vinyl monomer with some isocyanate groups on the skeleton of a vinyl polymer having at least two isocyanate groups in the molecule so to introduce a polymerizable double bond into the polymer, and subsequently completely blocking the isocyanate group(s) remaining on the polymer skeleton with a blocking agent, or vice versa. Thereafter an unsaturated monomer component consisting essentially of a hydroxyl-containing vinyl monomer is polymerized with the polymerizable double bond introduced.
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公开(公告)号：US5424369A
公开(公告)日：1995-06-13
申请号：US899984
申请日：1992-06-17
申请人： Yoshiyuki Yukawa , Motoshi Yabuta , Yasushi Nakao
发明人： Yoshiyuki Yukawa , Motoshi Yabuta , Yasushi Nakao
IPC分类号： C08G18/08 , C08G18/62 , C08G18/72 , C08G18/80 , C08G18/81 , C08F265/06 , C08F271/00
CPC分类号： C08G18/8175 , C08G18/0814 , C08G18/6266 , C08G18/6283 , C08G18/728 , C08G18/8061
摘要： A self-crosslinking resin comprising a resin containing a blocked isocyanate group, and a resin containing a hydroxyl group, and a tertiary amino group and/or a quaternary ammonium group and attached to the resin by a urethane bond.The self-crosslinking resins are useful for adhesive compositions and coating compositions of the aqueous type.
摘要翻译： 包含含有封端异氰酸酯基团的树脂和含有羟基的树脂，叔氨基和/或季铵基并通过氨基甲酸酯键附着在树脂上的自交联树脂。 自交联树脂可用于水性类型的粘合剂组合物和涂料组合物。
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公开(公告)号：US5414055A
公开(公告)日：1995-05-09
申请号：US64650
申请日：1993-05-21
申请人： Yoh Sugimura , Motoshi Yabuta , Yoshiyuki Yukawa , Yasuhiro Fujii
发明人： Yoh Sugimura , Motoshi Yabuta , Yoshiyuki Yukawa , Yasuhiro Fujii
IPC分类号： C08G18/62 , C08G18/10 , C08G18/63 , C08G18/72 , C09D175/00 , C09D175/04 , C08F283/04
CPC分类号： C08G18/728 , C08G18/10 , C08G18/633
摘要： (1) A coating resin composition consisting essentially of a self-crosslinking resin (I) having at least one hydroxyl group and at least one blocked isocyanate group in the molecule wherein the resin (I) is prepared by reacting some of the free isocyanate groups of a vinyl polymer (A) having at least two free isocyanate groups in the molecule with some of the hydroxyl groups of a polyolefin resin (B) having at least two hydroxyl groups in the molecule, and subsequently reacting a blocking agent with the remaining free isocyanate groups, and (2) a coating resin composition consisting essentially of a self-crosslinking resin (II) having at least one hydroxyl group and at least one blocked isocyanate group in the molecule wherein the resin (II) is prepared by reacting all free isocyanate groups of a vinyl polymer (C) having at least one free isocyanate group and at least one blocked isocyanate group in the molecule with some of the hydroxyl groups of a polyolefin resin (B) having at least two hydroxyl groups in the molecule.
摘要翻译： （1）一种基本上由分子中具有至少一个羟基和至少一个封端异氰酸酯基的自交联树脂（I）组成的涂料树脂组合物，其中树脂（I）是通过一些游离异氰酸酯基团 的分子中具有至少两个游离异氰酸酯基团的乙烯基聚合物（A），其中在分子中具有至少两个羟基的聚烯烃树脂（B）的一些羟基，然后使封闭剂与剩余的游离的 异氰酸酯基，和（2）主要由在分子中具有至少一个羟基和至少一个封端的异氰酸酯基的自交联树脂（II）组成的涂料树脂组合物，其中树脂（II）通过使全部自由基 在分子中具有至少一个游离异氰酸酯基和至少一个封端异氰酸酯基的乙烯基聚合物（C）的异氰酸酯基团，其中一些聚烯烃树脂（B）的一些羟基具有至少 分子中有两个羟基。
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