公开(公告)号：US20090312450A1

公开(公告)日：2009-12-17

申请号：US11996505

申请日：2006-07-26

申请人： Charles A. Martin ,  Aaron W. Sanders ,  Jimmy D. Earls ,  Kurt D. Olson ,  John R. Briggs ,  Alan K. Schrock ,  Zenon Lysenko ,  David A. Babb

发明人： Charles A. Martin ,  Aaron W. Sanders ,  Jimmy D. Earls ,  Kurt D. Olson ,  John R. Briggs ,  Alan K. Schrock ,  Zenon Lysenko ,  David A. Babb

IPC分类号： C08G18/34 ,  C08G18/32 ,  C07C229/02

CPC分类号： C08G18/3825 ,  C07C235/08 ,  C08G18/36 ,  C08G2101/0025 ,  C08G2101/005

摘要： Polyurethanes, and rigid polyurethane foams in particular, are made using certain amides of modified fatty acids. The fatty acid groups are substituted hydroxymethyl, N-hydroxyalkyl aminoalkyl or hydroxy-substituted ester groups. The amide portion of the molecule contains hydroxyalkyl or other hydroxyl-substituted organic groups bonded to the amide nitrogen.

摘要翻译： 聚氨酯和硬质聚氨酯泡沫特别是使用某些改性脂肪酸酰胺制成的。 脂肪酸基团是取代的羟甲基，N-羟基烷基氨基烷基或羟基取代的酯基。 分子的酰胺部分含有与酰胺氮键合的羟基烷基或其它羟基取代的有机基团。

公开(公告)号：US20100298610A1

公开(公告)日：2010-11-25

申请号：US12565446

申请日：2009-09-23

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas ,  Jeffrey S. Kanel

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas ,  Jeffrey S. Kanel

IPC分类号： C07C47/02

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。

公开(公告)号：US20100048753A1

公开(公告)日：2010-02-25

申请号：US12518432

申请日：2007-12-03

申请人： Wei-Jun Peng ,  David A. Babb ,  Aaron W. Sanders ,  Christopher W. Derstine ,  Jorge Jimenez ,  Zenon Lysenko ,  Kurt D. Olson ,  Joe D. Phillips ,  Brian M. Roesch ,  Alan K. Schrock

发明人： Wei-Jun Peng ,  David A. Babb ,  Aaron W. Sanders ,  Christopher W. Derstine ,  Jorge Jimenez ,  Zenon Lysenko ,  Kurt D. Olson ,  Joe D. Phillips ,  Brian M. Roesch ,  Alan K. Schrock

IPC分类号： C08G18/00 ,  C07C53/00 ,  C07C69/34

CPC分类号： C08G18/36 ,  C08G2190/00

摘要： An aldehyde composition containing a mixture of mono-formyl-, diformyl-, and triformyl-substituted fatty acids and/or fatty acid esters having a di-aldehyde/tri-aldehyde weight ratio of less than 5/1 and an average functionality number from greater than 0.96 to less than 1.26. A monomer alcohol composition containing a mixture of mono-hydroxymethyl-, dihydroxymethyl-, and trihydroxymethyl-substituted fatty acids and/or fatty acid esters having a diol/triol weight ratio of less than 5/1 and an average functionality number from greater than 0.90 to less than 1.20. The monomer alcohol can be converted into an oligomeric polyol for use in the manufacture of polyurethane flexible foams.

摘要翻译： 含有单甲酰基，二甲酰基和三甲酰基取代的脂肪酸和/或二醛/三醛重量比小于5/1的​​平均官能度数和/或脂肪酸酯的混合物的醛组合物， 大于0.96小于1.26。 含有单羟甲基 - ，二羟甲基 - 和三羟甲基取代的脂肪酸和/或二醇/三醇重量比小于5/1并且平均官能度数大于0.90的脂肪酸酯的混合物的单体醇组合物 小于1.20。 单体醇可以转化为用于制备聚氨酯柔性泡沫的低聚多元醇。

公开(公告)号：US08124812B2

公开(公告)日：2012-02-28

申请号：US12565446

申请日：2009-09-23

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C47/02 ,  C07C45/50 ,  C07C29/14 ,  C07C59/147

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。

公开(公告)号：US07615658B2

公开(公告)日：2009-11-10

申请号：US10551854

申请日：2004-04-22

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C51/367 ,  C07C27/00

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxymethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foam.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或具有以下重量组成的脂肪酸酯的混合物：大于约10至小于约95％的一元醇（单（羟甲基）}， 大于约1至小于约65％的二醇{二（羟甲基）}，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯; 优选大于约3至小于约35％的饱和物; 并且优选小于约10％的不饱和物。 醇组合物可以转化为用于制造聚氨酯板坯柔性泡沫的低聚多元醇。

公开(公告)号：US07960444B2

公开(公告)日：2011-06-14

申请号：US10553767

申请日：2004-04-21

申请人： Zenon Lysenko ,  Alan K. Schrock ,  David A. Babb ,  Aaron Sanders ,  John Tsavalas ,  H. Ray Jouett ,  Larry Chambers ,  Charles Keillor ,  James H. Gilchrist

发明人： Zenon Lysenko ,  Alan K. Schrock ,  David A. Babb ,  Aaron Sanders ,  John Tsavalas ,  H. Ray Jouett ,  Larry Chambers ,  Charles Keillor ,  James H. Gilchrist

IPC分类号： C08G18/00 ,  C08G18/04 ,  C07C57/02

CPC分类号： C08G18/36 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4288 ,  C08G18/4804 ,  C08G18/4841 ,  C08G18/4891 ,  C08G18/6696 ,  C08G2101/0008 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

摘要： Polyols useful in the manufacture of polyurethanes are disclosed. The polyols are prepared by reacting a vegetable oil based (hydroxymethyl containing) monomer with a polyol, polyamine or aminoalcohol under vacuum.

摘要翻译： 公开了可用于制造聚氨酯的多元醇。 通过在真空下使基于植物油的（含羟甲基）单体与多元醇，多胺或氨基醇反应来制备多元醇。

公开(公告)号：US08133930B2

公开(公告)日：2012-03-13

申请号：US10554633

申请日：2004-04-23

申请人： Eugene Paul Wiltz, Jr. ,  Zenon Lysenko ,  Fabio Aguirre ,  Aaron Sanders ,  John Tsavalas ,  David A. Babb ,  Alan K Schrock

发明人： Eugene Paul Wiltz, Jr. ,  Zenon Lysenko ,  Fabio Aguirre ,  Aaron Sanders ,  John Tsavalas ,  David A. Babb ,  Alan K Schrock

IPC分类号： C08G18/28

CPC分类号： C08G18/4288 ,  C08G18/4018 ,  C08G18/4072 ,  C08G18/4244 ,  C08G18/632 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The polyester is prepared in a multi-step process from animal or vegetable fats, by recovering the constitutent fatty acids, hydroformylating carbon-carbon double bonds in the fatty acids and reducing to form hydroxymethyl groups, and then forming a polyester by reaction with an initiator compound.

摘要翻译： 柔性聚氨酯泡沫通过使多异氰酸酯与高当量多元醇反应制备。 高当量多元醇的至少一部分是含有羟甲基的聚酯。 通过回收组分脂肪酸，在脂肪酸中加氢甲酰化碳 - 碳双键并还原形成羟甲基，然后通过与引发剂反应形成聚酯，从动物或植物脂肪的多步法制备聚酯 复合。

公开(公告)号：US07750108B2

公开(公告)日：2010-07-06

申请号：US11918633

申请日：2006-04-27

申请人： Zenon Lysenko ,  David A. Babb ,  Kenneth J. Stutts ,  Robbyn Prange ,  Min Zhang ,  Alan K. Schrock

发明人： Zenon Lysenko ,  David A. Babb ,  Kenneth J. Stutts ,  Robbyn Prange ,  Min Zhang ,  Alan K. Schrock

IPC分类号： C08G63/00

CPC分类号： C08G63/676 ,  C08G18/4018 ,  C08G18/4244 ,  C08G18/4288 ,  C08G18/4825 ,  C08G18/485 ,  C08G18/4891 ,  C08G18/7621 ,  C08G2101/0008 ,  C08G2101/0083

摘要： Copolyesters containing secondary hydroxyl groups are useful polyols for manufacturing polyurethanes. These can be prepared by reacting a secondary hydroxyl-containing fatty acid or ester thereof with an initiator containing hydroxyl and/or primary or secondary amino groups. A copolyester of particular interest includes a poly(ethylene oxide) segment derived from a poly(ethylene oxide) initiator.

摘要翻译： 含有仲羟基的共聚酯是制造聚氨酯的有用的多元醇。 这些可以通过使含仲羟基的脂肪酸或其酯与含有羟基和/或伯或仲氨基的引发剂反应来制备。 特别感兴趣的共聚酯包括衍生自聚（环氧乙烷）引发剂的聚（环氧乙烷）链段。

公开(公告)号：US20090264546A1

公开(公告)日：2009-10-22

申请号：US11918633

申请日：2006-04-27

申请人： Zenon Lysenko ,  David A. Babb ,  Kenneth J. Stutts ,  Robbyn Prange ,  Min Zhang ,  Alan K. Schrock

发明人： Zenon Lysenko ,  David A. Babb ,  Kenneth J. Stutts ,  Robbyn Prange ,  Min Zhang ,  Alan K. Schrock

IPC分类号： C08G18/30 ,  C08G63/685 ,  C08G63/664

CPC分类号： C08G63/676 ,  C08G18/4018 ,  C08G18/4244 ,  C08G18/4288 ,  C08G18/4825 ,  C08G18/485 ,  C08G18/4891 ,  C08G18/7621 ,  C08G2101/0008 ,  C08G2101/0083

摘要： Copolyesters containing secondary hydroxyl groups are useful polyols for manufacturing polyurethanes. These can be prepared by reacting a secondary hydroxyl-containing fatty acid or ester thereof with an initiator containing hydroxyl and/or primary or secondary amino groups. A copolyester of particular interest includes a poly(ethylene oxide) segment derived from a poly(ethylene oxide) initiator.

摘要翻译： 含有仲羟基的共聚酯是制造聚氨酯的有用的多元醇。 这些可以通过使含仲羟基的脂肪酸或其酯与含有羟基和/或伯或仲氨基的引发剂反应来制备。 特别感兴趣的共聚酯包括衍生自聚（环氧乙烷）引发剂的聚（环氧乙烷）链段。

公开(公告)号：US08178645B2

公开(公告)日：2012-05-15

申请号：US12668609

申请日：2008-07-10

申请人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

发明人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

IPC分类号： C08G18/42 ,  C08G63/00 ,  C08G18/71

CPC分类号： C08G18/4288 ,  C08G18/4269 ,  C08G18/4277 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/06

摘要： A polyester polyol, referred to hereinafter as a MHMS polyol comprises fatty acid based mer units wherein at least about 80 weight percent of the fatty acid based mer units are from methyl 9 (10) hydroxymethylstearate, or is prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof and which has an average hydroxyl functionality of from 1.5 to 4. A reaction product, referred to herein after as MHMS alkoxysilane prepolymer, is produced from at least one such MHMS polyol and at least one isocyanate functional silane. This prepolymer is moisture cured to form a silylated MHMS polymer.

摘要翻译： 以下称为MHMS多元醇的聚酯多元醇包括脂肪酸基mer单元，其中至少约80重量％的脂肪酸​​基mer单元为9（10）羟甲基硬脂酸甲酯，或由具有脂肪酸或 至少约80重量％的油酸或其酯，并且其平均羟基官能度为1.5-4的脂肪酸酯。本文中称为MHMS烷氧基硅烷预聚物的反应产物由至少一种这样的MHMS 多元醇和至少一种异氰酸酯官能的硅烷。 将该预聚物水分固化以形成甲硅烷基化的MHMS聚合物。