Polyvinylpyrridinium derivatives as anti-dye transfer agents

    公开(公告)号:USRE39450E1

    公开(公告)日:2006-12-26

    申请号:US10369911

    申请日:2003-02-20

    IPC分类号: C11D3/37 C08F228/02

    摘要: A water-soluble polyvinylpyrridinium derivative containing a quaternary nitrogen and an anionic moiety selected from a sulfonate and/or a carboxylate functionality, said polyvinylpyrridinium derivative having the structure wherein a is a repeating unit of 1 to 100; b is a repeating unit of 0 to 99; c is a repeating unit of 0 to 99; d is a repeating unit of 0 1 to 99; R is selected from the group consisting of (CR1R2)m1, benzene, and substituted benzene; Y is selected from the group consisting of (CR3R4)m2, benzene, and substituted benzene; substituted benzene is independently a benzene substituted with a group selected from the group consisting of amino moeity moiety, nitro moiety, halogen moiety, and combinations thereof; Z is derived from an ethylenically unsaturated monomer; m1 and m2 are independently 0 to 10; M+ is independently a cation wherein M is selected from the group consisting of hydrogen, ammonia, alkali metals, alkaline earth metals, zinc, copper, organic amines, amino acids, and amino saccharides; R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, hydroxyl, alkyl having C1 to C6, aryl having C6 to C18, and alkaryl having C7 to C18; and X− is independently a halide, with the proviso that if Y is benzene or substituted benzene then a is 0 to 99 and b is 1 to 100. The polyvinylpyrridinium derivatives inhibit dye transfer in detergent compositions having a high level of anionic surfactants without adversely affecting stain or soil removal or soil redeposition.

    Catalyzed water-soluble/dispersible reactive derivatives of polyimido compounds for modifying proteinaceous substrates
    8.
    发明授权
    Catalyzed water-soluble/dispersible reactive derivatives of polyimido compounds for modifying proteinaceous substrates 失效
    用于改性蛋白质底物的聚酰亚胺化合物的催化水溶性/可分散的活性衍生物

    公开(公告)号:US06306378B1

    公开(公告)日:2001-10-23

    申请号:US09287900

    申请日:1999-04-07

    IPC分类号: A61K711

    摘要: This invention relates to a two-part system useful for treating proteinaceous substrates. The two-part system has a first part comprising a water-soluble/dispersible reactive polyimido compound and a second part comprising a nucleophilic catalytic agent. The polyimido compounds may be selected from the group consisting of polysuccinimide compounds, polyglutimide compounds, and copolymers of thereof. The polyimido compound may also comprise a functionalizing moiety that provides functionality to the polyimido compound and is preferably derived from a nucleophilic moiety selected from the group consisting of amines, alcohols, phenols, thiols, and carboxylates; and a water-solubilizing/dispersing moiety that provides water-solubility and/or water-dispersibility to the polyimido compound and is preferably derived from a nucleophilic moiety selected from the group consisting of amines, alcohols, phenols, thiols, and carboxylates. The nucleophilic catalytic agent serves to catalyze nuclephilic substitution of the polyimido compound by the proteinaceous substrate. The invention also pertains to a method for treating a proteinaceous substrate with the two-part system and to a composition comprising a mixture of the polyimido compound and the nucleophilic catalytic agent.

    摘要翻译: 本发明涉及可用于处理蛋白质底物的两部分系统。 两部分系统具有包含水溶性/分散性反应性聚酰亚胺化合物的第一部分和包含亲核催化剂的第二部分。 聚酰亚胺化合物可以选自聚琥珀酰亚胺化合物,聚戊二酰亚胺化合物及其共聚物。 聚酰亚胺化合物还可以包含向聚亚胺化合物提供官能团的官能化部分,并且优选衍生自选自胺,醇,酚,硫醇和羧酸酯的亲核部分; 以及向聚酰亚胺化合物提供水溶性和/或水分散性的水溶性/分散部分,并且优选衍生自选自胺,醇,酚,硫醇和羧酸盐的亲核部分。 亲核催化剂用于催化蛋白质底物对聚酰亚胺化合物的亲核取代。 本发明还涉及用两部分系统处理蛋白质底物的方法以及包含聚酰亚胺化合物和亲核催化剂的混合物的组合物。