公开(公告)号：US4904453A

公开(公告)日：1990-02-27

申请号：US214582

申请日：1988-07-01

Applicant: Umberto Zardi

Inventor： Umberto Zardi

IPC: B01J8/04 ,  C01C1/04 ,  C07C29/152

CPC classification number: C01C1/0423 ,  B01J8/0415 ,  B01J8/0434 ,  B01J8/0453 ,  B01J8/0469 ,  B01J8/0496 ,  C07C29/152 ,  B01J2208/00194 ,  Y02P20/52 ,  Y10T29/49826

Abstract: The energy consumption of conventional reactors for heterogeneous synthesis, e.g., ammonia synthesis and methanol synthesis, wherein the synthesis gas flows substantially axially through catalyst beds, is substantially reduced by inserting in at least one catalyst bed: two concentric cylindrical substantially perforated walls to laterally delimit the bed; a bottom closure between these walls; and optionally a diaphragm on top of the bed. Optionally also, a catalyst granulometry gradient may be employed in the upper part of the bed. An upper minor portion of at least one of the cylindrical walls may be unperforated. The synthesis gas now traverses the bed substantially radially.

公开(公告)号：US07632778B2

公开(公告)日：2009-12-15

申请号：US10586320

申请日：2005-01-17

Applicant: Klaus Wanninger ,  Peter Britz ,  Nicolas Zartenar

Inventor： Klaus Wanninger ,  Peter Britz ,  Nicolas Zartenar

IPC: B01J21/00 ,  B01J21/02 ,  B01J21/04 ,  B01J21/06 ,  B01J8/00 ,  B01J23/00 ,  B01J23/10 ,  B01J23/38 ,  B01J23/40 ,  B01J23/46 ,  B01J23/48 ,  B01J23/54 ,  B01J23/56 ,  B01J23/63 ,  B01J23/70 ,  B01J23/76

CPC classification number: B01J8/0496 ,  B01D53/864 ,  B01J8/0434 ,  B01J19/0013 ,  B01J19/2485 ,  B01J23/6567 ,  B01J29/22 ,  B01J35/0006 ,  B01J37/0225 ,  B01J37/0246 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2219/00157 ,  B01J2219/00159 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0288 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0816 ,  C01B2203/0894 ,  C01B2203/1029 ,  C01B2203/1294 ,  Y02P20/52

Abstract: An apparatus for producing hydrogen, which comprises: a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products; b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); and c. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization, is described. In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).

Abstract translation: 一种生产氢气的装置，包括：a。 具有重整催化剂以将气态或可汽化的烃和水转化成氢气，一氧化碳和其它重整产物的加热蒸汽重整级（1） b。 在蒸汽重整阶段下游的至少一个阶段，用于催化转化离开蒸汽重整阶段（变换阶段）的氢，一氧化碳和过量蒸汽的混合物（2）; 和c。 描述了通过选择性甲烷化催化降低转化产物的残留一氧化碳含量的转移阶段下游的精细纯化阶段（3）。 在该装置中，变速级（2）和精净化级（3）构成为一体式中空体（放热催化剂级）。

公开(公告)号：US20070172401A1

公开(公告)日：2007-07-26

申请号：US10586320

申请日：2005-01-17

Applicant: Klaus Wanninger ,  Peter Britz ,  Nicolas Zartenar

Inventor： Klaus Wanninger ,  Peter Britz ,  Nicolas Zartenar

IPC: B01J8/04 ,  B01J23/00

CPC classification number: B01J8/0496 ,  B01D53/864 ,  B01J8/0434 ,  B01J19/0013 ,  B01J19/2485 ,  B01J23/6567 ,  B01J29/22 ,  B01J35/0006 ,  B01J37/0225 ,  B01J37/0246 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2219/00157 ,  B01J2219/00159 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0288 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0816 ,  C01B2203/0894 ,  C01B2203/1029 ,  C01B2203/1294 ,  Y02P20/52

Abstract: An apparatus for producing hydrogen, which comprises: a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products; b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); and c. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization, is described. In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).

Abstract translation: 一种生产氢气的装置，包括：a。 具有重整催化剂以将气态或可汽化的烃和水转化成氢气，一氧化碳和其它重整产物的加热蒸汽重整级（1） b。 在蒸汽重整阶段下游的至少一个阶段，用于催化转化离开蒸汽重整阶段（变换阶段）的氢，一氧化碳和过量蒸汽的混合物（2）; 和c。 描述了通过选择性甲烷化催化降低转化产物的残留一氧化碳含量的转移阶段下游的精细纯化阶段（3）。 在该装置中，变速级（2）和精净化级（3）构成为一体式中空体（放热催化剂级）。

公开(公告)号：US20020038066A1

公开(公告)日：2002-03-28

申请号：US09273848

申请日：1999-03-22

Inventor： VINCENT A. STRANGIO ,  FRITS M. DAUTZENBERG ,  HANS PETER ALEXANDER CALIS ,  AVINASH GUPTA

IPC: C07C004/02

CPC classification number: B01J19/32 ,  B01J8/0221 ,  B01J8/0434 ,  B01J8/0453 ,  B01J8/06 ,  B01J19/2485 ,  B01J2208/00203 ,  B01J2208/00415 ,  B01J2208/021 ,  B01J2219/30207 ,  B01J2219/30223 ,  B01J2219/30475 ,  B01J2219/3085 ,  B01J2219/32279 ,  B01J2219/32296 ,  B01J2219/32425 ,  B01J2219/32466 ,  C07C5/327 ,  C07C5/333 ,  C07C15/46

Abstract: A fixed particle bed in a vessel wherein the bed is a structured bed in a plurality of flow channels with the cross-section of the bed in each channel being from 1 to 20 particles, more preferably 1 to 10 particles.

Abstract translation: 在容器中的固定颗粒床，其中床是多个流动通道中的结构化床，床在每个通道中的横截面为1至20个颗粒，更优选1至10个颗粒。

公开(公告)号：US5006316A

公开(公告)日：1991-04-09

申请号：US194402

申请日：1988-05-16

Applicant: Umberto Zardi ,  Giorgio Pagani

Inventor： Umberto Zardi ,  Giorgio Pagani

IPC: B01J8/04

CPC classification number: B01J8/0434 ,  B01J8/043 ,  B01J8/0469

Abstract: In reactors for heterogeneous synthesis, comprising a boiler and a heat exchanger inserted at least partially into the end catalytic beds, and at least an intermediate catalytic bed, two airspaces are now provided in each catalytic bed by introducing couples of annular walls, one of said airspaces being produced between the cartridge's internal wall and the perforated wall inserted close to it.

Abstract translation: 在用于非均相合成的反应器中，包括锅炉和至少部分地插入到末端催化床中的热交换器，以及至少一个中间催化床，现在通过引入一对环形壁，在每个催化床中设置两个空气空间， 在盒的内壁和靠近它插入的穿孔壁之间产生空间。

公开(公告)号：US20170348660A1

公开(公告)日：2017-12-07

申请号：US15537540

申请日：2015-12-17

Applicant: ThyssenKrupp Industrial Solutions AG ,  thyssenkrupp AG

Inventor： Jürgen Fuchs ,  Klaus Ruthardt ,  Rolf Siefert

IPC: B01J8/04 ,  F23C99/00 ,  C01B21/28

CPC classification number: B01J8/0434 ,  B01J8/02 ,  B01J2208/00672 ,  B01J2208/00814 ,  B01J2208/0084 ,  B01J2208/00884 ,  B01J2208/025 ,  C01B21/28 ,  F23C99/006 ,  F23D2900/14581 ,  F23D2900/14582

Abstract: A method for disposing a bed comprising particles in a burner through which a gas can flow, more particularly in a burner basket of an ammonia oxidation burner, where the particles are disposed such that the bed has a greater flow resistance in an edge region of the burner than in an inner region of the burner. Further, a burner basket for a burner may have a bed comprising particles, wherein the particles are disposed such that the bed has a greater flow resistance in an edge region of the burner basket than in an inner region of the burner basket.

公开(公告)号：US4952375A

公开(公告)日：1990-08-28

申请号：US210868

申请日：1988-06-24

Applicant: Umberto Zardi

Inventor： Umberto Zardi

IPC: B01J8/04 ,  C01C1/04 ,  C07C29/152

CPC classification number: C01C1/0423 ,  B01J8/0415 ,  B01J8/0434 ,  B01J8/0453 ,  B01J8/0469 ,  B01J8/0496 ,  C07C29/152 ,  B01J2208/00194 ,  Y02P20/52 ,  Y10T29/49826

Abstract: The energy consumption of conventional reactors for heterogeneous synthesis, e.g., ammonia synthesis and methanol synthesis, wherein the synthesis gas flows substantially axially through catalyst beds, is substantially reduced by inserting in at least one catalyst bed: two concentric cylindrical substantially perforated walls to laterally delimit the bed; a bottom closure between these walls; and optionally a diaphragm on top of the bed. Optionally also, a catalyst granulometry gradient may be employed in the upper part of the bed. An upper minor portion of at least one of the cylindrical walls may be unperforated. The synthesis gas now traverses the bed substantially radially.

公开(公告)号：US4755362A

公开(公告)日：1988-07-05

申请号：US859044

申请日：1986-05-02

Applicant: Umberto Zardi

Inventor： Umberto Zardi

IPC: B01J8/04 ,  C01C1/04 ,  C07C29/152 ,  A01C1/00

CPC classification number: C01C1/0423 ,  B01J8/0415 ,  B01J8/0434 ,  B01J8/0453 ,  B01J8/0469 ,  B01J8/0496 ,  C07C29/152 ,  B01J2208/00194 ,  Y02P20/52 ,  Y10T29/49826

Abstract: The energy consumption of conventional reactors for heterogeneous synthesis, e.g., ammonia synthesis and methanol synthesis, wherein the synthesis gas flows substantially axially through catalyst beds, is substantially reduced by inserting in at least one catalyst bed: two concentric cylindrical substantially perforated walls to laterally delimit the bed; a bottom closure between these walls; and optionally a diaphragm on top of the bed. Optionally also, a catalyst granulometry gradient may be employed in the upper part of the bed. An upper minor portion of at least one of the cylindrical walls may be unperforated. The synthesis gas now traverses the bed substantially radially.

Abstract translation: 用于异质合成的常规反应器的能量消耗，例如氨合成和甲醇合成，其中合成气基本上轴向流过催化剂床，通过将至少一个催化剂床插入两个同心圆柱形的基本上穿孔的壁来大幅度地减少，以横向界定 床; 这些墙之间的底部封闭; 以及可选地在床的顶部上的隔膜。 也可以在床的上部使用催化剂粒度梯度。 至少一个圆柱形壁的上部小部分可以是未穿孔的。 合成气体现在大致径向地穿过床。